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WHC-SD-W100-TI-003 Rev. 0 Westinghouse Internal <strong>Hanford</strong> Company Memo From: Chemical Process Engineering Phone: 6-9616 L5-42 Date: May 29, 1992 Subject: WRAP 2A LITERATURE SEARCH UPDATE - NOTE ON SULFUR POLYMER CEMENT To: J. L. Westcott H2-58 cc: J. W. Biglin L5-31 J. A. Hunter L5-31 J. G. Riddelle H2-58 WOG/File-LB The hotte^t sC?id1-fiCation-med-i-a ^rr the-market- in recent years is sulfur polymer cement, sold as CHEMENT 2000. It is elementary sulfur (approximately 95%) mixed with a thermosetting polymer (dicyclopentadiene) that melts at 119°C. The sulfur polymer cement (SPC) was developed by the ,.; Sulfur institute of Washington D.C. to provide an additional market for suifur materiais. it was found to be very useful in coating, covering, or actually replacing concrete in applications where acidic or salt corrosion were severe. It has been shown in many of these applications to be superior to portland type concrete or cement products with the possible exception of polymer impregnated concrete. The reason for its enhanced performance in the above mentioned areas is probably the chemistry of the system. Portland cement mixes and concrete matrices are basic exhibiting an initial pH of about 13. Sulfur on the other hand is probably best considered as an Arhennius type acid. This means that sulfur would likely provide an excellent solidification media for acidic materials or provide protection from attack by acidic materials, but would likely react with or be attacked by basic materials. Cement or concrete on the other hand stabilizes base type materials well and the product matrix is stable to attacks by bases. It turns out both materials are fairly compatible with neutral materials and are generally stable in a neutral environment. It is recommended that SPC not be used to solidify any base as strong or stronger than sodium carbonate to avoid forming an unstable product, particularly if water is present. An example of an acid-base reaction is given below. Na2CO3 + H2O + S =- NaHCO3 + NaHS + 1/202 In addition to sulfur exhibiting acidic properties, sulfur is also a reducing agent. That means that it should not be mixed with, nor used to immobilize, oxidizing materials or materials with significant quantities of axidantsY The amounts of nitrite or nitrate material that can be present in SPC treated waste materials needs to be defined. In addition, sulfur is a combustible material (flashpoint 188°C) which burns with a very light blue, E-16 <strong>Hanford</strong> Operatione and EnpineeAnp Contractor for the US Department of Enarpy
J. L. Westcott Page 2 May 29, 1992 WHC-SD-W100-TI-003 Rev. 0 almost invisible, flame that emits sulfuric acid type fumes. Care should be taken to limit SPC mixing or handling temperatures well below the flashpoint region. ^1 /• ^ ^ l^ ^, W. 0. Greenhalgh, Principal Scientist rhamiral Drnroee Fnninuurinn -..-....--. ..---^^ -.^...^^...7 ldc E-17
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R 2.1 199^ ^.EN GINEERING DATA TRAN
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Date Received% • I INFORMATION RE
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. SUPPORTING DOCUMENT 1. Total Page
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WHC-SD-W100-TI-003 Rev. 0 EXECUTIVE
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WHC-SD-W100-TI-003 Rev. 0 been achi
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F`= WHC-SD-W100-TI-003 Rev. 0 DESCR
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WHC-SD-W100-TI-003 Rev. 0 LIST OF T
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WHC-SD-W100-TI-003 Rev. 0 WASTE REC
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WHC-SD-W100-TI-003 Rev. 0 1.2.1 Fee
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^s. WHC-SD-W100-TI-003 Rev. 0 conta
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2.1 REGULATORY FRAMEWORK WHC-SD-W10
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^..." ;_:.. :.^ .^.y^ WHC-SD-W100-T
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WHC-SD-W100-TI-003 Rev. 0 which the
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WHC-SD-W100-TI-003 Rev. 0 Type 1 wa
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3.3 TESTING APPROACH WHC-SD-W100-TI
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^.: fi WNC-SD-W100-TI-003 Rev. 0 Fi
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4.1 SCREENING TEST RESULTS WHC-SD-W
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WHC-SD-W100-TI-003 Rev. 0 4.1.3 The
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p Sam le Compressive Radiation stre
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WHC-SD-W100-TI-003 Rev. 0 Table 4-3
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..., TESTING RESULTS .^.CSSD-W-1OO-
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1.0 INTRODUCTION WHC-SD-W100-TI-003
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WHC-SD-W100-TI-003 Rev. 0 Waste For
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^-: -- ^ Component Waste Type 1 LET
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WHC-SD-W: JV-TI-VVJ ^cv. v APPENDIX
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Scope WHC-SD-W100-TI-003 Rev. 0 Sup
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00 V F-' Activity and Miltstone Cha
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WHC-SD-W100-TI-003 Rev. 0 Laborator
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WHC-SD-WIOO-TI-003 Rev. 0 APPENDIX
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16490 Chiaccothe Itoad Chagrin Fall
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ca-. tY•^_E Q . - - StoGkE4uip+!n
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Waste Type: WHC-SD-W100-TI-003 Rev.
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Stock E quipment Company A Unit of
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G' ,.,. d,_ s WHC-0-W100-TI-003 Rev
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-. LeachantSolution: Specimen Diame
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c^1, WHC-SD-W100-TI-003 Rev. 0 THER
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;=. .:^;. WHC-SD-W100-TI-003 Rev< 0
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Date: _ Leachability Time Point Lea
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23 Ninety ( 90) Day Immersion Test
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ty ,.. ='`F r...,, b Ly.. Specimen
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25 BIODEGRADATION TEST PROCEDURE St
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Date: WHC-SD-W100-TI-003 Rev. 0 BIO
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^_... ..^^ C:i1 Date: WHC-SD-W100-T
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Date: WHC-SD-W100-TI-003 Rev. 0 --
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f-^ -- WHC-SD-W100-TI-003 Rev. 0 2.
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^-..., 3•0 ASSAY FOR MEI'ALS 3.1
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WHC-SD-W100-TI-003 Rev. 0 APPENDIX
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WHC-SD-W100-TI-003 Rev. 0 STOCK EQU
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19 SCOPE AND APPLICATION WHC-SD-W10
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L:^3 ll Q. 4 AA :'ILTEP.S WHC-0-W10
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WHC-SD-W100-TI-003 Rev. 0 -, Proced
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WHC-SD-W100-TI-003 Rev. 0 Procedure
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(FM WHC-SD-W100-TI-003 Rev. 0 Proce
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C... 6 Wet Waste Sample Contains no
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CHARACTERIZATION DATA Part A: Overv
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Grit Specie or MaterialOverall Cont
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WHC-SD-W100-TI-003 Rev. 0 The incin
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WHC-SD-W100-TI-003 Rev. 0 183-H BAS
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WHC-SD-W100-TI-003 Rev. 0 June - Se
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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WHC-SD-W100-TI-003 Rev. 0 BASINS 3
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WHC-SD-W100-TI-003 Rev. 0 ---------
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J. L. Westcott Page 3 June 1, 1992
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•N`^C-Sf1-"d100-71-003 Rev. 0 ,S'
Page 195 and 196: CONTAINER /NFORMATlO N: `d"-C-Sn-'w
Page 197 and 198: ONTANVER BVFORMA SI7 E: AMOUN=i 8 G
Page 199 and 200: LOT WRAP 2A.4 SHEET 7.XLS RECOMMEND
Page 201 and 202: LOT WRAP 2A.5 SHEET 8.XLS RECOMMEND
Page 203 and 204: .:•n-,,, LOT WRAP 2A.6 SHEET 9.XL
Page 205 and 206: LOT WRAP 2A.7 SHEET 10.XLS RECOMMEN
Page 207 and 208: PHYSICAL DESCR/PTTON: V-r-S?-W100-T
Page 209 and 210: ,.: Westinoause Harlford COMM WHC-S
Page 211 and 212: O I tA SHEETII.XLS ;, LOT WRAP2A.2
Page 213 and 214: CONTAINER /NFORMAT/ON: DOSE: SIZE:
Page 215 and 216: PU33-11-1992 09:48 FROM EDS/qRI$ir
Page 217 and 218: LOT WRAP 2A 10 Slf-EET 14.)C,S RECO
Page 219 and 220: qN i: 105N-89-1097 105N-89-1098 105
Page 221 and 222: SIZE: DOSE: 5 GAL 1 1@15 Mr 30 GAL
Page 223 and 224: WHC-SD-W100-TI-003 Rev. 0 Westtngho
Page 225 and 226: LOT WRAP A2.14 SHEET 18.XLS RECOMME
Page 227 and 228: ---- - LOT WRAP ZA.13 SHEET 17.XLS
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Page 231 and 232: --^ WHC-SD-W100-TI-003 Rev. 0 APPEN
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Page 235 and 236: Table 1 Candidate Waste Forms Absor
Page 237 and 238: --- -Aauaspt and Pe-liroset WHC-SD-
Page 239 and 240: - '^ - qev. r' Literature Search WR
Page 241 and 242: Dow Polymer WHC-SD-W100-TI-003 Rev.
Page 243 and 244: L im e Literature Search WRAP 2A Pa
Page 245: The report compares the 7eachabilit
Page 249 and 250: Package #1: Package #2: WHC-SD-W100
Page 251 and 252: WHC-SD-W100-TI-003 Rev. 0 SURVEY OF
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Page 259 and 260: WHC-SD-W100-TI-003 Revo 0 Bibliogra
Page 261 and 262: WHC-SD-W100-TI-003 Rev. 0 A. P. Tos
Page 263 and 264: OAK R1DGE NATIONAL LABORATORY OPERA
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Page 269 and 270: WHC-SD-W100-TI-003 Revo 0 A report
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Page 273 and 274: WHC-SD-W100-TI-003 Rev. 0 reprocess
Page 275 and 276: WHC-SD-W100-TI-003 Rev. 0 STR?.THGI
Page 277 and 278: Contained under four reports: WHC-S
Page 279 and 280: ^.yo F-SD-W"00-7-003 Rev. 0 THERMOS
Page 281 and 282: WHC-SD-W100-TI-003 Rev. 0 The techn
Page 283 and 284: loomi^^lC& 111111111111F .^^.\ West
Page 285 and 286: û9^c ?fi. ...^ .._-, WHC-SD-W100-T
Page 287 and 288: Stock Equipment Company WHC-SD-WI00
Page 289 and 290: ^ i w STOCK EOUIPMENT COMPANY 14-OC
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WHC-SD-W100-TI-003 Rev. 0 Russ Czel
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Stock Equipment Company 3:0 -SCFIED
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THERMAL CYCLING SAMPLES BEFORE THE
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