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Y:,Cse Basin 3 - Sludqe Sodium 31%Sulfate5% Nitrate 35%Fluoride2% Copper 15%Uraniumtrace Zirconium 12% Basin 3 - Crystals Sodium 62%Nitrate2% Sulfate 30%Uraniumslight trace Fluoride 6% Ba5 i n 4 - Sodium IJ;+^.^+.. 1.1 1 GLO Sulfate Sludae 38%Fiuoride2% 47%iiraPi i uiTitrace 13% Basin 4 - Crystals ;N`^ v>, Sodium Nitrate Copper Zirconium 38%Sulfate3% 35%Fluoride2% 16%Uraniumslight 6% trace Basin 2 - Sorbed Liauid WHC-SD-W100-TI-003 Rev. 0 The liquid and entrained solids was thought to be sorbed on to Sorbond LPC-II, a calcium type absorbent. The chemical content of the liquid is given below: Sodium 27%Uraniumtrace Nitrate 73%Technetiumslight trace possible Sand Blast Grit The grit is at least 90% grit, the balance being a mixture of basin salt, sludge, dirt and sand, and liner material. Wastes designated Grit 1 and Grit 2 constitute a large volume of drummed basin wastes at the present time. The grit wastes were generated from cleaning basins I and 4. Gr_it_1 wasamixturQ of_sand blast grit plus the residual basin sludge. Grit 2 was a mixture of sand blast grit plus basin 4 sludge. These wastes are top priority for WRAP 2A processing. The waste compositions and representative surrogate wastes composition procedure for cement based testing is given below: D-4
Grit Specie or MaterialOverall Content Sand Blast Grit 90% WHC-SD-W100-TI-003 Rev. 0 Basin I Sludgel0% • Sodium = 29% • Sulfate - 29% • Copper - 17% • Nitrate - 11% • Fluoride - 9% • Zirconium - 4% • Silica - 1% • Molybdenum - 0.05% (uranium stand-in) • Ruthenium - 0.05% (technetium stand-in) • Chromium VI - 0.05% Grit 2 : Soecie or Material0vera1l Content Sand Blast Grit90% Basin 4 Crysta110% • Sodium - 38% • Nitrate - 47% • Sulfate - 13% • Fluoride - 2% • Molybdenum - 0.05% (uranium stand-in) • Chromiur VI - 0.05% • Cobalt i: - 0.01% • Strontium II - 0.01% The basin sludge portion of the Grit 1 surrogate was produced by weighing the appropriate amount of copper metal powder and dissolving it in dilute nitric acid which provided the nitrate. Zirconium powder, sulfuric acid, and hydrofluoric was added and mixed with the liquid in the preceding sequence. Sodium carbonate was used to neutralize the liquid, and then the chemical tracer compounds were added. The final pH was adjusted to a neutral value with nitric acid and sodium carbonate as appropriate. The liquid was dried, -- mil_fied, cieved to =20 mesh,--and- blended p^rior to use. The basin crystal portion of Grit 2 surrogate waste was made by weighing and dissolving the appropriate proportions of sodium nitrate, sodium sulfate, sodium fluoride, and sodium carbonate in water. The trace compounds were also added and stirred into the mixture. The liquid was then dried, milled, sieved to -20 mesh, and blended prior to use. Some carbonate was added as a source of sodium. L-045 LETF (300 Area Process Sewer Treatment Sludge) i.y -The 300 Area, in the past, has typically generated in excess of a million gallons per day of process water. The process sewer stream is monitored D-5
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R 2.1 199^ ^.EN GINEERING DATA TRAN
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Date Received% • I INFORMATION RE
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. SUPPORTING DOCUMENT 1. Total Page
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WHC-SD-W100-TI-003 Rev. 0 EXECUTIVE
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WHC-SD-W100-TI-003 Rev. 0 been achi
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__ _ _ MHC-SIL-yJ3,00-TI-D03 Rev. 0
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F`= WHC-SD-W100-TI-003 Rev. 0 DESCR
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WHC-SD-W100-TI-003 Rev. 0 LIST OF T
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WHC-SD-W100-TI-003 Rev. 0 WASTE REC
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WHC-SD-W100-TI-003 Rev. 0 1.2.1 Fee
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^s. WHC-SD-W100-TI-003 Rev. 0 conta
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__-'°'2 WHC-SD-W100-TI-003 Rev. 0
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2.1 REGULATORY FRAMEWORK WHC-SD-W10
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^..." ;_:.. :.^ .^.y^ WHC-SD-W100-T
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WHC-SD-W100-TI-003 Rev. 0 which the
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kIHC-Sû-Wi"v"u-Ti-u03 Rev. V ,--,,
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WHC-SD-W100-TI-003 Rev. 0 Type 1 wa
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3.3 TESTING APPROACH WHC-SD-W100-TI
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^.: fi WNC-SD-W100-TI-003 Rev. 0 Fi
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4.1 SCREENING TEST RESULTS WHC-SD-W
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,^. ----- -- WHC-SD-W100-TI-003 Rev
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WHC-SD-W100-TI-003 Rev. 0 4.1.3 The
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p Sam le Compressive Radiation stre
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WHC-SD-W100-TI-003 Rev. 0 Table 4-3
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..., TESTING RESULTS .^.CSSD-W-1OO-
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A I w ^^',; ^^ ;J ?1Fasf^.}: "q -?
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;..;: .^:. WHC-SD-W100-TI-003 Rev.
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--- ....ti s..` WHC-SD-WI00-TI-003
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1.0 INTRODUCTION WHC-SD-W100-TI-003
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WHC-SD-W100-TI-003 Rev. 0 Waste For
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^-: -- ^ Component Waste Type 1 LET
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.^x. --1vHC-SD iii00- T i-003 Rev.
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WHC-SD-W: JV-TI-VVJ ^cv. v APPENDIX
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,..^ c:-- z ,.E ^=t ^^ln^l WHC-SD-W
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Scope WHC-SD-W100-TI-003 Rev. 0 Sup
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00 V F-' Activity and Miltstone Cha
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WHC-SD-W100-TI-003 Rev. 0 Laborator
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WHC-SD-WIOO-TI-003 Rev. 0 APPENDIX
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16490 Chiaccothe Itoad Chagrin Fall
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ca-. tY•^_E Q . - - StoGkE4uip+!n
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^.. WHC-SD-W100-TI-003 Rev. 0 . , I
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Waste Type: WHC-SD-W100-TI-003 Rev.
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Stock E quipment Company A Unit of
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G' ,.,. d,_ s WHC-0-W100-TI-003 Rev
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Cx U: r°... .• , .ti Waste Type:
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-. LeachantSolution: Specimen Diame
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c^1, WHC-SD-W100-TI-003 Rev. 0 THER
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..... lry" - Stock E a uipment Comp
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;=. .:^;. WHC-SD-W100-TI-003 Rev< 0
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(.7 ..^^ -„n f^. [Y^. Waste Type:
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Date: _ Leachability Time Point Lea
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23 Ninety ( 90) Day Immersion Test
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ty ,.. ='`F r...,, b Ly.. Specimen
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25 BIODEGRADATION TEST PROCEDURE St
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Date: WHC-SD-W100-TI-003 Rev. 0 BIO
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^_... ..^^ C:i1 Date: WHC-SD-W100-T
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Date: WHC-SD-W100-TI-003 Rev. 0 --
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f-^ -- WHC-SD-W100-TI-003 Rev. 0 2.
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^-..., 3•0 ASSAY FOR MEI'ALS 3.1
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t..f f....,.. P....^ .-- ^ : .^ ^-.
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Page 123 and 124: WHC-SD-W100-TI-003 Rev. 0 APPENDIX
Page 125 and 126: WHC-SD-W100-TI-003 Rev. 0 STOCK EQU
Page 127 and 128: 19 SCOPE AND APPLICATION WHC-SD-W10
Page 129 and 130: L:^3 ll Q. 4 AA :'ILTEP.S WHC-0-W10
Page 131 and 132: 4_T tJrD o,...Ys j ^,.,. WHC-SD-W10
Page 133 and 134: WHC-SD-W100-TI-003 Rev. 0 -, Proced
Page 135 and 136: WHC-SD-W100-TI-003 Rev. 0 Procedure
Page 137 and 138: (FM WHC-SD-W100-TI-003 Rev. 0 Proce
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Page 141 and 142: ^..., . ,.y^ h:.r WHC-SD-WI00-Ti-00
Page 143 and 144: :. WHC-SD-W100-TI-003 Rev. 0 TA3i.E
Page 145 and 146: ^' . WHC-SD-W100-T1-003 Rev. 0 TABL
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Page 149 and 150: c. 03 00 r=3 ^t C^' II 6.0 II Calib
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Page 153 and 154: R: C=1 rIj s^ ^ ^.. WHC-SD-YlI00-TI
Page 155 and 156: .,,_..1 ---^ - - i-•_E ?*^^ Mater
Page 157 and 158: WHC-SD-W100-TI-003 Rev. 0 Dow Chemi
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Page 161 and 162: WHC-S®-hi1.00-T'.-00?, Rev. Dow Ch
Page 163 and 164: t;7_7 ,...:: ----------- WHC-SD-W10
Page 165 and 166: WHC-SD-W100-TI-003 Rev. 0 Daw M.. u
Page 167 and 168: ^ ^..rYfl VF •UIYb 1 1 AGA GllS.
Page 169 and 170: WHC-SD-W100-TI-003 Rev. 0 APPENDIX
Page 171: CHARACTERIZATION DATA Part A: Overv
Page 175 and 176: WHC-SD-W100-TI-003 Rev. 0 The incin
Page 177 and 178: WHC-SD-W100-TI-003 Rev. 0 183-H BAS
Page 179 and 180: WHC-SD-W100-TI-003 Rev. 0 June - Se
Page 181 and 182: WHC-SD-W100-TI-003 Rev. 0 BASINS 3
Page 183 and 184: WHC-SD-W100-TI-003 Rev. 0 BASINS 3
Page 185 and 186: ^- WHC-SD-W100-TI-003 Rev. 0 BASIN
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Page 189 and 190: J. L. Westcott Page 3 June 1, 1992
Page 191 and 192: u...^^, WHC-SD-W100-TI-003 Rev. 0 I
Page 193 and 194: •N`^C-Sf1-"d100-71-003 Rev. 0 ,S'
Page 195 and 196: CONTAINER /NFORMATlO N: `d"-C-Sn-'w
Page 197 and 198: ONTANVER BVFORMA SI7 E: AMOUN=i 8 G
Page 199 and 200: LOT WRAP 2A.4 SHEET 7.XLS RECOMMEND
Page 201 and 202: LOT WRAP 2A.5 SHEET 8.XLS RECOMMEND
Page 203 and 204: .:•n-,,, LOT WRAP 2A.6 SHEET 9.XL
Page 205 and 206: LOT WRAP 2A.7 SHEET 10.XLS RECOMMEN
Page 207 and 208: PHYSICAL DESCR/PTTON: V-r-S?-W100-T
Page 209 and 210: ,.: Westinoause Harlford COMM WHC-S
Page 211 and 212: O I tA SHEETII.XLS ;, LOT WRAP2A.2
Page 213 and 214: CONTAINER /NFORMAT/ON: DOSE: SIZE:
Page 215 and 216: PU33-11-1992 09:48 FROM EDS/qRI$ir
Page 217 and 218: LOT WRAP 2A 10 Slf-EET 14.)C,S RECO
Page 219 and 220: qN i: 105N-89-1097 105N-89-1098 105
Page 221 and 222: SIZE: DOSE: 5 GAL 1 1@15 Mr 30 GAL
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WHC-SD-W100-TI-003 Rev. 0 Westtngho
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LOT WRAP A2.14 SHEET 18.XLS RECOMME
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---- - LOT WRAP ZA.13 SHEET 17.XLS
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n .-.^..-n..^^- .. ... .dJ. ^ ShIEE
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--^ WHC-SD-W100-TI-003 Rev. 0 APPEN
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WHC-SD-W100-TI-003 Rev. 0 Westingho
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Table 1 Candidate Waste Forms Absor
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--- -Aauaspt and Pe-liroset WHC-SD-
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- '^ - qev. r' Literature Search WR
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Dow Polymer WHC-SD-W100-TI-003 Rev.
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L im e Literature Search WRAP 2A Pa
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The report compares the 7eachabilit
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J. L. Westcott Page 2 May 29, 1992
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Package #1: Package #2: WHC-SD-W100
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WHC-SD-W100-TI-003 Rev. 0 SURVEY OF
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f ..;' WHC-SD-W100-TI-003 Rev. 0 A
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 Bibliogra
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WHC-SD-W100-TI-003 Rev. 0 A. P. Tos
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OAK R1DGE NATIONAL LABORATORY OPERA
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 A report
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WHC-SD-W100-TI-003 Rev. 0 impermeab
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WHC-SD-W100-TI-003 Rev. 0 reprocess
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WHC-SD-W100-TI-003 Rev. 0 STR?.THGI
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Contained under four reports: WHC-S
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^.yo F-SD-W"00-7-003 Rev. 0 THERMOS
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WHC-SD-W100-TI-003 Rev. 0 The techn
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loomi^^lC& 111111111111F .^^.\ West
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û9^c ?fi. ...^ .._-, WHC-SD-W100-T
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Stock Equipment Company WHC-SD-WI00
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^ i w STOCK EOUIPMENT COMPANY 14-OC
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\. . 1 .: lh,lf^ LEACH / IMMERSIONI
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^;- v.4'? Sampls ID L781 Elsment CO
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4.a
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Sanp)a ID L781 Elamant STRONTIUM Ma
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.^ "-; SampI81D L3B2 Z e"- ^.;;. Sa
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Sample 10 L3B1 Elsmant CESIUM Matri
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Sample ID W B1 Elemant STRONIIUM Ma
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Westinghouse Hanford Company 2355 S
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--- - ftCR-e4Uip1P1eFf Company WHC-
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WHC-SD-W100-TI-003 Rev. 0 Russ Czel
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Stock Equipment Company 3:0 -SCFIED
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THERMAL CYCLING SAMPLES BEFORE THE
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BIODEGRADATION SAMPLES BEFORE THE S
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C/ 0D OC M1 0, ^yII i..) d tl ^ a I
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T 1 A w ^ • $ ^py yf ; pp V ^ py
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0 > d C.) O O F- 0 0 3 G NI U 3 ^ c
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en a-. p g aQ i ^ rr it - l r rF e^
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' iO`F*'P\^ Westinghouse Hanford Co
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Stock Equipment Company 1.0 SUMMARY
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Stock Equipment Company WHC-SD-W100
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2a0 SCHEDULE Activitv - Prepare Wor
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T 1 o+ THERMAL CYCLWG SAMPLES BEFOR
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T 1 OI 80 70 U 60 VJ w 50 w 0 40 30
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^ °' cn l .:. U CD w a: w r' i ^ I
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SAMPLE ID Li-117 L1-118 L1-19 L3-17
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T °,w ^ - : C s 0 n a ^^ s ^ i ^-
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71 I V y,,} ^ • 5il i ^ ^^ ^ ^ ^
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0 a^ on O O M F- 1OCD 3 1 G N^ U il
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O > W C f.) O O 1-- ^ O HI 6./ 3 ^
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0 > ar oe M 0 c C3, I O c V 3 Î d
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TI V 40 IN s i s : s ^l l i " p p l
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 _QVrDvrru
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^-_- .,:... WHC-SD-W100-TI-003 Rev.
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Ceramics and glass WHC-SD-W200-TI-0
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,. ., Extruder/melter WHC-SD-W100-T
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