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Waste source Waste type Sorbomd' liquids Sodium nitrate Table 1-2. WRAP 2A Design Ba sis Summary. ilajor chemical species Projected total o f concern i nven or (ft) ®® Anhual Annual feed Treatment th production `f 1put l, process outpu t (drums) 183-H Solar Evaporation Crysta!lline solibds Sodium sulfate 87,912 3,525 Polymer 999 Basins (in storage) Sludge ---- ^---_...---- Miscel---l-ane--ous cleanup Copper sulfate! ----------------- ------------ Contaminated debris ------------ 9,471 ---°-------- 385 ------- - Grout ---------- 53 C-018 evaporator salt cake Ammonium sulfate Liquid Effluent Treatment Ion exchange resins Nitrates and 277,000 12,600 Pol;ymer 3,288 Facilities (forecast) ------- ----------------- L-045 metal sludge radionuclides ------------------------------ Heavy metal hydroxides RO filter elements Contaminated debris Dry active waste Operations fins orectorage Construction debris and ast) ---- -- --------- --- -- Metal wastês - ---------- -••--- ----- Absorbed chemicals Thermal Treatment Facility Incinerator ash (forecast) ----------------- Retrieval (forecast) --------------------- Contaminated soils ------------ -------------- ------ ---- --------- 75,000 3,400 Grout 873 Contaminated debris 65,100 3,255 Grout 443 _ - ^----` ------------------- ---- ---- 2 ------------ Lead, mercury, reactives 21,500 Warie;z ol rmer Varies ----------------------------- - ------------ --------- --_ ------------ - Inorganics and heavy 34,000 1,701) metals Polymer - ------- '-_-_- 495 Heavy metals 59,600 2,980 Grout 809 'Sorbond is a trademark of American Colloid Company. zMetal waste is campaigned. Throughput varies with campaign length and waste volume. r.. ;? x y E 0 _i 5• 00w m < 0
2.1 REGULATORY FRAMEWORK WHC-SD-W100-TI-003 Rev. 0 2."0 WASTE FORM PERFORMANCE SPECIFICATIONS The purpose of WRAP 2A is to manage CH-MLLW by treating it in such a way as to produce a final waste form that meets all applicable, relevant, and appropriate regulations and ensures its suitability for land disposal in the mixed waste disposal trench at the Hanford Site. The regulations that apply to radioactive mixed waste (RMW) come from three main sources. 2.1.1 Federal Regulations The federal regulations regarding disposal of RMW can be divided into two categories. The first set of regulations is concerned with the radioactive c^ portion of the waste and is embodied in 10 CFR 61 (NRC 1992). These regulations establish technical requirements for the land disposal of tommrrcial l-ow-levei waste, including site selection, site design, facility operation, and closure. Although not legally required, these regulations have y== been used for guiaance. The second set of regulations was promulgated after passage of the Resource Conservation and Recovery Act of 1976 (RCRA) and is >y, concerned with the chemical hazards of the waste, embodied in 40 CFR 261-268 (EPA 1992). These regulations establish minimum standards for packaging, labeling, record keeping, and reporting for all generators, transporters, owners, and operators of hazardous waste treatment, storage, and disposal facilities. They also impose restrictions on land disposal of hazardous waste and identify acceptable treatment technologies that can be used to meet the land disposal restrictions. 2.2.2 State of Washington The State of Washington has established regulations that are applicable to RMW through the Washington Administrative Code, WAC-173-303. These regulations overlap the federal RCRA regulations but include some additional requirements for management of dangerous and hazardous wastes. 2.2.3 Hanford Site Solid Waste Acceptance Criteria The Hanford Site Solid Waste Acceptance Criteria, WHC-EP-0063-3 (WHC 1991), includes additional reporting requirements and limitations on radionuclide content of low-level waste ( LLW) and RMW to be disposed of at the Hanford Site. These requirements are based on U.S. Department of Energy (DOE) Orders 5820.2A ( DOE 1988) and 5400.3 ( DOE 1989) and will include requirements -------- -- imposed-by--performance-assessments of the disposai grounds. 2.2 PROGRAMMATIC AND FUNCTIONAL REQUIREMENTS The WRAP 2A Facility will serve to treat all inorganic CH-MLLW received by the Hanford Central Waste Complex. Major waste streams that have been identified for treatment in WRAP 2A contain oxidizers, corrosives, toxic heavy 2-1
Page 1 and 2: R 2.1 199^ ^.EN GINEERING DATA TRAN
Page 3 and 4: Date Received% • I INFORMATION RE
Page 5 and 6: . SUPPORTING DOCUMENT 1. Total Page
Page 7 and 8: WHC-SD-W100-TI-003 Rev. 0 EXECUTIVE
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Page 17 and 18: WHC-SD-W100-TI-003 Rev. 0 WASTE REC
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Page 47 and 48: WHC-SD-W100-TI-003 Rev. 0 Table 4-3
Page 49 and 50: ..., TESTING RESULTS .^.CSSD-W-1OO-
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Page 57 and 58: 1.0 INTRODUCTION WHC-SD-W100-TI-003
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Page 69 and 70: Scope WHC-SD-W100-TI-003 Rev. 0 Sup
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WHC-SD-WIOO-TI-003 Rev. 0 APPENDIX
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16490 Chiaccothe Itoad Chagrin Fall
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ca-. tY•^_E Q . - - StoGkE4uip+!n
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Waste Type: WHC-SD-W100-TI-003 Rev.
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Stock E quipment Company A Unit of
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G' ,.,. d,_ s WHC-0-W100-TI-003 Rev
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Cx U: r°... .• , .ti Waste Type:
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-. LeachantSolution: Specimen Diame
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c^1, WHC-SD-W100-TI-003 Rev. 0 THER
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;=. .:^;. WHC-SD-W100-TI-003 Rev< 0
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Date: _ Leachability Time Point Lea
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23 Ninety ( 90) Day Immersion Test
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ty ,.. ='`F r...,, b Ly.. Specimen
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25 BIODEGRADATION TEST PROCEDURE St
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Date: WHC-SD-W100-TI-003 Rev. 0 BIO
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^_... ..^^ C:i1 Date: WHC-SD-W100-T
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Date: WHC-SD-W100-TI-003 Rev. 0 --
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f-^ -- WHC-SD-W100-TI-003 Rev. 0 2.
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^-..., 3•0 ASSAY FOR MEI'ALS 3.1
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 STOCK EQU
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19 SCOPE AND APPLICATION WHC-SD-W10
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L:^3 ll Q. 4 AA :'ILTEP.S WHC-0-W10
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4_T tJrD o,...Ys j ^,.,. WHC-SD-W10
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WHC-SD-W100-TI-003 Rev. 0 -, Proced
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WHC-SD-W100-TI-003 Rev. 0 Procedure
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(FM WHC-SD-W100-TI-003 Rev. 0 Proce
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C... 6 Wet Waste Sample Contains no
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^' . WHC-SD-W100-T1-003 Rev. 0 TABL
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WHC-SD-W100-TI-003 Rev. 0 Dow Chemi
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WHC-SD-W100-TI-003 Rev. 0 Daw M.. u
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CHARACTERIZATION DATA Part A: Overv
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Grit Specie or MaterialOverall Cont
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WHC-SD-W100-TI-003 Rev. 0 The incin
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WHC-SD-W100-TI-003 Rev. 0 183-H BAS
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WHC-SD-W100-TI-003 Rev. 0 June - Se
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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WHC-SD-W100-TI-003 Rev. 0 ---------
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J. L. Westcott Page 3 June 1, 1992
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•N`^C-Sf1-"d100-71-003 Rev. 0 ,S'
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CONTAINER /NFORMATlO N: `d"-C-Sn-'w
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ONTANVER BVFORMA SI7 E: AMOUN=i 8 G
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LOT WRAP 2A.4 SHEET 7.XLS RECOMMEND
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LOT WRAP 2A.5 SHEET 8.XLS RECOMMEND
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.:•n-,,, LOT WRAP 2A.6 SHEET 9.XL
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LOT WRAP 2A.7 SHEET 10.XLS RECOMMEN
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PHYSICAL DESCR/PTTON: V-r-S?-W100-T
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,.: Westinoause Harlford COMM WHC-S
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O I tA SHEETII.XLS ;, LOT WRAP2A.2
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CONTAINER /NFORMAT/ON: DOSE: SIZE:
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PU33-11-1992 09:48 FROM EDS/qRI$ir
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LOT WRAP 2A 10 Slf-EET 14.)C,S RECO
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qN i: 105N-89-1097 105N-89-1098 105
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SIZE: DOSE: 5 GAL 1 1@15 Mr 30 GAL
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WHC-SD-W100-TI-003 Rev. 0 Westtngho
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LOT WRAP A2.14 SHEET 18.XLS RECOMME
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---- - LOT WRAP ZA.13 SHEET 17.XLS
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--^ WHC-SD-W100-TI-003 Rev. 0 APPEN
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WHC-SD-W100-TI-003 Rev. 0 Westingho
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Table 1 Candidate Waste Forms Absor
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--- -Aauaspt and Pe-liroset WHC-SD-
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- '^ - qev. r' Literature Search WR
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Dow Polymer WHC-SD-W100-TI-003 Rev.
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L im e Literature Search WRAP 2A Pa
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The report compares the 7eachabilit
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J. L. Westcott Page 2 May 29, 1992
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Package #1: Package #2: WHC-SD-W100
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WHC-SD-W100-TI-003 Rev. 0 SURVEY OF
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 Bibliogra
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WHC-SD-W100-TI-003 Rev. 0 A. P. Tos
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OAK R1DGE NATIONAL LABORATORY OPERA
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WHC-SD-W100-TI-003 Revo 0 A report
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WHC-SD-W100-TI-003 Rev. 0 reprocess
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WHC-SD-W100-TI-003 Rev. 0 STR?.THGI
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Contained under four reports: WHC-S
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^.yo F-SD-W"00-7-003 Rev. 0 THERMOS
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WHC-SD-W100-TI-003 Rev. 0 The techn
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Stock Equipment Company WHC-SD-WI00
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Sample 10 L3B1 Elsmant CESIUM Matri
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Sample ID W B1 Elemant STRONIIUM Ma
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Westinghouse Hanford Company 2355 S
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--- - ftCR-e4Uip1P1eFf Company WHC-
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WHC-SD-W100-TI-003 Rev. 0 Russ Czel
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Stock Equipment Company 3:0 -SCFIED
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THERMAL CYCLING SAMPLES BEFORE THE
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BIODEGRADATION SAMPLES BEFORE THE S
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Stock Equipment Company 1.0 SUMMARY
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Stock Equipment Company WHC-SD-W100
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2a0 SCHEDULE Activitv - Prepare Wor
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