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CONCLUSIONS WHC-SD-W100-TI-003 Rev. 0 The immobilization/stabilization technologies selected for use in WRAP 2A have been tested on waste surrogates approximately reflecting the chemical characteristics of 80% of the baseline feed volume. The baseline process selection has been confirmed for the feed streams studied. Suitable formulations have been developed and waste form performance testing has shown that the technologies are capable of meeting all applicable regulatory acceptance criteria. ThQrmosetting -pn]ymer fermul.ationshavebeen-deveTuped-for four baseline WRAP 2A waste streams. Waste surrogates were successfully immobilized at waste loadings from 50 wt% to 66 wt%. Performance test results at these waste loadings met all specifications except TCLP for chromium and mercury. Specimens prepared as pellets with a 25 wt% waste loading met TCLP limits for all constituents. TCLP results for polymer waste forms were shown to be highly dependent on the method used for TCLP sample preparation and somewhat less strongly influenced by waste loading. 4-14
;..;: .^:. WHC-SD-W100-TI-003 Rev. 0 5.0 REFERENCES DOE 1988, DOE Order 5820.2A, "Radioactive Waste Management," U.S. Department of Energy, Washington, D.C. DOE 1989, DOE Order 5400.3, "Hazardous and Radioactiv€ 1Mixed-Waste-Program," U.S. Department of Energy, Washington, D.C. Ecology, EPA, and DOE, 1992, Hanford Federal Facility Agreement and Consent Order, 2 Vols., Washington State Department of Ecology, U.S. Environmental Protection Agency, and U.S. Department of Energy. EPA 1984, Handbook for Stabilization and Solidification of Hazardous Wastes, U.S. Environmental Protection Agency, Washington, D.C. EPA 1992, Code of Federal Regulations, 1989, 40 CFR 260-268, Office of the Federal Register National Archives and Records Administration, Washington, D.C. NRC 1991, "Technical Position on Waste Form, Revision 1," Final Waste Classification and Waste Form Technical Position Papers, U.S. Nuclear Regulatory Commission, Washington, D.C. NRC 1992, Code of Federal Regulations, 1992, 10 CFR 61, "Licensing Requirements for Land Disposal of Radioactive Waste," Office of the Federal Register, National Archives and Records Administration, Washington, D.C. llEgC ^ gg2a, W,PAD Module 2A Conceptual Design Report, United Engineers and Constructors, Englewood, Colorado. UE&C 1992b, WRAP 2 Preconceptual Design Additional Fo11ow-On Activities Report,_Draft_Letter_Report, From M-.-J. W3lters-to-A:-W. Kello-yg, dated February 7, 1992, United_E_ng-ineers_andConstructors, Englewood, Colorado. - WAC 173-303, Department of Ecology, 1991, Washington Administrative Code "Dangerous Waste Regulations," WAC-173-303. WHC 1991, Hanford Site Solid Waste Acceptance Criteria, WHC-EP-0063-3, Westinghouse Hanford Company, Richland, Washington. WHC 1993, WRAP Module 2A Waste Form Qualification Plan, WHC-SD-W100-TP-002, Rev. 0, Westinghouse Hanford Company, Richland, Washington. 5-1
Page 1 and 2: R 2.1 199^ ^.EN GINEERING DATA TRAN
Page 3 and 4: Date Received% • I INFORMATION RE
Page 5 and 6: . SUPPORTING DOCUMENT 1. Total Page
Page 7 and 8: WHC-SD-W100-TI-003 Rev. 0 EXECUTIVE
Page 9 and 10: WHC-SD-W100-TI-003 Rev. 0 been achi
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Page 13 and 14: F`= WHC-SD-W100-TI-003 Rev. 0 DESCR
Page 15 and 16: WHC-SD-W100-TI-003 Rev. 0 LIST OF T
Page 17 and 18: WHC-SD-W100-TI-003 Rev. 0 WASTE REC
Page 19 and 20: WHC-SD-W100-TI-003 Rev. 0 1.2.1 Fee
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Page 25 and 26: 2.1 REGULATORY FRAMEWORK WHC-SD-W10
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Page 35 and 36: 3.3 TESTING APPROACH WHC-SD-W100-TI
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Page 39 and 40: 4.1 SCREENING TEST RESULTS WHC-SD-W
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Page 47 and 48: WHC-SD-W100-TI-003 Rev. 0 Table 4-3
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Page 57 and 58: 1.0 INTRODUCTION WHC-SD-W100-TI-003
Page 59 and 60: WHC-SD-W100-TI-003 Rev. 0 Waste For
Page 61 and 62: ^-: -- ^ Component Waste Type 1 LET
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Page 65 and 66: WHC-SD-W: JV-TI-VVJ ^cv. v APPENDIX
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Page 69 and 70: Scope WHC-SD-W100-TI-003 Rev. 0 Sup
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Page 73 and 74: WHC-SD-W100-TI-003 Rev. 0 Laborator
Page 75 and 76: WHC-SD-WIOO-TI-003 Rev. 0 APPENDIX
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Page 79 and 80: ca-. tY•^_E Q . - - StoGkE4uip+!n
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Page 91 and 92: -. LeachantSolution: Specimen Diame
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Page 101 and 102: Date: _ Leachability Time Point Lea
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23 Ninety ( 90) Day Immersion Test
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ty ,.. ='`F r...,, b Ly.. Specimen
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25 BIODEGRADATION TEST PROCEDURE St
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Date: WHC-SD-W100-TI-003 Rev. 0 BIO
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^_... ..^^ C:i1 Date: WHC-SD-W100-T
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Date: WHC-SD-W100-TI-003 Rev. 0 --
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f-^ -- WHC-SD-W100-TI-003 Rev. 0 2.
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^-..., 3•0 ASSAY FOR MEI'ALS 3.1
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 STOCK EQU
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19 SCOPE AND APPLICATION WHC-SD-W10
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L:^3 ll Q. 4 AA :'ILTEP.S WHC-0-W10
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4_T tJrD o,...Ys j ^,.,. WHC-SD-W10
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WHC-SD-W100-TI-003 Rev. 0 -, Proced
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WHC-SD-W100-TI-003 Rev. 0 Procedure
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(FM WHC-SD-W100-TI-003 Rev. 0 Proce
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C... 6 Wet Waste Sample Contains no
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^' . WHC-SD-W100-T1-003 Rev. 0 TABL
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c. 03 00 r=3 ^t C^' II 6.0 II Calib
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WHC-SD-W100-TI-003 Rev. 0 Dow Chemi
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WHC-SD-W100-TI-003 Rev. 0 Daw M.. u
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CHARACTERIZATION DATA Part A: Overv
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Grit Specie or MaterialOverall Cont
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WHC-SD-W100-TI-003 Rev. 0 The incin
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WHC-SD-W100-TI-003 Rev. 0 183-H BAS
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WHC-SD-W100-TI-003 Rev. 0 June - Se
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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^- WHC-SD-W100-TI-003 Rev. 0 BASIN
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WHC-SD-W100-TI-003 Rev. 0 ---------
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J. L. Westcott Page 3 June 1, 1992
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u...^^, WHC-SD-W100-TI-003 Rev. 0 I
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•N`^C-Sf1-"d100-71-003 Rev. 0 ,S'
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CONTAINER /NFORMATlO N: `d"-C-Sn-'w
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ONTANVER BVFORMA SI7 E: AMOUN=i 8 G
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LOT WRAP 2A.4 SHEET 7.XLS RECOMMEND
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LOT WRAP 2A.5 SHEET 8.XLS RECOMMEND
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.:•n-,,, LOT WRAP 2A.6 SHEET 9.XL
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LOT WRAP 2A.7 SHEET 10.XLS RECOMMEN
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PHYSICAL DESCR/PTTON: V-r-S?-W100-T
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,.: Westinoause Harlford COMM WHC-S
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O I tA SHEETII.XLS ;, LOT WRAP2A.2
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CONTAINER /NFORMAT/ON: DOSE: SIZE:
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PU33-11-1992 09:48 FROM EDS/qRI$ir
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LOT WRAP 2A 10 Slf-EET 14.)C,S RECO
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qN i: 105N-89-1097 105N-89-1098 105
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SIZE: DOSE: 5 GAL 1 1@15 Mr 30 GAL
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WHC-SD-W100-TI-003 Rev. 0 Westtngho
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LOT WRAP A2.14 SHEET 18.XLS RECOMME
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---- - LOT WRAP ZA.13 SHEET 17.XLS
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--^ WHC-SD-W100-TI-003 Rev. 0 APPEN
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WHC-SD-W100-TI-003 Rev. 0 Westingho
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Table 1 Candidate Waste Forms Absor
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--- -Aauaspt and Pe-liroset WHC-SD-
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- '^ - qev. r' Literature Search WR
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Dow Polymer WHC-SD-W100-TI-003 Rev.
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L im e Literature Search WRAP 2A Pa
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The report compares the 7eachabilit
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J. L. Westcott Page 2 May 29, 1992
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Package #1: Package #2: WHC-SD-W100
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WHC-SD-W100-TI-003 Rev. 0 SURVEY OF
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f ..;' WHC-SD-W100-TI-003 Rev. 0 A
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 Bibliogra
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WHC-SD-W100-TI-003 Rev. 0 A. P. Tos
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OAK R1DGE NATIONAL LABORATORY OPERA
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WHC-SD-W100-TI-003 Rev. 0 commercia
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WHC-SD-W100-TI-003 Revo 0 A report
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WHC-SD-W100-TI-003 Rev. 0 impermeab
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WHC-SD-W100-TI-003 Rev. 0 reprocess
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WHC-SD-W100-TI-003 Rev. 0 STR?.THGI
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Contained under four reports: WHC-S
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^.yo F-SD-W"00-7-003 Rev. 0 THERMOS
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WHC-SD-W100-TI-003 Rev. 0 The techn
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Stock Equipment Company WHC-SD-WI00
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^ i w STOCK EOUIPMENT COMPANY 14-OC
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\. . 1 .: lh,lf^ LEACH / IMMERSIONI
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Sanp)a ID L781 Elamant STRONTIUM Ma
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.^ "-; SampI81D L3B2 Z e"- ^.;;. Sa
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Sample 10 L3B1 Elsmant CESIUM Matri
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Sample ID W B1 Elemant STRONIIUM Ma
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Westinghouse Hanford Company 2355 S
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--- - ftCR-e4Uip1P1eFf Company WHC-
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WHC-SD-W100-TI-003 Rev. 0 Russ Czel
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Stock Equipment Company 3:0 -SCFIED
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THERMAL CYCLING SAMPLES BEFORE THE
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BIODEGRADATION SAMPLES BEFORE THE S
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Stock Equipment Company 1.0 SUMMARY
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Stock Equipment Company WHC-SD-W100
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2a0 SCHEDULE Activitv - Prepare Wor
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T 1 o+ THERMAL CYCLWG SAMPLES BEFOR
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WHC-SD-W100-TI-003 Rev. 0 _QVrDvrru
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^-_- .,:... WHC-SD-W100-TI-003 Rev.
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Ceramics and glass WHC-SD-W200-TI-0
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,. ., Extruder/melter WHC-SD-W100-T
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