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WHC-SD-W100-TI-003 Rev. 0 metals, soluble salts, and reactive metals. TheAphysical characteristics range from semiliquid sludges and salt cake to dry powders, ash, soils, and contaminated debris. The wide variety of chemical and physical characteristics expected in WRAP 2A feedstreams precludes the use of a single immobilization technology for all waste types. The desire to minimize operating costs suggests the use of cement-based binders whenever possible. However, several feedstreams are known to be incompatible with cement-based materials, so a second technology is required. The objective of this approach is to provide two immobilization technologies that together can successfully treat all known and anticipated WRAP 2A feedstreams. The conceptual design of WRAP Module 2A thus includes two immobilization process trains: a cement-based grouting train and a vinyl ester styrene ,-; polymer train. Both systems provide the capability to mix binder and waste either-in the waste drum or use a vibratory mixing technique. Additionally, the design of the grout system includes the flexibility to allow use of multiple formulations of inorganic binders, ( i.e., portland cement, slag cement, or gypsum cement). The available combination of technologies is --; expected to be able to successfully treat all WRAP 2A feeds. 2.3 TEST SELECTION AND ACCEPTANCE CRITERIA The WRAP 2A waste forms are subject to rules and regulations promulgated by several entities. Primary performance requirements are described in U.S. Environmental Protection Agency (EPA) regulations, Washington Administrative Code, and DOE orders. Other applicable guidance comes from the <strong>Hanford</strong> <strong>Site</strong> So1id Waste Acceptance Criteria (WHC 1991) and U.S. Nuclear Aegul-atoryû^t,sîc^t (NRC) re-yulations. Since there is no single regulation or guidance document that contains all applicable performance requirements and some discrepancies exist between similar requirements in different regulations, the WRAP 2A WFQ program has developed project-specific waste form performance specifications that ensure that waste forms that meet the specifications will also be compliant with all applicable regulatory requirements and guidance documents. The WRAP 2A waste form performance soer;fications- are-summartzed in-?abl-s--2-I: The following sections describe aV- -- -- -- -- the t..^$ a_lf^r"lan re£}S.S _&pe^. } . fl . ^ f3r WD11D "n ....`t ° r.,"__ : a^.,,r Gn wa^6e r^ruu in uL d. all 2.3.1 Compressive Strength T!}e-neaszrement of the compressive strength is the key method of determining the stability and structural integrity of the waste form. The need for adequate compressive strength is a result of the desire to control subsidence in the disposal grounds, thus requiring the waste form to be able to withstand the full pressure of the overburden after it is buried. The most stringent compressive strength requirements are based on NRC requirements in 10 CFR 61 (NRC 1992) for shallow land disposal of Class B and Class C LLW. There are presently two NRC standards, depending on the nature of the matrix. For cementitious matrices, the minimum acceptable compressive 2-2
^..." ;_:.. :.^ .^.y^ WHC-SD-W100-TI-003 Rev. 0 Table 2-1. WRAP 2A Waste Form Performance Specifications. Waste form characteristic Test method Acceptance criteria Compressive strength orTASTMM 5 Strength >500 lbf/in2 Leachability index ANS 16.1 Leach Index >6 Biodegradation ASTM G21 and ASTM D695 or ASTM C39 G22, Thermal cycling Radiation stability Immersion No growth, Strength >500 lbf/in 2 ASTM ASTM D695, Strength >500 lbf/inZ after 30 thermal cycles or ASTM C39 ASTM D695 Strength >500 lbfjinz after or ASTM C39 irradiation to 10 rad ASTM 0695 Strength >500 lbf/in 2 after or ASTM C39 90-day water immersion Free liquids ANS 55.1 Free liquid
Page 1 and 2: R 2.1 199^ ^.EN GINEERING DATA TRAN
Page 3 and 4: Date Received% • I INFORMATION RE
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Page 7 and 8: WHC-SD-W100-TI-003 Rev. 0 EXECUTIVE
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Page 17 and 18: WHC-SD-W100-TI-003 Rev. 0 WASTE REC
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Page 49 and 50: ..., TESTING RESULTS .^.CSSD-W-1OO-
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Page 57 and 58: 1.0 INTRODUCTION WHC-SD-W100-TI-003
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Page 65 and 66: WHC-SD-W: JV-TI-VVJ ^cv. v APPENDIX
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Page 69 and 70: Scope WHC-SD-W100-TI-003 Rev. 0 Sup
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Page 73 and 74: WHC-SD-W100-TI-003 Rev. 0 Laborator
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16490 Chiaccothe Itoad Chagrin Fall
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ca-. tY•^_E Q . - - StoGkE4uip+!n
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^.. WHC-SD-W100-TI-003 Rev. 0 . , I
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Waste Type: WHC-SD-W100-TI-003 Rev.
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Stock E quipment Company A Unit of
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G' ,.,. d,_ s WHC-0-W100-TI-003 Rev
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Cx U: r°... .• , .ti Waste Type:
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-. LeachantSolution: Specimen Diame
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c^1, WHC-SD-W100-TI-003 Rev. 0 THER
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..... lry" - Stock E a uipment Comp
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;=. .:^;. WHC-SD-W100-TI-003 Rev< 0
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(.7 ..^^ -„n f^. [Y^. Waste Type:
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Date: _ Leachability Time Point Lea
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23 Ninety ( 90) Day Immersion Test
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ty ,.. ='`F r...,, b Ly.. Specimen
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25 BIODEGRADATION TEST PROCEDURE St
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Date: WHC-SD-W100-TI-003 Rev. 0 BIO
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^_... ..^^ C:i1 Date: WHC-SD-W100-T
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Date: WHC-SD-W100-TI-003 Rev. 0 --
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f-^ -- WHC-SD-W100-TI-003 Rev. 0 2.
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^-..., 3•0 ASSAY FOR MEI'ALS 3.1
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 STOCK EQU
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19 SCOPE AND APPLICATION WHC-SD-W10
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L:^3 ll Q. 4 AA :'ILTEP.S WHC-0-W10
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4_T tJrD o,...Ys j ^,.,. WHC-SD-W10
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WHC-SD-W100-TI-003 Rev. 0 -, Proced
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WHC-SD-W100-TI-003 Rev. 0 Procedure
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(FM WHC-SD-W100-TI-003 Rev. 0 Proce
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C... 6 Wet Waste Sample Contains no
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WHC-SD-W100-TI-003 Rev. 0 Dow Chemi
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WHC-SD-W100-TI-003 Rev. 0 Daw M.. u
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CHARACTERIZATION DATA Part A: Overv
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Grit Specie or MaterialOverall Cont
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WHC-SD-W100-TI-003 Rev. 0 The incin
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WHC-SD-W100-TI-003 Rev. 0 183-H BAS
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WHC-SD-W100-TI-003 Rev. 0 June - Se
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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WHC-SD-W100-TI-003 Rev. 0 ---------
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J. L. Westcott Page 3 June 1, 1992
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•N`^C-Sf1-"d100-71-003 Rev. 0 ,S'
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CONTAINER /NFORMATlO N: `d"-C-Sn-'w
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ONTANVER BVFORMA SI7 E: AMOUN=i 8 G
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LOT WRAP 2A.4 SHEET 7.XLS RECOMMEND
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LOT WRAP 2A.5 SHEET 8.XLS RECOMMEND
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.:•n-,,, LOT WRAP 2A.6 SHEET 9.XL
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LOT WRAP 2A.7 SHEET 10.XLS RECOMMEN
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PHYSICAL DESCR/PTTON: V-r-S?-W100-T
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,.: Westinoause Harlford COMM WHC-S
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O I tA SHEETII.XLS ;, LOT WRAP2A.2
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CONTAINER /NFORMAT/ON: DOSE: SIZE:
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PU33-11-1992 09:48 FROM EDS/qRI$ir
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LOT WRAP 2A 10 Slf-EET 14.)C,S RECO
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qN i: 105N-89-1097 105N-89-1098 105
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SIZE: DOSE: 5 GAL 1 1@15 Mr 30 GAL
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WHC-SD-W100-TI-003 Rev. 0 Westtngho
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LOT WRAP A2.14 SHEET 18.XLS RECOMME
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---- - LOT WRAP ZA.13 SHEET 17.XLS
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--^ WHC-SD-W100-TI-003 Rev. 0 APPEN
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WHC-SD-W100-TI-003 Rev. 0 Westingho
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Table 1 Candidate Waste Forms Absor
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--- -Aauaspt and Pe-liroset WHC-SD-
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- '^ - qev. r' Literature Search WR
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Dow Polymer WHC-SD-W100-TI-003 Rev.
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L im e Literature Search WRAP 2A Pa
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The report compares the 7eachabilit
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J. L. Westcott Page 2 May 29, 1992
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Package #1: Package #2: WHC-SD-W100
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WHC-SD-W100-TI-003 Rev. 0 SURVEY OF
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f ..;' WHC-SD-W100-TI-003 Rev. 0 A
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 Bibliogra
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WHC-SD-W100-TI-003 Rev. 0 A. P. Tos
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OAK R1DGE NATIONAL LABORATORY OPERA
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 A report
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WHC-SD-W100-TI-003 Rev. 0 impermeab
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WHC-SD-W100-TI-003 Rev. 0 reprocess
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WHC-SD-W100-TI-003 Rev. 0 STR?.THGI
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Contained under four reports: WHC-S
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^.yo F-SD-W"00-7-003 Rev. 0 THERMOS
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WHC-SD-W100-TI-003 Rev. 0 The techn
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Stock Equipment Company WHC-SD-WI00
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^ i w STOCK EOUIPMENT COMPANY 14-OC
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\. . 1 .: lh,lf^ LEACH / IMMERSIONI
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4.a
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Sanp)a ID L781 Elamant STRONTIUM Ma
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Sample 10 L3B1 Elsmant CESIUM Matri
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Sample ID W B1 Elemant STRONIIUM Ma
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Westinghouse Hanford Company 2355 S
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--- - ftCR-e4Uip1P1eFf Company WHC-
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WHC-SD-W100-TI-003 Rev. 0 Russ Czel
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Stock Equipment Company 3:0 -SCFIED
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THERMAL CYCLING SAMPLES BEFORE THE
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BIODEGRADATION SAMPLES BEFORE THE S
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Stock Equipment Company 1.0 SUMMARY
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Stock Equipment Company WHC-SD-W100
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2a0 SCHEDULE Activitv - Prepare Wor
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WHC-SD-W100-TI-003 Rev. 0 _QVrDvrru
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Ceramics and glass WHC-SD-W200-TI-0
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,. ., Extruder/melter WHC-SD-W100-T
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