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.Ê Stock Ea uipment Company A Unit of General Signal fermlN¢SDA/a! WHC-SD-W100-TI-003 Rev. 0 TABLE OF CONTENTS Toxicity Characteristic Leaching Procedure (TCLP) Pace 1.0 Scope and Application . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 2.0 Summary of Method . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 3.0 Interferences .................................. 3 4.0 Apparatus and Materials . . . . . . . . . . . . . . . . . . . . . . . . . 3 4.1 Agitation Apparatus . . . . . . . . . . . . . . . . . . . . . . . . . . 3 4.2 Extraction Vessel . . . . . . . . . . . . . . . . . . . . . . . . . . : . 4 43 Filtration Devices . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 4.4 Filters ..................................... 5 45 pI'I Metcrs . .. .. . . . . . . . .. . .. . . .. . . . . . . . . . . . . S 4.6 Laboratory Balance . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 5.0 Reagents ..................................... 5 6.0 Sample Collection, Preservation, and Handling . . . . . . . . . 6 7.0 Preliminary TCLP Evaluation . . . . . . . . . . . . . . . . . . . . . . 6 7.1 Preliminary Determination of Percent Solids ........ 7 7.2 Determination of Whether Waste is liquid or Has Insignificant Amounts of Solid Material ... 8 7.3 Determinapon of `wnethEr the Wastes Require Particle-Size Reduction . . . . . . . . . . . . . . . . . . . . . 9 7.4 Determination of Appropriate Extraction Fluid ..... 9 8.0 Procedure when Volatiles are not Involved . . . . . . . . . . . 10 9.0 Quality Assurance Requirements . . . . . . . . . . . . . . . . . . . 14 .b ..... ........... ........... . , . . . . . . . . . . . . . . . . . . . . . . . . ... F9gure Number 2 - Rotary Agitation . . . . . . . . . . . . . . . . . . . . . 16 Table Number I - Volatile Contaminates . . . . . . . . . . . . . . . . . . 17 Table Number 2 - Suitable Rotary Agitation Apparatusl ...... 18 Table Number 3 - Suitable Zero-Headspaa Extractor Vessels . 19 Table Number 4 - Suitable Filter Holdersl . . . . . . . . . . . . . . . . 20 Table Number 5 - Suitable Filter Media . . . . . . . . . . . . . . . . . . 21 Appendix A ....................................... 22 C-52 Procedure 90109-0 Page 2„ of 22 . :a
19 SCOPE AND APPLICATION WHC-SD-W100-TI-003 Rev. 0 STOCK EQUIPMENT COMPANY Toxicity Characteristic I.each Procedure F:'C•..P) Procedure 90109-0 1.1 The TC4P is designed to determine the mobility of both organic and inorganic contaminates present in liquid, solid, and multiphasic wastes. 1.2 If a total analysis of the waste demonstrates that individual contaminates are not present in the waste, or that they are present but at such low concentrations that the appropriate regulatory thresholds could not possibly be exceeded, the TCLP need not be run. Us SUMMARY OF METHOD 3.0 21 For liquid wastes ( i.e, those containing insignificant solid material), the waste, after filtration through a 0.6-0.8 an glass fiber filter, is defined as the TCLP extract. 2.2 For wastes comprised of solids or for wastes containing significant amounts of solid material, the particle-size of the waste is reduced (if necessary); the liquid phase, if any, is separated from the solid phase and stored for later analysis. The solid phase is extraeted with an amount of extraction fluid equal to twenty (20) times the weight of the solid phase. The extraction fluid employed is a function of alkalinity of the solid phase of the waste. A special extractor vessel is used when testing for volatiles (Reference Table 1, Page 17). Following extraction, the liquid extract is separated from the solid phase by 0.6 to 0.8 µtn glass fiber filter filtration. 2.3 If compatible (i.e., multiple phases will not form on combination), the initial liquid phase of the waste is added to the liquid extract, and these liquids are analyzed together. If incompatible, the liquids are analyzed separately and the results are mathematically combined to yield a volume-weighted average connection. J 2- P-otcaaal--inte rznces _-strtriy__ - eacoynterea_dunnn ' anA ^ are discuSSed in -- - ^ -"-'^ the individual analytical methods. 4.0 APPARATUS AND MATERIALS 4.1 AGITATION APPARATUS Stock E p uipment Company A Unit of General Signal Fp,n 41408-11tM/a6 An aeceptable agitation apparatus is one which is capable of routing the extraction vessel in an end-over-end fashion (Reference Table 2, Page 18) at thirty (30) s two (2) rpm. Suitable devices known to EPA are identified in Table 2. C-53 Page _I of 22
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R 2.1 199^ ^.EN GINEERING DATA TRAN
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Date Received% • I INFORMATION RE
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. SUPPORTING DOCUMENT 1. Total Page
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WHC-SD-W100-TI-003 Rev. 0 EXECUTIVE
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F`= WHC-SD-W100-TI-003 Rev. 0 DESCR
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2.1 REGULATORY FRAMEWORK WHC-SD-W10
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3.3 TESTING APPROACH WHC-SD-W100-TI
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4.1 SCREENING TEST RESULTS WHC-SD-W
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WHC-SD-W100-TI-003 Rev. 0 Table 4-3
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1.0 INTRODUCTION WHC-SD-W100-TI-003
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WHC-SD-W100-TI-003 Rev. 0 Waste For
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^-: -- ^ Component Waste Type 1 LET
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WHC-SD-W: JV-TI-VVJ ^cv. v APPENDIX
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Scope WHC-SD-W100-TI-003 Rev. 0 Sup
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00 V F-' Activity and Miltstone Cha
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WHC-SD-W100-TI-003 Rev. 0 Laborator
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J. L. Westcott Page 3 June 1, 1992
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•N`^C-Sf1-"d100-71-003 Rev. 0 ,S'
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CONTAINER /NFORMATlO N: `d"-C-Sn-'w
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ONTANVER BVFORMA SI7 E: AMOUN=i 8 G
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LOT WRAP 2A.4 SHEET 7.XLS RECOMMEND
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LOT WRAP 2A.5 SHEET 8.XLS RECOMMEND
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.:•n-,,, LOT WRAP 2A.6 SHEET 9.XL
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LOT WRAP 2A.7 SHEET 10.XLS RECOMMEN
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PHYSICAL DESCR/PTTON: V-r-S?-W100-T
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,.: Westinoause Harlford COMM WHC-S
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O I tA SHEETII.XLS ;, LOT WRAP2A.2
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CONTAINER /NFORMAT/ON: DOSE: SIZE:
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PU33-11-1992 09:48 FROM EDS/qRI$ir
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LOT WRAP 2A 10 Slf-EET 14.)C,S RECO
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qN i: 105N-89-1097 105N-89-1098 105
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SIZE: DOSE: 5 GAL 1 1@15 Mr 30 GAL
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WHC-SD-W100-TI-003 Rev. 0 Westtngho
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LOT WRAP A2.14 SHEET 18.XLS RECOMME
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Table 1 Candidate Waste Forms Absor
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- '^ - qev. r' Literature Search WR
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L im e Literature Search WRAP 2A Pa
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The report compares the 7eachabilit
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J. L. Westcott Page 2 May 29, 1992
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WHC-SD-W100-TI-003 Rev. 0 SURVEY OF
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OAK R1DGE NATIONAL LABORATORY OPERA
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WHC-SD-W100-TI-003 Rev. 0 STR?.THGI
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Contained under four reports: WHC-S
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Stock Equipment Company WHC-SD-WI00
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^ i w STOCK EOUIPMENT COMPANY 14-OC
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Sample ID W B1 Elemant STRONIIUM Ma
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Westinghouse Hanford Company 2355 S
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WHC-SD-W100-TI-003 Rev. 0 Russ Czel
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Stock Equipment Company 3:0 -SCFIED
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THERMAL CYCLING SAMPLES BEFORE THE
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BIODEGRADATION SAMPLES BEFORE THE S
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Stock Equipment Company 1.0 SUMMARY
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Stock Equipment Company WHC-SD-W100
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2a0 SCHEDULE Activitv - Prepare Wor
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 _QVrDvrru
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^-_- .,:... WHC-SD-W100-TI-003 Rev.
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Ceramics and glass WHC-SD-W200-TI-0
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,. ., Extruder/melter WHC-SD-W100-T
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