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1.0 SUNYNARY WHC-SD-W100-TI-003 Rev. 0 Weeks of September 28. 199 2 and October 5. 1992 I started and completed the assays for the following leach time points: 30 second, 2 hour, 7 hour, 24 hour, 2 day, 3 day, 4 day, and 5 day. The leachants were assayed for the following elements: Cesium, Cobalt and Strontium. I have calculated the leachability index numbers for the above time points. The 18 day leach interval has arrived and the samples were changed. = The samples are intact; no apparent degradation. I have assayed the 18 day leach interval. The leachability calculations have been updated with the 18 day leach interval. ------------ Week of October 19. 1992 I started the thermal cycling portion of the test. The thermal __-----cymli^g-test-will be complete early November. The compressive strength results will be noted in the November progress report. Stock contracted with a consultant from the University of Akron Polymer Department to discuss the problem in trying to solidify TYPE 2 & 4 surrogate waste streams. The consultant has S'2ige
WHC-SD-W100-TI-003 Rev. 0 Russ Czellath -2- November 2. 1992 --------------I-also-tr3Ed-more--experimentG-involving TYPE 2 surrogate waste. I adjusted the pH of the waste to 10.5 and tried to solidified it. The best result obtained was a gell. I also tried the same thing to surrogate waste TYPE 4 with the same results. I tried to minimize the amount of energy input for mixing the waste. The theory here is that oxygen may inhibit polymerization, so I decided to hand mix two (2) se3idificatio.^.s, a type 2(pH 10.5) and a type 4(pH 10.5) surrogate. These solidifications have obtained the best gell of all the variations tried (these gells are very firm). I.. _y p*:; I ordered copper sulfate to attempt solidification with the derakane resin; it's possible the compound that the copper is in might be inhibiting the polymerization. I have ordered another polymer that is more reactive than the current polymer being used for this testing program. Early indications show that TYPE 4 surroaate waste can be solidified in this new polymer. I have been working on optimizing the loading ratio (waste to binder) for TYPE 4 surrogate waste. The following experiments have been performed: ID BINDER (gms) A 100 B --100 C --- - lnn D 100 CATALYST PROMOTOR WASTE (gms) (gms) (gms) 2.5 1.0 - - 2,5 0.2 -2=5 0.4 2.5 1.0 E 100 2.5 1.0 100 200 200 200 150 SPEED POWER (rpm) (watts) 1800 6.1 1799 8.4 1815 8.1 1000 3.8 1000 2.2 Sample "A° set up rock hard in a very few minutes, this waste had a pH adjustment of 10.5. All the samples after "A" have no pH adjustment. Sample "B" has set up but not rock hard. Sample "C" a little better results than "B". Sample "D" results are the same as "C". Sample "E" set rock hard. I can only assume that the maximum waste to binder loading will be greater than 1.5/1 but less than 2/1. Type 2 surrogate waste solidification is promising but there still maybe the problem of copper concentration. F-33
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R 2.1 199^ ^.EN GINEERING DATA TRAN
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Date Received% • I INFORMATION RE
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. SUPPORTING DOCUMENT 1. Total Page
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WHC-SD-W100-TI-003 Rev. 0 EXECUTIVE
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WHC-SD-W100-TI-003 Rev. 0 been achi
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F`= WHC-SD-W100-TI-003 Rev. 0 DESCR
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WHC-SD-W100-TI-003 Rev. 0 LIST OF T
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WHC-SD-W100-TI-003 Rev. 0 WASTE REC
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WHC-SD-W100-TI-003 Rev. 0 1.2.1 Fee
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^s. WHC-SD-W100-TI-003 Rev. 0 conta
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__-'°'2 WHC-SD-W100-TI-003 Rev. 0
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2.1 REGULATORY FRAMEWORK WHC-SD-W10
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^..." ;_:.. :.^ .^.y^ WHC-SD-W100-T
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WHC-SD-W100-TI-003 Rev. 0 which the
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kIHC-Sû-Wi"v"u-Ti-u03 Rev. V ,--,,
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WHC-SD-W100-TI-003 Rev. 0 Type 1 wa
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3.3 TESTING APPROACH WHC-SD-W100-TI
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4.1 SCREENING TEST RESULTS WHC-SD-W
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WHC-SD-W100-TI-003 Rev. 0 4.1.3 The
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p Sam le Compressive Radiation stre
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WHC-SD-W100-TI-003 Rev. 0 Table 4-3
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..., TESTING RESULTS .^.CSSD-W-1OO-
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;..;: .^:. WHC-SD-W100-TI-003 Rev.
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1.0 INTRODUCTION WHC-SD-W100-TI-003
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WHC-SD-W100-TI-003 Rev. 0 Waste For
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^-: -- ^ Component Waste Type 1 LET
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.^x. --1vHC-SD iii00- T i-003 Rev.
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WHC-SD-W: JV-TI-VVJ ^cv. v APPENDIX
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,..^ c:-- z ,.E ^=t ^^ln^l WHC-SD-W
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Scope WHC-SD-W100-TI-003 Rev. 0 Sup
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00 V F-' Activity and Miltstone Cha
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WHC-SD-W100-TI-003 Rev. 0 Laborator
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WHC-SD-WIOO-TI-003 Rev. 0 APPENDIX
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16490 Chiaccothe Itoad Chagrin Fall
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ca-. tY•^_E Q . - - StoGkE4uip+!n
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^.. WHC-SD-W100-TI-003 Rev. 0 . , I
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Waste Type: WHC-SD-W100-TI-003 Rev.
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Stock E quipment Company A Unit of
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G' ,.,. d,_ s WHC-0-W100-TI-003 Rev
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Cx U: r°... .• , .ti Waste Type:
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-. LeachantSolution: Specimen Diame
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c^1, WHC-SD-W100-TI-003 Rev. 0 THER
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..... lry" - Stock E a uipment Comp
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;=. .:^;. WHC-SD-W100-TI-003 Rev< 0
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(.7 ..^^ -„n f^. [Y^. Waste Type:
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Date: _ Leachability Time Point Lea
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23 Ninety ( 90) Day Immersion Test
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ty ,.. ='`F r...,, b Ly.. Specimen
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25 BIODEGRADATION TEST PROCEDURE St
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Date: WHC-SD-W100-TI-003 Rev. 0 BIO
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^_... ..^^ C:i1 Date: WHC-SD-W100-T
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Date: WHC-SD-W100-TI-003 Rev. 0 --
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f-^ -- WHC-SD-W100-TI-003 Rev. 0 2.
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^-..., 3•0 ASSAY FOR MEI'ALS 3.1
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^c. v 3 0 w.3 cn a v t[ACeRUtIIY IO
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 STOCK EQU
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19 SCOPE AND APPLICATION WHC-SD-W10
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L:^3 ll Q. 4 AA :'ILTEP.S WHC-0-W10
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4_T tJrD o,...Ys j ^,.,. WHC-SD-W10
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WHC-SD-W100-TI-003 Rev. 0 -, Proced
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WHC-SD-W100-TI-003 Rev. 0 Procedure
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(FM WHC-SD-W100-TI-003 Rev. 0 Proce
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C... 6 Wet Waste Sample Contains no
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^..., . ,.y^ h:.r WHC-SD-WI00-Ti-00
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:. WHC-SD-W100-TI-003 Rev. 0 TA3i.E
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^' . WHC-SD-W100-T1-003 Rev. 0 TABL
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^- ^-> ^ C^Jl I I^t ^.: l WHC-St]-W
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c. 03 00 r=3 ^t C^' II 6.0 II Calib
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LY; ^ C=l . ^.^ .^,..,, €:^. MHC-
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R: C=1 rIj s^ ^ ^.. WHC-SD-YlI00-TI
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.,,_..1 ---^ - - i-•_E ?*^^ Mater
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WHC-SD-W100-TI-003 Rev. 0 Dow Chemi
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^ ±.£:a [7.p -;^ --- --------- WH
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WHC-S®-hi1.00-T'.-00?, Rev. Dow Ch
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t;7_7 ,...:: ----------- WHC-SD-W10
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WHC-SD-W100-TI-003 Rev. 0 Daw M.. u
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^ ^..rYfl VF •UIYb 1 1 AGA GllS.
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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CHARACTERIZATION DATA Part A: Overv
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Grit Specie or MaterialOverall Cont
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WHC-SD-W100-TI-003 Rev. 0 The incin
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WHC-SD-W100-TI-003 Rev. 0 183-H BAS
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WHC-SD-W100-TI-003 Rev. 0 June - Se
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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^- WHC-SD-W100-TI-003 Rev. 0 BASIN
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WHC-SD-W100-TI-003 Rev. 0 ---------
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J. L. Westcott Page 3 June 1, 1992
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u...^^, WHC-SD-W100-TI-003 Rev. 0 I
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•N`^C-Sf1-"d100-71-003 Rev. 0 ,S'
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CONTAINER /NFORMATlO N: `d"-C-Sn-'w
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ONTANVER BVFORMA SI7 E: AMOUN=i 8 G
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LOT WRAP 2A.4 SHEET 7.XLS RECOMMEND
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LOT WRAP 2A.5 SHEET 8.XLS RECOMMEND
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.:•n-,,, LOT WRAP 2A.6 SHEET 9.XL
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LOT WRAP 2A.7 SHEET 10.XLS RECOMMEN
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PHYSICAL DESCR/PTTON: V-r-S?-W100-T
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,.: Westinoause Harlford COMM WHC-S
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O I tA SHEETII.XLS ;, LOT WRAP2A.2
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CONTAINER /NFORMAT/ON: DOSE: SIZE:
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PU33-11-1992 09:48 FROM EDS/qRI$ir
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LOT WRAP 2A 10 Slf-EET 14.)C,S RECO
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qN i: 105N-89-1097 105N-89-1098 105
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SIZE: DOSE: 5 GAL 1 1@15 Mr 30 GAL
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WHC-SD-W100-TI-003 Rev. 0 Westtngho
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LOT WRAP A2.14 SHEET 18.XLS RECOMME
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---- - LOT WRAP ZA.13 SHEET 17.XLS
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n .-.^..-n..^^- .. ... .dJ. ^ ShIEE
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--^ WHC-SD-W100-TI-003 Rev. 0 APPEN
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WHC-SD-W100-TI-003 Rev. 0 Westingho
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Table 1 Candidate Waste Forms Absor
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--- -Aauaspt and Pe-liroset WHC-SD-
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- '^ - qev. r' Literature Search WR
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Dow Polymer WHC-SD-W100-TI-003 Rev.
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L im e Literature Search WRAP 2A Pa
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The report compares the 7eachabilit
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J. L. Westcott Page 2 May 29, 1992
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Package #1: Package #2: WHC-SD-W100
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WHC-SD-W100-TI-003 Rev. 0 SURVEY OF
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f ..;' WHC-SD-W100-TI-003 Rev. 0 A
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WHC-SD-W100-TI-003 Rev. 0 SURVEY OF
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Page 263 and 264: OAK R1DGE NATIONAL LABORATORY OPERA
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Page 269 and 270: WHC-SD-W100-TI-003 Revo 0 A report
Page 271 and 272: WHC-SD-W100-TI-003 Rev. 0 impermeab
Page 273 and 274: WHC-SD-W100-TI-003 Rev. 0 reprocess
Page 275 and 276: WHC-SD-W100-TI-003 Rev. 0 STR?.THGI
Page 277 and 278: Contained under four reports: WHC-S
Page 279 and 280: ^.yo F-SD-W"00-7-003 Rev. 0 THERMOS
Page 281 and 282: WHC-SD-W100-TI-003 Rev. 0 The techn
Page 283 and 284: loomi^^lC& 111111111111F .^^.\ West
Page 285 and 286: û9^c ?fi. ...^ .._-, WHC-SD-W100-T
Page 287 and 288: Stock Equipment Company WHC-SD-WI00
Page 289 and 290: ^ i w STOCK EOUIPMENT COMPANY 14-OC
Page 291 and 292: \. . 1 .: lh,lf^ LEACH / IMMERSIONI
Page 293 and 294: ^;- v.4'? Sampls ID L781 Elsment CO
Page 295 and 296: 4.a
Page 297 and 298: Sanp)a ID L781 Elamant STRONTIUM Ma
Page 299 and 300: .^ "-; SampI81D L3B2 Z e"- ^.;;. Sa
Page 301 and 302: Sample 10 L3B1 Elsmant CESIUM Matri
Page 303 and 304: Sample ID W B1 Elemant STRONIIUM Ma
Page 305 and 306: Westinghouse Hanford Company 2355 S
Page 307: --- - ftCR-e4Uip1P1eFf Company WHC-
Page 311 and 312: Stock Equipment Company 3:0 -SCFIED
Page 313 and 314: THERMAL CYCLING SAMPLES BEFORE THE
Page 315 and 316: BIODEGRADATION SAMPLES BEFORE THE S
Page 317 and 318: C/ 0D OC M1 0, ^yII i..) d tl ^ a I
Page 319 and 320: T 1 A w ^ • $ ^py yf ; pp V ^ py
Page 321 and 322: T 1 A ^ !^^ + ^ i •^^w^:rwwwwrpR^
Page 323 and 324: 'i A v lf^. j^^ u e e - - I I I a i
Page 325 and 326: 0 > d C.) O O F- 0 0 3 G NI U 3 ^ c
Page 327 and 328: en a-. p g aQ i ^ rr it - l r rF e^
Page 329 and 330: ' iO`F*'P\^ Westinghouse Hanford Co
Page 331 and 332: Stock Equipment Company 1.0 SUMMARY
Page 333 and 334: Stock Equipment Company WHC-SD-W100
Page 335 and 336: 2a0 SCHEDULE Activitv - Prepare Wor
Page 337 and 338: T 1 o+ THERMAL CYCLWG SAMPLES BEFOR
Page 339 and 340: T 1 OI 80 70 U 60 VJ w 50 w 0 40 30
Page 341 and 342: ^ °' cn l .:. U CD w a: w r' i ^ I
Page 343 and 344: SAMPLE ID Li-117 L1-118 L1-19 L3-17
Page 345 and 346: T °,w ^ - : C s 0 n a ^^ s ^ i ^-
Page 347 and 348: 71 I V y,,} ^ • 5il i ^ ^^ ^ ^ ^
Page 349 and 350: 0 a^ on O O M F- 1OCD 3 1 G N^ U il
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Page 355 and 356: TI V 40 IN s i s : s ^l l i " p p l
Page 357 and 358: WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 _QVrDvrru
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^-_- .,:... WHC-SD-W100-TI-003 Rev.
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Ceramics and glass WHC-SD-W200-TI-0
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,. ., Extruder/melter WHC-SD-W100-T
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