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Grit<br />

Specie or MaterialOverall Content<br />

Sand Blast Grit 90%<br />

WHC-SD-W100-TI-003 Rev. 0<br />

Basin I Sludgel0%<br />

• Sodium = 29%<br />

• Sulfate - 29%<br />

• Copper - 17%<br />

• Nitrate - 11%<br />

• Fluoride - 9%<br />

• Zirconium - 4%<br />

• Silica - 1%<br />

• Molybdenum - 0.05% (uranium stand-in)<br />

• Ruthenium - 0.05% (technetium stand-in)<br />

• Chromium VI - 0.05%<br />

Grit 2 :<br />

Soecie or Material0vera1l Content<br />

Sand Blast Grit90%<br />

Basin 4 Crysta110%<br />

• Sodium - 38%<br />

• Nitrate - 47%<br />

• Sulfate - 13%<br />

• Fluoride - 2%<br />

• Molybdenum - 0.05% (uranium stand-in)<br />

• Chromiur VI - 0.05%<br />

• Cobalt i: - 0.01%<br />

• Strontium II - 0.01%<br />

The basin sludge portion of the Grit 1 surrogate was produced by weighing the<br />

appropriate amount of copper metal powder and dissolving it in dilute nitric<br />

acid which provided the nitrate. Zirconium powder, sulfuric acid, and<br />

hydrofluoric was added and mixed with the liquid in the preceding sequence.<br />

Sodium carbonate was used to neutralize the liquid, and then the chemical<br />

tracer compounds were added. The final pH was adjusted to a neutral value<br />

with nitric acid and sodium carbonate as appropriate. The liquid was dried,<br />

-- mil_fied, cieved to =20 mesh,--and- blended p^rior to use.<br />

The basin crystal portion of Grit 2 surrogate waste was made by weighing and<br />

dissolving the appropriate proportions of sodium nitrate, sodium sulfate,<br />

sodium fluoride, and sodium carbonate in water. The trace compounds were also<br />

added and stirred into the mixture. The liquid was then dried, milled, sieved<br />

to -20 mesh, and blended prior to use. Some carbonate was added as a source<br />

of sodium.<br />

L-045 LETF (300 Area Process Sewer Treatment Sludge)<br />

i.y -The 300 Area, in the past, has typically generated in excess of a million<br />

gallons per day of process water. The process sewer stream is monitored<br />

D-5

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