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WHC-SD-W100-TI-003 Rev. 0 Eight different waste types, representing about 80% of the projected feed to WRAP 2A were used for these initial phases of testing. The remaining 20% consists of small quantities of various waste types that require better characterization data before testing. This 20% will be tested as better information becomes available. Four of the waste types were tested with cementitious waste forms, and four different waste types were tested with the thermosetting polymer. The split as to which waste was to be treated with which immobilization medium was based on the conceptual design baseline. Screening tests were performed using the major chemical constituent of each waste type to measure the gross compatibility with the immobilization media. Positive results were obtained here in that a solid monolith was successfully prepared from each major chemical constituent with the selected immobilization medium. This indicated that more advanced testing should be performed to confirm that a detailed surrogate waste in the immobilization matrix could pass all applicable test criteria imposed on the final waste form. Test criteria for solidified mixed waste were assembled from applicable -- - -----r_egulaiiory=documeQtation (DDEArder 5820-2A--[D4E -1-988], Washingtpn Administrative Code 173-303 [WAC 1990], and 10 CFR 261 [NRC 1992]), including guidance documents from the U.S. Nuclear Regulatory Commission (NRC Technical --- - ---Posi#iop-on-Waste-Faxm.[NRC-184T])-and the U.S. Er^vironmental Protection Agency Handbook for Stabilization_and Solidification of Hazardous Wastes (EPA 1984). Waste surrogates were then prepared by WHC to represent each of the eight waste types for testing. Surrogates for polymer testing were sent to the vendor commissioned for that portion of the test work. Surrogates for the cementitious testing were used in the WHC laboratory responsible for the grout performance testing. Test specimens were prepared with the surrogate wastes, and tests were performed. Detailed discussion of the laboratory work and results are contained in this report. All cementitious specimens performed as expected and confirmed baseline process selection. Successful test results have also iii
WHC-SD-W100-TI-003 Rev. 0 been achieved with some of the polymer specimens. All surrogates have been successfully solidified and have formed free-standing monoliths that exceed strength criteria. Some additional formulation work is necessary with the polymer-wastetypss to ensure adequate encapsulation of some key constituents. If the remaining tests show positive results, then the baseline process selection will be confirmed and the next stage of testing will proceed. The -follow-on tests will consist of laboratory parametric studies, mixing -----€qu#-pmer,t tests, and confirmatory testing using actual waste. These tests -- will_qenera_teprocess €ontxol data, detailed design data, and data required for pe%mit approval. iv
Page 1 and 2: R 2.1 199^ ^.EN GINEERING DATA TRAN
Page 3 and 4: Date Received% • I INFORMATION RE
Page 5 and 6: . SUPPORTING DOCUMENT 1. Total Page
Page 7: WHC-SD-W100-TI-003 Rev. 0 EXECUTIVE
Page 11 and 12: __ _ _ MHC-SIL-yJ3,00-TI-D03 Rev. 0
Page 13 and 14: F`= WHC-SD-W100-TI-003 Rev. 0 DESCR
Page 15 and 16: WHC-SD-W100-TI-003 Rev. 0 LIST OF T
Page 17 and 18: WHC-SD-W100-TI-003 Rev. 0 WASTE REC
Page 19 and 20: WHC-SD-W100-TI-003 Rev. 0 1.2.1 Fee
Page 21 and 22: ^s. WHC-SD-W100-TI-003 Rev. 0 conta
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Page 25 and 26: 2.1 REGULATORY FRAMEWORK WHC-SD-W10
Page 27 and 28: ^..." ;_:.. :.^ .^.y^ WHC-SD-W100-T
Page 29 and 30: WHC-SD-W100-TI-003 Rev. 0 which the
Page 31 and 32: kIHC-Sû-Wi"v"u-Ti-u03 Rev. V ,--,,
Page 33 and 34: WHC-SD-W100-TI-003 Rev. 0 Type 1 wa
Page 35 and 36: 3.3 TESTING APPROACH WHC-SD-W100-TI
Page 37 and 38: ^.: fi WNC-SD-W100-TI-003 Rev. 0 Fi
Page 39 and 40: 4.1 SCREENING TEST RESULTS WHC-SD-W
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Page 43 and 44: WHC-SD-W100-TI-003 Rev. 0 4.1.3 The
Page 45 and 46: p Sam le Compressive Radiation stre
Page 47 and 48: WHC-SD-W100-TI-003 Rev. 0 Table 4-3
Page 49 and 50: ..., TESTING RESULTS .^.CSSD-W-1OO-
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Page 53 and 54: ;..;: .^:. WHC-SD-W100-TI-003 Rev.
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Page 57 and 58: 1.0 INTRODUCTION WHC-SD-W100-TI-003
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WHC-SD-W100-TI-003 Rev. 0 Waste For
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^-: -- ^ Component Waste Type 1 LET
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.^x. --1vHC-SD iii00- T i-003 Rev.
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WHC-SD-W: JV-TI-VVJ ^cv. v APPENDIX
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,..^ c:-- z ,.E ^=t ^^ln^l WHC-SD-W
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Scope WHC-SD-W100-TI-003 Rev. 0 Sup
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00 V F-' Activity and Miltstone Cha
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WHC-SD-W100-TI-003 Rev. 0 Laborator
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WHC-SD-WIOO-TI-003 Rev. 0 APPENDIX
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16490 Chiaccothe Itoad Chagrin Fall
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ca-. tY•^_E Q . - - StoGkE4uip+!n
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^.. WHC-SD-W100-TI-003 Rev. 0 . , I
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Waste Type: WHC-SD-W100-TI-003 Rev.
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Stock E quipment Company A Unit of
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G' ,.,. d,_ s WHC-0-W100-TI-003 Rev
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Cx U: r°... .• , .ti Waste Type:
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-. LeachantSolution: Specimen Diame
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c^1, WHC-SD-W100-TI-003 Rev. 0 THER
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..... lry" - Stock E a uipment Comp
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;=. .:^;. WHC-SD-W100-TI-003 Rev< 0
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(.7 ..^^ -„n f^. [Y^. Waste Type:
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Date: _ Leachability Time Point Lea
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23 Ninety ( 90) Day Immersion Test
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ty ,.. ='`F r...,, b Ly.. Specimen
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25 BIODEGRADATION TEST PROCEDURE St
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Date: WHC-SD-W100-TI-003 Rev. 0 BIO
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^_... ..^^ C:i1 Date: WHC-SD-W100-T
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Date: WHC-SD-W100-TI-003 Rev. 0 --
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f-^ -- WHC-SD-W100-TI-003 Rev. 0 2.
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^-..., 3•0 ASSAY FOR MEI'ALS 3.1
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 STOCK EQU
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19 SCOPE AND APPLICATION WHC-SD-W10
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L:^3 ll Q. 4 AA :'ILTEP.S WHC-0-W10
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4_T tJrD o,...Ys j ^,.,. WHC-SD-W10
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WHC-SD-W100-TI-003 Rev. 0 -, Proced
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WHC-SD-W100-TI-003 Rev. 0 Procedure
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(FM WHC-SD-W100-TI-003 Rev. 0 Proce
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C... 6 Wet Waste Sample Contains no
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^..., . ,.y^ h:.r WHC-SD-WI00-Ti-00
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:. WHC-SD-W100-TI-003 Rev. 0 TA3i.E
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^' . WHC-SD-W100-T1-003 Rev. 0 TABL
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c. 03 00 r=3 ^t C^' II 6.0 II Calib
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WHC-SD-W100-TI-003 Rev. 0 Dow Chemi
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WHC-S®-hi1.00-T'.-00?, Rev. Dow Ch
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WHC-SD-W100-TI-003 Rev. 0 Daw M.. u
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^ ^..rYfl VF •UIYb 1 1 AGA GllS.
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CHARACTERIZATION DATA Part A: Overv
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Grit Specie or MaterialOverall Cont
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WHC-SD-W100-TI-003 Rev. 0 The incin
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WHC-SD-W100-TI-003 Rev. 0 183-H BAS
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WHC-SD-W100-TI-003 Rev. 0 June - Se
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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^- WHC-SD-W100-TI-003 Rev. 0 BASIN
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WHC-SD-W100-TI-003 Rev. 0 ---------
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J. L. Westcott Page 3 June 1, 1992
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u...^^, WHC-SD-W100-TI-003 Rev. 0 I
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•N`^C-Sf1-"d100-71-003 Rev. 0 ,S'
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CONTAINER /NFORMATlO N: `d"-C-Sn-'w
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ONTANVER BVFORMA SI7 E: AMOUN=i 8 G
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LOT WRAP 2A.4 SHEET 7.XLS RECOMMEND
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LOT WRAP 2A.5 SHEET 8.XLS RECOMMEND
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.:•n-,,, LOT WRAP 2A.6 SHEET 9.XL
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LOT WRAP 2A.7 SHEET 10.XLS RECOMMEN
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PHYSICAL DESCR/PTTON: V-r-S?-W100-T
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,.: Westinoause Harlford COMM WHC-S
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O I tA SHEETII.XLS ;, LOT WRAP2A.2
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CONTAINER /NFORMAT/ON: DOSE: SIZE:
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PU33-11-1992 09:48 FROM EDS/qRI$ir
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LOT WRAP 2A 10 Slf-EET 14.)C,S RECO
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qN i: 105N-89-1097 105N-89-1098 105
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SIZE: DOSE: 5 GAL 1 1@15 Mr 30 GAL
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WHC-SD-W100-TI-003 Rev. 0 Westtngho
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LOT WRAP A2.14 SHEET 18.XLS RECOMME
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---- - LOT WRAP ZA.13 SHEET 17.XLS
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--^ WHC-SD-W100-TI-003 Rev. 0 APPEN
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WHC-SD-W100-TI-003 Rev. 0 Westingho
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Table 1 Candidate Waste Forms Absor
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--- -Aauaspt and Pe-liroset WHC-SD-
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- '^ - qev. r' Literature Search WR
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Dow Polymer WHC-SD-W100-TI-003 Rev.
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L im e Literature Search WRAP 2A Pa
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The report compares the 7eachabilit
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J. L. Westcott Page 2 May 29, 1992
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Package #1: Package #2: WHC-SD-W100
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WHC-SD-W100-TI-003 Rev. 0 SURVEY OF
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f ..;' WHC-SD-W100-TI-003 Rev. 0 A
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 Bibliogra
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WHC-SD-W100-TI-003 Rev. 0 A. P. Tos
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OAK R1DGE NATIONAL LABORATORY OPERA
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 A report
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WHC-SD-W100-TI-003 Rev. 0 impermeab
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WHC-SD-W100-TI-003 Rev. 0 reprocess
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WHC-SD-W100-TI-003 Rev. 0 STR?.THGI
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Contained under four reports: WHC-S
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^.yo F-SD-W"00-7-003 Rev. 0 THERMOS
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WHC-SD-W100-TI-003 Rev. 0 The techn
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Stock Equipment Company WHC-SD-WI00
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^ i w STOCK EOUIPMENT COMPANY 14-OC
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Sanp)a ID L781 Elamant STRONTIUM Ma
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Sample 10 L3B1 Elsmant CESIUM Matri
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Sample ID W B1 Elemant STRONIIUM Ma
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Westinghouse Hanford Company 2355 S
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--- - ftCR-e4Uip1P1eFf Company WHC-
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WHC-SD-W100-TI-003 Rev. 0 Russ Czel
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Stock Equipment Company 3:0 -SCFIED
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THERMAL CYCLING SAMPLES BEFORE THE
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BIODEGRADATION SAMPLES BEFORE THE S
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Stock Equipment Company 1.0 SUMMARY
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Stock Equipment Company WHC-SD-W100
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2a0 SCHEDULE Activitv - Prepare Wor
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T 1 o+ THERMAL CYCLWG SAMPLES BEFOR
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T 1 OI 80 70 U 60 VJ w 50 w 0 40 30
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WHC-SD-W100-TI-003 Rev. 0 _QVrDvrru
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^-_- .,:... WHC-SD-W100-TI-003 Rev.
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Ceramics and glass WHC-SD-W200-TI-0
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,. ., Extruder/melter WHC-SD-W100-T
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