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WHC-SD-W100-TI-003 Rev. 0 Pulverized fly ash contains mostly silica and alumina, with very little calcium. The lack of calcium requires addition of lime or cement to activate this material. Fly ash can be added in ratios as high as 10:1 and still obtain a suitable final waste form. Gypsum cement Gypsum cement is composed of hydrated calcium sulfate. It has a lower compressive strength than portland cement. The elimination of calcium hydroxide gives this material a lower pH than OPC. Plaster of paris Plaster of paris is the most recognizable gypsum cement. This same material is also used in wallboard. Envirostone"'") This material is a proprietary mixture based on gypsum cement. The proprietary additives are claimed to make this mix more compatible with organic and acidic wastes. Modified cements Cement mixtures can be modified to enhance their ability to incorporate difficult wastes, and to increase their resistance to loss of soluble waste constituents through leaching. Physical absorbents Physical absorbents are used to incorporate non-hydraulic materials such as _liquid arganics _into the -waste matrix. Polymer impregnated cement Polymer impregnation is a method to decrease leachability be filling the interstitial pores with water-resistant polymer. Thermoplastic Polymers Thermoplastic polymers are a class of materials that melt at elevated temperatures. These matrices can be used to immobilize materials through micro- and macro- encapsulation. Bitumen ( asphalt) Bituminous polymers are familiar materials used in the construction of roads, and in the roofing industry. They are produced from crude oil, and can have varying physical properties. Straight run G-4
^-_- .,:... WHC-SD-W100-TI-003 Rev. 0 This is the raw material as is comes directly from the distillation column. It has a low softening temperature, high penetration, and low compressive strength. Pitch This is straight-run bitumen that has been solvents. The material solidifies when the controls are required. Oxidized liquefied by dilution with organic solvent evaporates. Solvent vapor Oxidized bitumen is produced by blowing air through straight-run material. It is commonly used for roofing applications. This material is stronger, harder, and less sensitive to temperature changes than straight-run. This results in hig,i'cr nieitiny^ p"uint proccssing temperatures. Cracked Cracked bitumen is more fe^Ci *ive to temperature changes than other types. This imparts a quick-hardening nature, giving high strength combined with low penetrat-ion--and--a high softening point. Cracked bitumens can become brittle at low temperature. Emulsions Bitumen emulsions are similar to pitch, except the solvent is aqueous with surfactants to prevent phase separation. The material solidifies when the wat2r--i-s-evaporated. Sulfur Sulfur has several possible uses in radioactive waste treatment in WRAP Module 2A. It can be used as a solidification matrix, a hardener, and as an amalgam for mercury treatment. Immobilization matrix Sulfur "cement" can be used in a manner similar to other thermopolymers. It exhibits high strength and low penetration. Vapor controls are necessary and there is some concern about potential phase changes in the final waste form causing ioss of structural properties over time. Bitumen hardener _-____Sulfur can be added to straight-run bitumen to increase its hardness and compressive strength. Sulfur hardening of bitumen is a non-reversible process. Polyethylene G-5
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R 2.1 199^ ^.EN GINEERING DATA TRAN
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Date Received% • I INFORMATION RE
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. SUPPORTING DOCUMENT 1. Total Page
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WHC-SD-W100-TI-003 Rev. 0 EXECUTIVE
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WHC-SD-W100-TI-003 Rev. 0 been achi
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__ _ _ MHC-SIL-yJ3,00-TI-D03 Rev. 0
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F`= WHC-SD-W100-TI-003 Rev. 0 DESCR
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WHC-SD-W100-TI-003 Rev. 0 LIST OF T
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WHC-SD-W100-TI-003 Rev. 0 WASTE REC
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WHC-SD-W100-TI-003 Rev. 0 1.2.1 Fee
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^s. WHC-SD-W100-TI-003 Rev. 0 conta
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__-'°'2 WHC-SD-W100-TI-003 Rev. 0
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2.1 REGULATORY FRAMEWORK WHC-SD-W10
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^..." ;_:.. :.^ .^.y^ WHC-SD-W100-T
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WHC-SD-W100-TI-003 Rev. 0 which the
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kIHC-Sû-Wi"v"u-Ti-u03 Rev. V ,--,,
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WHC-SD-W100-TI-003 Rev. 0 Type 1 wa
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3.3 TESTING APPROACH WHC-SD-W100-TI
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^.: fi WNC-SD-W100-TI-003 Rev. 0 Fi
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4.1 SCREENING TEST RESULTS WHC-SD-W
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,^. ----- -- WHC-SD-W100-TI-003 Rev
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WHC-SD-W100-TI-003 Rev. 0 4.1.3 The
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p Sam le Compressive Radiation stre
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WHC-SD-W100-TI-003 Rev. 0 Table 4-3
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..., TESTING RESULTS .^.CSSD-W-1OO-
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A I w ^^',; ^^ ;J ?1Fasf^.}: "q -?
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;..;: .^:. WHC-SD-W100-TI-003 Rev.
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--- ....ti s..` WHC-SD-WI00-TI-003
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1.0 INTRODUCTION WHC-SD-W100-TI-003
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WHC-SD-W100-TI-003 Rev. 0 Waste For
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^-: -- ^ Component Waste Type 1 LET
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.^x. --1vHC-SD iii00- T i-003 Rev.
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WHC-SD-W: JV-TI-VVJ ^cv. v APPENDIX
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,..^ c:-- z ,.E ^=t ^^ln^l WHC-SD-W
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Scope WHC-SD-W100-TI-003 Rev. 0 Sup
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00 V F-' Activity and Miltstone Cha
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WHC-SD-W100-TI-003 Rev. 0 Laborator
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WHC-SD-WIOO-TI-003 Rev. 0 APPENDIX
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16490 Chiaccothe Itoad Chagrin Fall
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ca-. tY•^_E Q . - - StoGkE4uip+!n
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^.. WHC-SD-W100-TI-003 Rev. 0 . , I
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Waste Type: WHC-SD-W100-TI-003 Rev.
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Stock E quipment Company A Unit of
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G' ,.,. d,_ s WHC-0-W100-TI-003 Rev
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Cx U: r°... .• , .ti Waste Type:
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-. LeachantSolution: Specimen Diame
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c^1, WHC-SD-W100-TI-003 Rev. 0 THER
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..... lry" - Stock E a uipment Comp
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;=. .:^;. WHC-SD-W100-TI-003 Rev< 0
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(.7 ..^^ -„n f^. [Y^. Waste Type:
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Date: _ Leachability Time Point Lea
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23 Ninety ( 90) Day Immersion Test
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ty ,.. ='`F r...,, b Ly.. Specimen
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25 BIODEGRADATION TEST PROCEDURE St
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Date: WHC-SD-W100-TI-003 Rev. 0 BIO
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^_... ..^^ C:i1 Date: WHC-SD-W100-T
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Date: WHC-SD-W100-TI-003 Rev. 0 --
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f-^ -- WHC-SD-W100-TI-003 Rev. 0 2.
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^-..., 3•0 ASSAY FOR MEI'ALS 3.1
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^c. v 3 0 w.3 cn a v t[ACeRUtIIY IO
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 STOCK EQU
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19 SCOPE AND APPLICATION WHC-SD-W10
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L:^3 ll Q. 4 AA :'ILTEP.S WHC-0-W10
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4_T tJrD o,...Ys j ^,.,. WHC-SD-W10
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WHC-SD-W100-TI-003 Rev. 0 -, Proced
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WHC-SD-W100-TI-003 Rev. 0 Procedure
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(FM WHC-SD-W100-TI-003 Rev. 0 Proce
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C... 6 Wet Waste Sample Contains no
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^..., . ,.y^ h:.r WHC-SD-WI00-Ti-00
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:. WHC-SD-W100-TI-003 Rev. 0 TA3i.E
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^' . WHC-SD-W100-T1-003 Rev. 0 TABL
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^- ^-> ^ C^Jl I I^t ^.: l WHC-St]-W
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c. 03 00 r=3 ^t C^' II 6.0 II Calib
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LY; ^ C=l . ^.^ .^,..,, €:^. MHC-
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R: C=1 rIj s^ ^ ^.. WHC-SD-YlI00-TI
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.,,_..1 ---^ - - i-•_E ?*^^ Mater
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WHC-SD-W100-TI-003 Rev. 0 Dow Chemi
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WHC-S®-hi1.00-T'.-00?, Rev. Dow Ch
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t;7_7 ,...:: ----------- WHC-SD-W10
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WHC-SD-W100-TI-003 Rev. 0 Daw M.. u
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^ ^..rYfl VF •UIYb 1 1 AGA GllS.
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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CHARACTERIZATION DATA Part A: Overv
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Grit Specie or MaterialOverall Cont
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WHC-SD-W100-TI-003 Rev. 0 The incin
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WHC-SD-W100-TI-003 Rev. 0 183-H BAS
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WHC-SD-W100-TI-003 Rev. 0 June - Se
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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^- WHC-SD-W100-TI-003 Rev. 0 BASIN
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WHC-SD-W100-TI-003 Rev. 0 ---------
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J. L. Westcott Page 3 June 1, 1992
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u...^^, WHC-SD-W100-TI-003 Rev. 0 I
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•N`^C-Sf1-"d100-71-003 Rev. 0 ,S'
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CONTAINER /NFORMATlO N: `d"-C-Sn-'w
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ONTANVER BVFORMA SI7 E: AMOUN=i 8 G
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LOT WRAP 2A.4 SHEET 7.XLS RECOMMEND
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LOT WRAP 2A.5 SHEET 8.XLS RECOMMEND
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.:•n-,,, LOT WRAP 2A.6 SHEET 9.XL
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LOT WRAP 2A.7 SHEET 10.XLS RECOMMEN
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PHYSICAL DESCR/PTTON: V-r-S?-W100-T
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,.: Westinoause Harlford COMM WHC-S
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O I tA SHEETII.XLS ;, LOT WRAP2A.2
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CONTAINER /NFORMAT/ON: DOSE: SIZE:
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PU33-11-1992 09:48 FROM EDS/qRI$ir
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LOT WRAP 2A 10 Slf-EET 14.)C,S RECO
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qN i: 105N-89-1097 105N-89-1098 105
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SIZE: DOSE: 5 GAL 1 1@15 Mr 30 GAL
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WHC-SD-W100-TI-003 Rev. 0 Westtngho
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LOT WRAP A2.14 SHEET 18.XLS RECOMME
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---- - LOT WRAP ZA.13 SHEET 17.XLS
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n .-.^..-n..^^- .. ... .dJ. ^ ShIEE
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--^ WHC-SD-W100-TI-003 Rev. 0 APPEN
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WHC-SD-W100-TI-003 Rev. 0 Westingho
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Table 1 Candidate Waste Forms Absor
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--- -Aauaspt and Pe-liroset WHC-SD-
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- '^ - qev. r' Literature Search WR
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Dow Polymer WHC-SD-W100-TI-003 Rev.
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L im e Literature Search WRAP 2A Pa
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The report compares the 7eachabilit
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J. L. Westcott Page 2 May 29, 1992
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Package #1: Package #2: WHC-SD-W100
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WHC-SD-W100-TI-003 Rev. 0 SURVEY OF
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f ..;' WHC-SD-W100-TI-003 Rev. 0 A
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 Bibliogra
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WHC-SD-W100-TI-003 Rev. 0 A. P. Tos
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OAK R1DGE NATIONAL LABORATORY OPERA
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 A report
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WHC-SD-W100-TI-003 Rev. 0 impermeab
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WHC-SD-W100-TI-003 Rev. 0 reprocess
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WHC-SD-W100-TI-003 Rev. 0 STR?.THGI
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Contained under four reports: WHC-S
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^.yo F-SD-W"00-7-003 Rev. 0 THERMOS
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WHC-SD-W100-TI-003 Rev. 0 The techn
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loomi^^lC& 111111111111F .^^.\ West
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û9^c ?fi. ...^ .._-, WHC-SD-W100-T
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Stock Equipment Company WHC-SD-WI00
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^ i w STOCK EOUIPMENT COMPANY 14-OC
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\. . 1 .: lh,lf^ LEACH / IMMERSIONI
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^;- v.4'? Sampls ID L781 Elsment CO
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4.a
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Sanp)a ID L781 Elamant STRONTIUM Ma
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.^ "-; SampI81D L3B2 Z e"- ^.;;. Sa
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Sample 10 L3B1 Elsmant CESIUM Matri
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Sample ID W B1 Elemant STRONIIUM Ma
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Westinghouse Hanford Company 2355 S
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--- - ftCR-e4Uip1P1eFf Company WHC-
Page 309 and 310: WHC-SD-W100-TI-003 Rev. 0 Russ Czel
Page 311 and 312: Stock Equipment Company 3:0 -SCFIED
Page 313 and 314: THERMAL CYCLING SAMPLES BEFORE THE
Page 315 and 316: BIODEGRADATION SAMPLES BEFORE THE S
Page 317 and 318: C/ 0D OC M1 0, ^yII i..) d tl ^ a I
Page 319 and 320: T 1 A w ^ • $ ^py yf ; pp V ^ py
Page 321 and 322: T 1 A ^ !^^ + ^ i •^^w^:rwwwwrpR^
Page 323 and 324: 'i A v lf^. j^^ u e e - - I I I a i
Page 325 and 326: 0 > d C.) O O F- 0 0 3 G NI U 3 ^ c
Page 327 and 328: en a-. p g aQ i ^ rr it - l r rF e^
Page 329 and 330: ' iO`F*'P\^ Westinghouse Hanford Co
Page 331 and 332: Stock Equipment Company 1.0 SUMMARY
Page 333 and 334: Stock Equipment Company WHC-SD-W100
Page 335 and 336: 2a0 SCHEDULE Activitv - Prepare Wor
Page 337 and 338: T 1 o+ THERMAL CYCLWG SAMPLES BEFOR
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Page 341 and 342: ^ °' cn l .:. U CD w a: w r' i ^ I
Page 343 and 344: SAMPLE ID Li-117 L1-118 L1-19 L3-17
Page 345 and 346: T °,w ^ - : C s 0 n a ^^ s ^ i ^-
Page 347 and 348: 71 I V y,,} ^ • 5il i ^ ^^ ^ ^ ^
Page 349 and 350: 0 a^ on O O M F- 1OCD 3 1 G N^ U il
Page 351 and 352: O > W C f.) O O 1-- ^ O HI 6./ 3 ^
Page 353 and 354: 0 > ar oe M 0 c C3, I O c V 3 Î d
Page 355 and 356: TI V 40 IN s i s : s ^l l i " p p l
Page 357 and 358: WHC-SD-W100-TI-003 Rev. 0 APPENDIX
Page 359: WHC-SD-W100-TI-003 Rev. 0 _QVrDvrru
Page 363 and 364: Ceramics and glass WHC-SD-W200-TI-0
Page 365 and 366: ,. ., Extruder/melter WHC-SD-W100-T
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