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.^( SPECIMEN PREPARATION WHC-SD-W100-TI-003 Rev. 0 STOCK EQUIPMENT COMPANY 10 CFR 61 WASTE FORM VERIFICATION PROGRAM 1.1 LAB SCALE, ONE (1) GALLON SPECIMENS 1.1.1 Specimen Preparation PROCEDURE 90110-0 Lab scale, one (1) gallon size specimens, will be prepared for this testing program. The three (3) groups of specimens prepared for testing are listed in Table 13. Table 1.1 • Labels, One (1) Gallon Specimen Group I Polymer Control Group II Waste Stream Without Co, Sr, Cs Group III Waste Stream With Co. Sr, Cs Control Ll - - Waste Number 1 - L2 L3 Waste Number 2 - LA IS Waste Number 3 - L6 L7 Waste Number 4 - L8 L9 The waste streams listed containing Co, Sr, Cs (Group III), will have between 0.20 and 0.25 weight percent (of the total solidification) as metal, added to them, The three (3) metal salts that will be added to each of the waste streams listed in Group III are: Co (as CoCL2 • 6H20) ACS Reagent Grade, Sr (as SrCL2 • 61-120) ACS Rea,ent Grade, and Cs (as CsCL) ACS Reagent Grade. Mixing of the waste streams and polymer will be accomplished using a high shear energy mi;ting technique. Stock Eauipment Companv C-6 A Unit of General Signal ^mm 9199-5n•9^96 Pagc = of
^.. WHC-SD-W100-TI-003 Rev. 0 . , I PROCEDURE 90110-0 i 1.1.2 Sample Tube Insertion Tubes with the nominal dimensions of 1-7/16' I.D. and two inches (2') s 1/4' in length will be made. Maximum departure from perpendicularity to the as;s by either end: 1.0 degree. Maximum out of plane allowance for ends; 0.025 inch. After the specimens have been cast, the test specimens will be sealed and allowed to remain undisturbed for a seven (7) day period to permit the polymer/waste mixture to cure. At the end of the curing period, each specimen will be opened and the core tube removed. Labeling will be accomplished using the procedure with the exception that each specimen is not directly labeled, but placed in a prelabeled, sealed container. For example, the second specimen from the tube of specimen LZ will carry a label LZA2 on the container. Six (6) specimens obtained from each solidification, three (3) will be leached in distilled water and three (3) will be leached in synthetic sea water (per ANSI 16.1 and Section 2.2). All six ( 6) samples per specimen will be used for the ninety (90) day immersion test (Section 2.3). 1.13 Mibng of the waste streams and polymer will be accomplished using a high shear energy mixing technique. In preparing for the solidification, the polymer will be mixed. This is done to minimiz e introduction of a random variable into any solidification. The surrogated waste will be mixed to minimize introduction of a random variable into any solidification. All components will be preweighed prior to the start of solidi5cation. 1.1.4 Specimen Cast Preparation After mixdttg of all the components, the polymer/waste mixture will be poured into the tubes. All the specimens generated will be covered and allowed to cure for seven (7) days. The remainder of the polymer/waste mixnue will be used to obtain a esothertn profile and to determine Free L'quids ( Section 2.7). Table 1.1a Test Description Test Procedure Section Number Samples Required Compressive Strength 2.1 Biodegradation 2.5 3 Radiation 2.6 3 Tnermai Cycie Degradation Stock cquipment Company A Unit of General Signal ImT W!-SDAIN C-7 zi 3 Page 4 of 3?
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R 2.1 199^ ^.EN GINEERING DATA TRAN
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Date Received% • I INFORMATION RE
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. SUPPORTING DOCUMENT 1. Total Page
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WHC-SD-W100-TI-003 Rev. 0 EXECUTIVE
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WHC-SD-W100-TI-003 Rev. 0 been achi
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F`= WHC-SD-W100-TI-003 Rev. 0 DESCR
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WHC-SD-W100-TI-003 Rev. 0 LIST OF T
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WHC-SD-W100-TI-003 Rev. 0 WASTE REC
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WHC-SD-W100-TI-003 Rev. 0 1.2.1 Fee
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^s. WHC-SD-W100-TI-003 Rev. 0 conta
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__-'°'2 WHC-SD-W100-TI-003 Rev. 0
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2.1 REGULATORY FRAMEWORK WHC-SD-W10
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^..." ;_:.. :.^ .^.y^ WHC-SD-W100-T
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Page 57 and 58: 1.0 INTRODUCTION WHC-SD-W100-TI-003
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Page 69 and 70: Scope WHC-SD-W100-TI-003 Rev. 0 Sup
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Page 73 and 74: WHC-SD-W100-TI-003 Rev. 0 Laborator
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Page 77 and 78: 16490 Chiaccothe Itoad Chagrin Fall
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Page 125 and 126: WHC-SD-W100-TI-003 Rev. 0 STOCK EQU
Page 127 and 128: 19 SCOPE AND APPLICATION WHC-SD-W10
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4_T tJrD o,...Ys j ^,.,. WHC-SD-W10
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WHC-SD-W100-TI-003 Rev. 0 -, Proced
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WHC-SD-W100-TI-003 Rev. 0 Procedure
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(FM WHC-SD-W100-TI-003 Rev. 0 Proce
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C... 6 Wet Waste Sample Contains no
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^..., . ,.y^ h:.r WHC-SD-WI00-Ti-00
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:. WHC-SD-W100-TI-003 Rev. 0 TA3i.E
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^' . WHC-SD-W100-T1-003 Rev. 0 TABL
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^- ^-> ^ C^Jl I I^t ^.: l WHC-St]-W
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c. 03 00 r=3 ^t C^' II 6.0 II Calib
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LY; ^ C=l . ^.^ .^,..,, €:^. MHC-
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R: C=1 rIj s^ ^ ^.. WHC-SD-YlI00-TI
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.,,_..1 ---^ - - i-•_E ?*^^ Mater
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WHC-SD-W100-TI-003 Rev. 0 Dow Chemi
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^ ±.£:a [7.p -;^ --- --------- WH
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WHC-S®-hi1.00-T'.-00?, Rev. Dow Ch
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t;7_7 ,...:: ----------- WHC-SD-W10
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WHC-SD-W100-TI-003 Rev. 0 Daw M.. u
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^ ^..rYfl VF •UIYb 1 1 AGA GllS.
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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CHARACTERIZATION DATA Part A: Overv
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Grit Specie or MaterialOverall Cont
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WHC-SD-W100-TI-003 Rev. 0 The incin
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WHC-SD-W100-TI-003 Rev. 0 183-H BAS
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WHC-SD-W100-TI-003 Rev. 0 June - Se
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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^- WHC-SD-W100-TI-003 Rev. 0 BASIN
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WHC-SD-W100-TI-003 Rev. 0 ---------
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J. L. Westcott Page 3 June 1, 1992
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u...^^, WHC-SD-W100-TI-003 Rev. 0 I
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•N`^C-Sf1-"d100-71-003 Rev. 0 ,S'
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CONTAINER /NFORMATlO N: `d"-C-Sn-'w
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ONTANVER BVFORMA SI7 E: AMOUN=i 8 G
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LOT WRAP 2A.4 SHEET 7.XLS RECOMMEND
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LOT WRAP 2A.5 SHEET 8.XLS RECOMMEND
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.:•n-,,, LOT WRAP 2A.6 SHEET 9.XL
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LOT WRAP 2A.7 SHEET 10.XLS RECOMMEN
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PHYSICAL DESCR/PTTON: V-r-S?-W100-T
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,.: Westinoause Harlford COMM WHC-S
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O I tA SHEETII.XLS ;, LOT WRAP2A.2
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CONTAINER /NFORMAT/ON: DOSE: SIZE:
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PU33-11-1992 09:48 FROM EDS/qRI$ir
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LOT WRAP 2A 10 Slf-EET 14.)C,S RECO
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qN i: 105N-89-1097 105N-89-1098 105
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SIZE: DOSE: 5 GAL 1 1@15 Mr 30 GAL
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WHC-SD-W100-TI-003 Rev. 0 Westtngho
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LOT WRAP A2.14 SHEET 18.XLS RECOMME
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---- - LOT WRAP ZA.13 SHEET 17.XLS
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n .-.^..-n..^^- .. ... .dJ. ^ ShIEE
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--^ WHC-SD-W100-TI-003 Rev. 0 APPEN
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WHC-SD-W100-TI-003 Rev. 0 Westingho
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Table 1 Candidate Waste Forms Absor
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--- -Aauaspt and Pe-liroset WHC-SD-
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- '^ - qev. r' Literature Search WR
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Dow Polymer WHC-SD-W100-TI-003 Rev.
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L im e Literature Search WRAP 2A Pa
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The report compares the 7eachabilit
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J. L. Westcott Page 2 May 29, 1992
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Package #1: Package #2: WHC-SD-W100
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WHC-SD-W100-TI-003 Rev. 0 SURVEY OF
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f ..;' WHC-SD-W100-TI-003 Rev. 0 A
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WHC-SD-W100-TI-003 Revo 0 Bibliogra
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OAK R1DGE NATIONAL LABORATORY OPERA
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 A report
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WHC-SD-W100-TI-003 Rev. 0 impermeab
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WHC-SD-W100-TI-003 Rev. 0 reprocess
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WHC-SD-W100-TI-003 Rev. 0 STR?.THGI
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Contained under four reports: WHC-S
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^.yo F-SD-W"00-7-003 Rev. 0 THERMOS
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WHC-SD-W100-TI-003 Rev. 0 The techn
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loomi^^lC& 111111111111F .^^.\ West
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û9^c ?fi. ...^ .._-, WHC-SD-W100-T
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Stock Equipment Company WHC-SD-WI00
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^ i w STOCK EOUIPMENT COMPANY 14-OC
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\. . 1 .: lh,lf^ LEACH / IMMERSIONI
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^;- v.4'? Sampls ID L781 Elsment CO
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4.a
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Sanp)a ID L781 Elamant STRONTIUM Ma
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.^ "-; SampI81D L3B2 Z e"- ^.;;. Sa
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Sample 10 L3B1 Elsmant CESIUM Matri
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Sample ID W B1 Elemant STRONIIUM Ma
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Westinghouse Hanford Company 2355 S
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--- - ftCR-e4Uip1P1eFf Company WHC-
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WHC-SD-W100-TI-003 Rev. 0 Russ Czel
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Stock Equipment Company 3:0 -SCFIED
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THERMAL CYCLING SAMPLES BEFORE THE
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BIODEGRADATION SAMPLES BEFORE THE S
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C/ 0D OC M1 0, ^yII i..) d tl ^ a I
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T 1 A w ^ • $ ^py yf ; pp V ^ py
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T 1 A ^ !^^ + ^ i •^^w^:rwwwwrpR^
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en a-. p g aQ i ^ rr it - l r rF e^
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' iO`F*'P\^ Westinghouse Hanford Co
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Stock Equipment Company 1.0 SUMMARY
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Stock Equipment Company WHC-SD-W100
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2a0 SCHEDULE Activitv - Prepare Wor
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T 1 o+ THERMAL CYCLWG SAMPLES BEFOR
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T 1 OI 80 70 U 60 VJ w 50 w 0 40 30
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^ °' cn l .:. U CD w a: w r' i ^ I
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SAMPLE ID Li-117 L1-118 L1-19 L3-17
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T °,w ^ - : C s 0 n a ^^ s ^ i ^-
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71 I V y,,} ^ • 5il i ^ ^^ ^ ^ ^
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0 a^ on O O M F- 1OCD 3 1 G N^ U il
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O > W C f.) O O 1-- ^ O HI 6./ 3 ^
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0 > ar oe M 0 c C3, I O c V 3 Î d
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TI V 40 IN s i s : s ^l l i " p p l
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 _QVrDvrru
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^-_- .,:... WHC-SD-W100-TI-003 Rev.
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Ceramics and glass WHC-SD-W200-TI-0
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,. ., Extruder/melter WHC-SD-W100-T
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