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WHC-SD-W100-TI-003 Rev. 0 Table 2 Viable Candidate Waste Forms for WRAP 2A Cementitious Materials Organic Binders Inorganic Binders •Portland Cement Type •Portland Cement Type III -+Poaaol-an Cement •Envirostone® •Plaster of Paris •Slag Cement ;Polymer Modified Cement •Latex Cement •Syncretem •Concreted Pellets •Grout Mixes -Salt Resistant -Sulfate Resistant -Weather Resistant I •Bitumen •Cold Working Polymers -Dow Polymer® =Water Extended Polyester (WEP) -Epoxies, etc. •Heat Setting Polymers -Polyethylene -Polypropylene -Polyurethane -Polymethyl Methacrylate, etc. •Polymer Impregnated Concrete •Sulfur Polymer Cement •High Temp Sulfur •Water Glass (Sodium Silicate) •Acid Anhydride Melts •Aquasetm •Petrosetm -Hiah Densitv _ -Epoxy Grout ' ®Envirostone is a trademark of U.S. Gypsum Company. ®Dow Polymer is a trademark of Dow Chemical Company. ®Aquaset is a trademark of Fluid Tech, Inc. ®Petroset is a trademark of Fluid Tech, Inc. ®Syncrete is a trademark of STMI of France. E-6
--- -Aauaspt and Pe-liroset WHC-SD-W100-TI-003 Rev. 0 LITERATURE SEARCH FOR WRAP SOLIDIFIERS 1. "Aquaset and Petroset," Technical Data Sheet, Fluid Tech, Inc., Las Vegas, NV. B itume n Aquaset is designed for aqueous waste and Petroset is designed for organic liquids. Up to 40 to 48 gallons of liquid can be solidified in a 55 gallon drum. - 1. S. Simpson, H.-lidal, and M. Morris, "Mixed and Chelated Waste Test Programs with Bitumen Solidification," Spectrum '88, September 11-15, 1988, Pasco, WA, pp 323-325. ;-, Bitumen solidification tests with mixed and chelated wastes were carried =- • out. Test results are still being evaluated for 10 CFR-61 type v.,* analyses. = 2. M. Snellman and M. Valkiainen, "Long Term Behavior of Bituminized Waste," Waste ,... cni_Sn7 rN . Management '86, Vol. 3, March 2-6, 1986, Tucson, AZ, ^Y Water uptake by bitumen solidified ion exchange resin was studied. Water uptake corresponded to the resin content, but no unacceptable bitumen product long term effects were observed. 3. A. J. Mattus, R. D. Doyle, and D. P. Swindlehurst, "Asphalt Solidification of Mixed Wastes," Waste Management '88, Vol. 1, February 28 - March 3, 1988, Tucson, AZ, pp 229-234. Solidification of some mixed waste with bitumen can be used to "delist" the waste so it can be disposed of as a radioactive waste. 4. A. Bernard, A. C. Nomine, G. Cornec, A. Bonnet, and L. Farges, "Long Term Leaching Tests on Full-Scale Blocks of Radioactive Wastes," Nuclear and Chemical Waste Management , Vol. 3, pp 161-168, 1982. Cement Leaching tests on full size waste blocks showed bitumen exhibited leach advantages over cement based waste products. 1. C. V. Mclsaac, D. W. Akers, J. W. McConnell, and N. Morcos, "Leach Studies on Cement-Solidified Ion Exchange Resins from Decontamination Processes at Operating Nuclear Power Stations," EGG-M-92090, Idaho National Engineering Laboratory, EG&G Idaho, Inc., Idaho Falls, ID. Tested Cemented resin samples against NRC requirements, the samples did not pass the tests. 2. L. Weitzman and L. E. Hamel, "Evaluation of Solidification/Stabilization as a Best Demonstrated Available Technology for Contaminated Soils," PB89-169908, Acurex Corporation, Research Triangle Park, NC, March 1989. E-7
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R 2.1 199^ ^.EN GINEERING DATA TRAN
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Date Received% • I INFORMATION RE
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. SUPPORTING DOCUMENT 1. Total Page
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WHC-SD-W100-TI-003 Rev. 0 EXECUTIVE
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2.1 REGULATORY FRAMEWORK WHC-SD-W10
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^..." ;_:.. :.^ .^.y^ WHC-SD-W100-T
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3.3 TESTING APPROACH WHC-SD-W100-TI
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4.1 SCREENING TEST RESULTS WHC-SD-W
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1.0 INTRODUCTION WHC-SD-W100-TI-003
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WHC-SD-W100-TI-003 Rev. 0 Waste For
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^-: -- ^ Component Waste Type 1 LET
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WHC-SD-W: JV-TI-VVJ ^cv. v APPENDIX
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Scope WHC-SD-W100-TI-003 Rev. 0 Sup
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00 V F-' Activity and Miltstone Cha
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WHC-SD-W100-TI-003 Rev. 0 Laborator
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WHC-SD-WIOO-TI-003 Rev. 0 APPENDIX
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16490 Chiaccothe Itoad Chagrin Fall
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Waste Type: WHC-SD-W100-TI-003 Rev.
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Stock E quipment Company A Unit of
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-. LeachantSolution: Specimen Diame
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Date: _ Leachability Time Point Lea
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23 Ninety ( 90) Day Immersion Test
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25 BIODEGRADATION TEST PROCEDURE St
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Date: WHC-SD-W100-TI-003 Rev. 0 BIO
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 STOCK EQU
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19 SCOPE AND APPLICATION WHC-SD-W10
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CHARACTERIZATION DATA Part A: Overv
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Grit Specie or MaterialOverall Cont
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WHC-SD-W100-TI-003 Rev. 0 The incin
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Page 189 and 190: J. L. Westcott Page 3 June 1, 1992
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Page 207 and 208: PHYSICAL DESCR/PTTON: V-r-S?-W100-T
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Page 249 and 250: Package #1: Package #2: WHC-SD-W100
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WHC-SD-W100-TI-003 Rev. 0 Russ Czel
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Stock Equipment Company 3:0 -SCFIED
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THERMAL CYCLING SAMPLES BEFORE THE
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