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natural-products-in-plant-pest-management

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50 J.C. Pretorius and E. van der WattMonoterpenes, consist<strong>in</strong>g of two isoprene units (C 10), form the ma<strong>in</strong>component of essential oils and are therefore economically important due totheir aroma (perfume), e.g. menthol, camphor, geraniol and p<strong>in</strong>ene (Fig. 3.4).Their application potential <strong>in</strong> agriculture lies <strong>in</strong> the fact that specific monoterpenesare growth <strong>in</strong>hibitors of higher <strong>plant</strong>s (e.g. menthol and p<strong>in</strong>ene) andtherefore have the potential to be developed as <strong>natural</strong> herbicides.Sesquiterpenes consist of three isoprene units (C 15) (Fig. 3.5). One of thebest known sesquiterpenes is absissic acid (ABA), which has a hormonalfunction. Plants show<strong>in</strong>g <strong>natural</strong> resistance towards drought stress synthesizemore ABA than drought-sensitive crops. Theoretically, the externalapplication of ABA to crops has the potential to manipulate drought resistance<strong>in</strong> crops. Other sesquiterpenes have medic<strong>in</strong>al value e.g. as diureticsand as antimicrobials (e.g. kad<strong>in</strong>ene from juniper berry).Diterpenes consist of four isoprene units (C 20) and are the rarest types ofterpenes <strong>in</strong> <strong>plant</strong>s. Of the most important <strong>in</strong> this group is the hormone gibberellicacid (GA; Fig. 3.6). Although <strong>natural</strong> hormones are used <strong>in</strong> the horticulturaland agricultural <strong>in</strong>dustries on a small scale as growth stimulants, itis expensive and not economically justifiable on a large scale.OHCOOHIso-amyl alcoholAngelic acidFig. 3.3. Hemiterpenes found <strong>in</strong> the form of alcohols or acids.OHOMenthol Camphor Geraniol P<strong>in</strong>eneFig. 3.4. Examples of monoterpenes.OHH 3 COH CHCH 33HOHH COOHCH 3HABAKad<strong>in</strong>eneFig. 3.5. Examples of sesquiterpenes.

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