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J. L. Westcott Page 2 June 1, 1992 3. Basin 1- Sorbed Liquid WHC-SD-W100-TI-003 Rev. 0 CPE-WOG-002 The liquid, wet sludge, and crystalline material was removed and sorbed ---------- anzo--px-0bably--a-di-ato„aceous earth absorbent. The liquid fraction was probably mostly sodium nitrate, possibly some sodium sulfate, with a -s ight ^raEe :^, .__^-_.:.._ of i:raffTUnt an u"55y ue^nneum. 4. Basin 2 - Sludge Copper ^coro now Nitrate 30% ^:__-_:.._m circoniu Silicon ^ 6% 4% Sodium 21% Fluoride 2% Sulfate 9% Uranium trace S. Basin 3 - Sludge Sodium 31% Sulfate 5% Nitrate 35% Fluoride 2% Copper 15% Uranium trace Zirconium 12% 6. Basin 3 - Salt Sodium 62% Sulfate 30% Fluoride 6% 7. Basin 4 - Sludge Nitrate 2% Uranium slight trace Sodium 38% Fluoride 2% Nitrate 47% Uranium trace Sulfate 13% 8. Basin 4 - Salt Sodium 38% Sulfate 3% Nitrate 35% Fluoride 2% Copper 16% Uranium slight trace Zirconium 6% 9. Basin 2 - Sorbed Liquid The liquid and entrained solids was thought to be sorbed on to Sorbond LPC-II, a calcium type absorbent. The chemical content of the liquid is given below: Sodium 27% Uranium trace Nitrate 73% Technetium slight trace possible D-20 'i
J. L. Westcott Page 3 June 1, 1992 10. Sand Blast Grit WHC-SD-W100-TI-003 Rev. 0 CPE-WOG-002 The grit is expected to be at least 90% grit, the balance being a mixture of basin salt, sludge, dirt and sand, and liner material. This is not expected to be designated hazardous from the contents, but if designated it would probably be by association. 11. C-018 LETF Facility ( Stabilized Distillate Residue) Ammonium Sulfate (in dry form) > 95% Volatile Radionuclides - Trace levels 12. C-018 LETF Facility Spent ion exchange resin 13. C-045 LETF Facility (300 Area Process Sewer Treatment) Ferric Hydroxide Sludge ( on Occasion) 14. C-045 LETF Facility Spent ion exchange resin (Duolite) - on Occasion 15. LLMW Incineration or Destruction Facility Ash Residue RECDMMEnDATIUnS _The-foll3wing recommended methods will made and the appropriate waste forms tested in the laboratory: A. Cement is recommended and will be tested on the basin wastes numbered 1 through 10. Slag cement appears from the literature search to provide the best waste product performance in regards to leachability and EPA toxicity testing. Therefore, it is the prime candidate; however, portland cement type I-II, or type III will be used as back-up if any of the basin mixes appear to yield a poor product with slag cement. In addition, a cement modifier suggested by E. W. McDaniel of ORNL will be obtained and tested for its ability to increase retention of salt materials such as nitrates. B. Gypsum cement is recommended for ammonium sulfate listed as waste no. 11. Slag and portland cements exhibit strongly basic slurries in the mixing stage, this would release ammonia gas. Gypsum cement however is neutral during mixing and stabilizes the ammonium sulfate in the ammonium ion form. Laboratory screening experiments will be used to determine whether plaster of paris or a modified gypsum cement is used. Gypsum cement can be handled in the same type equipment as slag cement if the set is retarded. Either a slow setting material or a retarder will be added to provide a reasonable set time. D-21
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R 2.1 199^ ^.EN GINEERING DATA TRAN
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Date Received% • I INFORMATION RE
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. SUPPORTING DOCUMENT 1. Total Page
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WHC-SD-W100-TI-003 Rev. 0 EXECUTIVE
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WHC-SD-W100-TI-003 Rev. 0 been achi
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__ _ _ MHC-SIL-yJ3,00-TI-D03 Rev. 0
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F`= WHC-SD-W100-TI-003 Rev. 0 DESCR
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WHC-SD-W100-TI-003 Rev. 0 LIST OF T
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WHC-SD-W100-TI-003 Rev. 0 WASTE REC
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WHC-SD-W100-TI-003 Rev. 0 1.2.1 Fee
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^s. WHC-SD-W100-TI-003 Rev. 0 conta
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__-'°'2 WHC-SD-W100-TI-003 Rev. 0
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2.1 REGULATORY FRAMEWORK WHC-SD-W10
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^..." ;_:.. :.^ .^.y^ WHC-SD-W100-T
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WHC-SD-W100-TI-003 Rev. 0 which the
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kIHC-Sû-Wi"v"u-Ti-u03 Rev. V ,--,,
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WHC-SD-W100-TI-003 Rev. 0 Type 1 wa
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3.3 TESTING APPROACH WHC-SD-W100-TI
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^.: fi WNC-SD-W100-TI-003 Rev. 0 Fi
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4.1 SCREENING TEST RESULTS WHC-SD-W
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,^. ----- -- WHC-SD-W100-TI-003 Rev
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WHC-SD-W100-TI-003 Rev. 0 4.1.3 The
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p Sam le Compressive Radiation stre
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WHC-SD-W100-TI-003 Rev. 0 Table 4-3
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..., TESTING RESULTS .^.CSSD-W-1OO-
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;..;: .^:. WHC-SD-W100-TI-003 Rev.
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--- ....ti s..` WHC-SD-WI00-TI-003
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1.0 INTRODUCTION WHC-SD-W100-TI-003
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WHC-SD-W100-TI-003 Rev. 0 Waste For
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^-: -- ^ Component Waste Type 1 LET
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.^x. --1vHC-SD iii00- T i-003 Rev.
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WHC-SD-W: JV-TI-VVJ ^cv. v APPENDIX
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,..^ c:-- z ,.E ^=t ^^ln^l WHC-SD-W
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Scope WHC-SD-W100-TI-003 Rev. 0 Sup
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00 V F-' Activity and Miltstone Cha
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WHC-SD-W100-TI-003 Rev. 0 Laborator
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WHC-SD-WIOO-TI-003 Rev. 0 APPENDIX
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16490 Chiaccothe Itoad Chagrin Fall
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ca-. tY•^_E Q . - - StoGkE4uip+!n
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^.. WHC-SD-W100-TI-003 Rev. 0 . , I
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Waste Type: WHC-SD-W100-TI-003 Rev.
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Stock E quipment Company A Unit of
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G' ,.,. d,_ s WHC-0-W100-TI-003 Rev
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Cx U: r°... .• , .ti Waste Type:
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-. LeachantSolution: Specimen Diame
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c^1, WHC-SD-W100-TI-003 Rev. 0 THER
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..... lry" - Stock E a uipment Comp
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;=. .:^;. WHC-SD-W100-TI-003 Rev< 0
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(.7 ..^^ -„n f^. [Y^. Waste Type:
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Date: _ Leachability Time Point Lea
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23 Ninety ( 90) Day Immersion Test
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ty ,.. ='`F r...,, b Ly.. Specimen
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25 BIODEGRADATION TEST PROCEDURE St
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Date: WHC-SD-W100-TI-003 Rev. 0 BIO
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^_... ..^^ C:i1 Date: WHC-SD-W100-T
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Date: WHC-SD-W100-TI-003 Rev. 0 --
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f-^ -- WHC-SD-W100-TI-003 Rev. 0 2.
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^-..., 3•0 ASSAY FOR MEI'ALS 3.1
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 STOCK EQU
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19 SCOPE AND APPLICATION WHC-SD-W10
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L:^3 ll Q. 4 AA :'ILTEP.S WHC-0-W10
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4_T tJrD o,...Ys j ^,.,. WHC-SD-W10
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WHC-SD-W100-TI-003 Rev. 0 -, Proced
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WHC-SD-W100-TI-003 Rev. 0 Procedure
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Page 145 and 146: ^' . WHC-SD-W100-T1-003 Rev. 0 TABL
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Page 153 and 154: R: C=1 rIj s^ ^ ^.. WHC-SD-YlI00-TI
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Page 157 and 158: WHC-SD-W100-TI-003 Rev. 0 Dow Chemi
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Page 161 and 162: WHC-S®-hi1.00-T'.-00?, Rev. Dow Ch
Page 163 and 164: t;7_7 ,...:: ----------- WHC-SD-W10
Page 165 and 166: WHC-SD-W100-TI-003 Rev. 0 Daw M.. u
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Page 169 and 170: WHC-SD-W100-TI-003 Rev. 0 APPENDIX
Page 171 and 172: CHARACTERIZATION DATA Part A: Overv
Page 173 and 174: Grit Specie or MaterialOverall Cont
Page 175 and 176: WHC-SD-W100-TI-003 Rev. 0 The incin
Page 177 and 178: WHC-SD-W100-TI-003 Rev. 0 183-H BAS
Page 179 and 180: WHC-SD-W100-TI-003 Rev. 0 June - Se
Page 181 and 182: WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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Page 191 and 192: u...^^, WHC-SD-W100-TI-003 Rev. 0 I
Page 193 and 194: •N`^C-Sf1-"d100-71-003 Rev. 0 ,S'
Page 195 and 196: CONTAINER /NFORMATlO N: `d"-C-Sn-'w
Page 197 and 198: ONTANVER BVFORMA SI7 E: AMOUN=i 8 G
Page 199 and 200: LOT WRAP 2A.4 SHEET 7.XLS RECOMMEND
Page 201 and 202: LOT WRAP 2A.5 SHEET 8.XLS RECOMMEND
Page 203 and 204: .:•n-,,, LOT WRAP 2A.6 SHEET 9.XL
Page 205 and 206: LOT WRAP 2A.7 SHEET 10.XLS RECOMMEN
Page 207 and 208: PHYSICAL DESCR/PTTON: V-r-S?-W100-T
Page 209 and 210: ,.: Westinoause Harlford COMM WHC-S
Page 211 and 212: O I tA SHEETII.XLS ;, LOT WRAP2A.2
Page 213 and 214: CONTAINER /NFORMAT/ON: DOSE: SIZE:
Page 215 and 216: PU33-11-1992 09:48 FROM EDS/qRI$ir
Page 217 and 218: LOT WRAP 2A 10 Slf-EET 14.)C,S RECO
Page 219 and 220: qN i: 105N-89-1097 105N-89-1098 105
Page 221 and 222: SIZE: DOSE: 5 GAL 1 1@15 Mr 30 GAL
Page 223 and 224: WHC-SD-W100-TI-003 Rev. 0 Westtngho
Page 225 and 226: LOT WRAP A2.14 SHEET 18.XLS RECOMME
Page 227 and 228: ---- - LOT WRAP ZA.13 SHEET 17.XLS
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Page 231 and 232: --^ WHC-SD-W100-TI-003 Rev. 0 APPEN
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Page 235 and 236: Table 1 Candidate Waste Forms Absor
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- '^ - qev. r' Literature Search WR
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Dow Polymer WHC-SD-W100-TI-003 Rev.
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L im e Literature Search WRAP 2A Pa
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The report compares the 7eachabilit
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J. L. Westcott Page 2 May 29, 1992
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Package #1: Package #2: WHC-SD-W100
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WHC-SD-W100-TI-003 Rev. 0 SURVEY OF
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f ..;' WHC-SD-W100-TI-003 Rev. 0 A
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 Bibliogra
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WHC-SD-W100-TI-003 Rev. 0 A. P. Tos
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OAK R1DGE NATIONAL LABORATORY OPERA
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 A report
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WHC-SD-W100-TI-003 Rev. 0 impermeab
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WHC-SD-W100-TI-003 Rev. 0 reprocess
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WHC-SD-W100-TI-003 Rev. 0 STR?.THGI
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Contained under four reports: WHC-S
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^.yo F-SD-W"00-7-003 Rev. 0 THERMOS
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WHC-SD-W100-TI-003 Rev. 0 The techn
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loomi^^lC& 111111111111F .^^.\ West
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Stock Equipment Company WHC-SD-WI00
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^ i w STOCK EOUIPMENT COMPANY 14-OC
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\. . 1 .: lh,lf^ LEACH / IMMERSIONI
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^;- v.4'? Sampls ID L781 Elsment CO
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4.a
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Sanp)a ID L781 Elamant STRONTIUM Ma
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Sample 10 L3B1 Elsmant CESIUM Matri
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Sample ID W B1 Elemant STRONIIUM Ma
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Westinghouse Hanford Company 2355 S
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--- - ftCR-e4Uip1P1eFf Company WHC-
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WHC-SD-W100-TI-003 Rev. 0 Russ Czel
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Stock Equipment Company 3:0 -SCFIED
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THERMAL CYCLING SAMPLES BEFORE THE
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BIODEGRADATION SAMPLES BEFORE THE S
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C/ 0D OC M1 0, ^yII i..) d tl ^ a I
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' iO`F*'P\^ Westinghouse Hanford Co
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Stock Equipment Company 1.0 SUMMARY
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Stock Equipment Company WHC-SD-W100
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2a0 SCHEDULE Activitv - Prepare Wor
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T 1 o+ THERMAL CYCLWG SAMPLES BEFOR
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T 1 OI 80 70 U 60 VJ w 50 w 0 40 30
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SAMPLE ID Li-117 L1-118 L1-19 L3-17
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TI V 40 IN s i s : s ^l l i " p p l
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 _QVrDvrru
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^-_- .,:... WHC-SD-W100-TI-003 Rev.
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Ceramics and glass WHC-SD-W200-TI-0
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,. ., Extruder/melter WHC-SD-W100-T
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