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[•.^^ h_:... J. L. Westcott Page 2 May 27, 1992 WHC-SD-W100-TI-003 Rev. 0 - - - - - * CPE-WOG-001 also be examined for unacceotable flammability or combustibility characteristics. The other class of solidifiers is inorganic binders which offer some of the characteristics of both cementitious agents and organic binders. The most useful literature packet is one entitled "Literature Search for WRAP Solidifiers." It summarizes most of the important references. The literature pointed out a number of additives or modifiers that improve waste product performance particularly for cement. Materials such as lime, silica, or alumina can improve cement leachability. For gypsum cements, retardant modifiers are probably necessary for proper solidification of phscerxfoarisand Envirostane*was*.e products' A1so, materials or reagents to avoid are important in considering the use of organic binders or polymers. A number of these guidelines are included in the literature references and summaries. This completes the initial phase of the WRAP literature search. We will attempi to keep the iiterature search current with time and periodically update to support the design work. If you have any questions or comments, please call me on 6-9616. W. 0. Greenhalgh, Principal Scientist Chemical Process Engineering dfm Attachments 'Envirostone0 is available in a slow set formulation. We have submitted a procurement request to obtain some for laboratory testing and evaluation. E-4 .
Table 1 Candidate Waste Forms Absorbents Cementitious Materials Or anic Binders •Vermiculite •Portland Cement Type I •Bitumen Kitty-L#tter - -•Partland Cement •Coid Working Polymers •Zeolites Type III -Dow Polymer® •Diatomaceous Earth •Pozzolan Cement -Water Extended •Calcium Sulfate •Envirostone® Polyester (WEP) Dissicants .Plaster of Paris -Epoxies, etc. •Silica Gel •Grout ( <strong>Hanford</strong>- •Heat Setting Polymers •Agricuiturai Products Nitrate Mix) -Polyethylene (cellulose, corn cobs, •Slag Cement -Polypropylene -etc.) •Polymer Modified -Polyurethane Cement -Polymethyl •Latex Cement Methacrylate, etc. •Syncrete® •Polymer Impregnated •FUETAP Concrete Concrete ( PIC) or •Concreted Pellets other waste form •Grout Mixes -Salt Resistant -Sulfate Resistant -Weather Resistant -High Density -E p oxy Grout Calcines Ceramics Inor g anic Binders •Salt Cake •Pellets •Sulfur Polymer Cement •Metal Oxides •Alkali-Clay Fixation •High Temp Sulfur •Granules/Pellets ( Cancrinite) -Water Glass ( Sodium •Formed Clay Silicate) •Fired Inorganic Resins •Acid Anhydride Melts •Aquaset® •Petroset® Metal Matrices Synthetic Rocks Vitrification •Alloy Melts •Titanates (Synroc) •Borosilicate Glass •Hardware Fusion -Hydrothermal Process •Phosphate Glass •Alumino Silicate Glass •Soda Glass •Other - Flint/ Borate/etc. •Fused Soils ®Envirostone is a trademark of U.S. Gypsum Company. --®Dow- Polymet•-is--a trademark of Davr Chemica i Company. •Aquaset is a trademark of Fluid Tech, Inc. •Petroset is a trademark of Fluid Tech, Inc. ®Syncrete is a trademark of STMI of France. E-5
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R 2.1 199^ ^.EN GINEERING DATA TRAN
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Date Received% • I INFORMATION RE
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. SUPPORTING DOCUMENT 1. Total Page
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WHC-SD-W100-TI-003 Rev. 0 EXECUTIVE
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2.1 REGULATORY FRAMEWORK WHC-SD-W10
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3.3 TESTING APPROACH WHC-SD-W100-TI
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4.1 SCREENING TEST RESULTS WHC-SD-W
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WHC-SD-W100-TI-003 Rev. 0 Table 4-3
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..., TESTING RESULTS .^.CSSD-W-1OO-
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1.0 INTRODUCTION WHC-SD-W100-TI-003
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WHC-SD-W100-TI-003 Rev. 0 Waste For
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^-: -- ^ Component Waste Type 1 LET
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WHC-SD-W: JV-TI-VVJ ^cv. v APPENDIX
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Scope WHC-SD-W100-TI-003 Rev. 0 Sup
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00 V F-' Activity and Miltstone Cha
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WHC-SD-W100-TI-003 Rev. 0 Laborator
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WHC-SD-WIOO-TI-003 Rev. 0 APPENDIX
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16490 Chiaccothe Itoad Chagrin Fall
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Waste Type: WHC-SD-W100-TI-003 Rev.
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Stock E quipment Company A Unit of
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-. LeachantSolution: Specimen Diame
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c^1, WHC-SD-W100-TI-003 Rev. 0 THER
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Date: _ Leachability Time Point Lea
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23 Ninety ( 90) Day Immersion Test
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25 BIODEGRADATION TEST PROCEDURE St
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 STOCK EQU
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19 SCOPE AND APPLICATION WHC-SD-W10
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L:^3 ll Q. 4 AA :'ILTEP.S WHC-0-W10
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WHC-SD-W100-TI-003 Rev. 0 -, Proced
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WHC-SD-W100-TI-003 Rev. 0 Procedure
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CHARACTERIZATION DATA Part A: Overv
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Grit Specie or MaterialOverall Cont
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WHC-SD-W100-TI-003 Rev. 0 The incin
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WHC-SD-W100-TI-003 Rev. 0 183-H BAS
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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Page 189 and 190: J. L. Westcott Page 3 June 1, 1992
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Page 193 and 194: •N`^C-Sf1-"d100-71-003 Rev. 0 ,S'
Page 195 and 196: CONTAINER /NFORMATlO N: `d"-C-Sn-'w
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Page 199 and 200: LOT WRAP 2A.4 SHEET 7.XLS RECOMMEND
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Page 207 and 208: PHYSICAL DESCR/PTTON: V-r-S?-W100-T
Page 209 and 210: ,.: Westinoause Harlford COMM WHC-S
Page 211 and 212: O I tA SHEETII.XLS ;, LOT WRAP2A.2
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Page 221 and 222: SIZE: DOSE: 5 GAL 1 1@15 Mr 30 GAL
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Page 249 and 250: Package #1: Package #2: WHC-SD-W100
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Page 277 and 278: Contained under four reports: WHC-S
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WHC-SD-W100-TI-003 Rev. 0 Russ Czel
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Stock Equipment Company 3:0 -SCFIED
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THERMAL CYCLING SAMPLES BEFORE THE
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