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natural-products-in-plant-pest-management

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Natural Products from Plants 57of certa<strong>in</strong> seedl<strong>in</strong>gs and shows potential as an herbicide. Scopolet<strong>in</strong> has astimulat<strong>in</strong>g effect on seed germ<strong>in</strong>ation but an <strong>in</strong>hibit<strong>in</strong>g effect on seedl<strong>in</strong>ggrowth, <strong>in</strong>dicat<strong>in</strong>g a potential as pre-emergence herbicide.Flavonoids are the largest group of <strong>natural</strong> phenolic compounds found<strong>in</strong> <strong>plant</strong>s. More than 5000 different flavonoids have been described. All flavonoidshave one th<strong>in</strong>g <strong>in</strong> common, namely a 15-carbon ‘skeleton’ structured<strong>in</strong> three phenyl r<strong>in</strong>gs (A, B and C; Fig. 3.21). Other examples are shown<strong>in</strong> Fig. 3.22.A large variety of biological activities have been associated with flavonoids,<strong>in</strong>clud<strong>in</strong>g antiviral, anti-<strong>in</strong>flammatory, antioxidant, antidiabetic,anticancer, <strong>in</strong>sect-repell<strong>in</strong>g and free-radical-scaveng<strong>in</strong>g activities. Whatmakes this group extraord<strong>in</strong>ary from an <strong>in</strong>dustrial perspective are the excessivequantities found <strong>in</strong> both edible and non-edible <strong>plant</strong>s as well as theirpotential to be developed <strong>in</strong>to <strong>natural</strong> <strong>products</strong>. It is estimated that about 2%of all carbon photosynthesized by <strong>plant</strong>s is converted to flavonoids and thisamounts to approximately 1 × 10 9 tons per annum. With this enormousamount of flavonoids available, and <strong>in</strong> light of the numerous bioactivitiesidentified to date, the time is now ripe to consolidate our knowledge of theBACFig. 3.21. Typical fl avonoid structure.HOOHOHOHOHOHOOHOOOHOHOHOHOHOHOHEpicatech<strong>in</strong> Gallocatech<strong>in</strong> (+)-Catech<strong>in</strong>OHOHOHOHOHOHHOOHHOOHOOHOHyperosidegalactoseOOHOQuercitr<strong>in</strong>rhamnoseFig. 3.22. Flavonoid examples.

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