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Photonic crystals in biology

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Poster Session, Tuesday, June 15<br />

Theme A1 - B702<br />

Fas t Track Preparat ion of ZnO nanorods <strong>in</strong> Water<br />

M. A. Shah 1 *, F.M.Al-Marzouki 1 and A.A. Al-Ghamdi 1<br />

1 Department of Physics, Faculty of Sciences, K<strong>in</strong>g Abdul Aziz University, Jeddah 21589, K<strong>in</strong>gdom of Saudi Arabia<br />

Abstract-We will present a fast, soft, economical and bio-safe synthesis of hexagonal-shaped z<strong>in</strong>c oxide (ZnO) nanorods at very low temperature<br />

of ~120 o C simply by us<strong>in</strong>g metallic z<strong>in</strong>c powder and de-ionized (DI) water without the use of any additives or am<strong>in</strong>es. The product is believed to<br />

be bio-safe and bio-compatible and can be readily used for medic<strong>in</strong>e besides other applications.<br />

Nanostructures of z<strong>in</strong>c oxide (ZnO), <strong>in</strong>clud<strong>in</strong>g particles,<br />

rods, wires, belts, tubes, cages, walls, flowers and r<strong>in</strong>gs have<br />

scattered a great deal of attention <strong>in</strong> recent years because of<br />

their useful electronic and optoelectronic properties and<br />

novel application <strong>in</strong> catalysis, pa<strong>in</strong>ts, wave filters, UV<br />

detectors, transparent conductive films, varistors, gas<br />

sens<strong>in</strong>g, solar cells, sun screens and other cosmetic products.<br />

Moreover, the wide range of morphological diversity <strong>in</strong> the<br />

nano-regime has made this material a promis<strong>in</strong>g candidate <strong>in</strong><br />

the field of nanotechnology and opened up new possibilit ies<br />

for the fabrication of high performance devices based on<br />

these nanostructures. Among the various nanoforms, one<br />

dimensional (1D) nanostructures have received considerable<br />

attention due to their potential <strong>in</strong>terests for understand<strong>in</strong>g<br />

fundamental physical concepts and for efficient field<br />

emission that has enormous commercial applications such as<br />

field emission flat panel displays, x-ray sources, parallel<br />

beam electron microscopy and vacuum microwave<br />

amp lifiers [1].<br />

Synthesis of nanomaterials forms a vital aspect of the<br />

science of nanomaterials and chemical methods have proved<br />

to be more effective and versatile than physical methods and<br />

have, therefore, been employed widely. While nanomaterials<br />

have been generated by physical methods too such as laser<br />

ablation, arc discharge and evaporation, chemical methods<br />

have proved to be more attractive as they provide better<br />

control over the size and shape, which is one of the essential<br />

features <strong>in</strong> nanoscience. Chemical synthesis of nanomaterials<br />

has been reviewed by few authors but <strong>in</strong>numerable<br />

improvements and better methods are be<strong>in</strong>g reported<br />

cont<strong>in</strong>ually <strong>in</strong> the last few years [2,3].<br />

In this work we will explore the formation of ZnO<br />

nanostructures by the reaction of z<strong>in</strong>c metal with DI water at<br />

very low temperature of 120oC. The simple reaction is<br />

carried out <strong>in</strong> absence of any additives and/or am<strong>in</strong>es. The<br />

synthesized ZnO products were characterized <strong>in</strong> terms of<br />

their structural and optical properties. By the morphological<br />

<strong>in</strong>vestigations us<strong>in</strong>g FESEM, it was observed that the grown<br />

products are hexagonal-shaped ZnO nanorods with the<br />

diameters and lengths <strong>in</strong> the range of 70-90 nm with several<br />

micrometers. The EDS and XRD pattern confirmed the<br />

composition and crystall<strong>in</strong> ity of the grown nanorods and<br />

revealed that the grown products are pure ZnO with the<br />

wurtzite hexagonal phase. The optical properties of grown<br />

products were characterized by room-temperature<br />

photolum<strong>in</strong>escence spectroscopy which confirmed the good<br />

optical properties for the grown products.<br />

[2] H. Wie, Y. Wu, N. Lun, and C. Hu, Mater. Sci. Eng. A Vol.<br />

393, 80 (2005).<br />

[3] Z.W. Pan, Z.R. Dia and Z.L. Wang, Science Vol. 291, 1947<br />

(2001).<br />

*Correspond<strong>in</strong>g author: 0Tmashahnit@yahoo.com<br />

[1] C. X. Xu, Y. Liu, and G. Wang, Solid State Communication<br />

Vol. 122, 175 (2002).<br />

6th Nanoscience and Nanotechnology Conference, zmir, 2010 212

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