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Ikelic - Alliance Digital Repository

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STATUS OF COAL PROJECTS (Underline denotes changes since June 1994)<br />

COMMERCIAL AND R&D PROJECTS (Continued)<br />

MRS COAL HYDROGENATOR PROCESS PROJECT - British Gas pic and Osaka Gas Company Ltd. (C-400)<br />

Work is being carried out jointly by British Gas pic and the Osaka Gas Company<br />

Ltd. of Japan, to produce methane and valuable<br />

liquid hydrocarbon coproducts by the direct thermal reaction of hydrogen with coal. A novel reactor, the MRS (for Midlands<br />

Research Station) coal hydrogenator incorporating internal gas recirculation in an entrained flow system has been developed to<br />

provide a means of carrying out the process without the problems of coal agglomeration, having to deal with excessive coal fines, or<br />

excessive hydrogenation gas preheat as found in earlier work.<br />

A 200 kilogram per hour pilot plant was built to prove the reactor concept and to determine the overall process economics. The<br />

process uses an entrained flow reactor with internal gas recirculation based on the Gas Recycle Hydrogenator (GRH) reactor that<br />

British Gas developed to full commercial application for oil gasification.<br />

Following commissioning of the plant in October 1987, a test program designed to establish the operability of the reactor and to<br />

of the commercial process concept confirmed<br />

obtain process data was successfully completed. An Engineering and Costing Study<br />

overall technical feasibility and exceptionally high overall efficiency giving attractive economics.<br />

In December 1988, the sponsors went ahead with the second stage of the joint research program to carry out a further two year<br />

development program of runs at more extended conditions and to expand the pilot plant facilities to enable more advanced testing<br />

to be carried out.<br />

Through 1989, performance tests have been conducted at over 43 different operating conditions. Four different coals have been<br />

tested, and a total of 10 tonnes have been gasified at temperatures of between 780 degrees centigrade and 1,000 degrees centigrade.<br />

The initial plant design only allowed tests of up to a few hours duration to be carried out. The plant was modified in early 1990 to<br />

provide continuous feeding of powdered coal and continuous cooling and discharge of the char byproduct. Over 50 tonnes of coal<br />

was successfully gasified during 21 performance tests with a cumulative feeding time of 18 days. Continuous operation for periods<br />

of up to 67 hours was achieved.<br />

A full-scale physical model of a 50 tonne per day development-scale Coal Hydrogenator was commissioned in 1992. This has<br />

enabled the scaleup of the hydrogenator to be studied. A range of coal injectors at feedrates of up to 50 tonnes per day have been<br />

successfully tested.<br />

The next stage of development is expected to be at 50 tonnes per day and consideration is being given for this to be built in Japan.<br />

- MW. KELLOGG UPGRADING OF REFINERY OIL AND PETROLEUM COKE PROJECT MW.<br />

States Department of Energy (C-404)<br />

Kellogg Company and United<br />

In September 1993, the Department of Energy (DOE) selected the M.W. Kellogg Company, Houston, TX, to study a technology<br />

that could increase the efficiency of U.S. refineries by converting the heavy, difficult-to-process "bottom of the barrel"<br />

into commer<br />

cially<br />

useful products.<br />

As part of the $1.4 million, 3-year project, Kellogg will adapt a process originally developed for gasifying coal. The company will<br />

apply the technology to processing heavy slurry oil and the solid, coal-like petroleum coke often left after refineries extract lighter<br />

fuels such as gasoline, diesel and heating oil.<br />

Kellogg has been working with the Energy Department since the early 1980s to develop a fluid bed coal gasification and combus<br />

tion processes. During the testing of the KRW fluid bed gasification process, petroleum coke was successfully gasified. More<br />

recently, a high-velocity Transport reactor design has successfully been piloted in an effort to reduce the capital cost of the coal<br />

gasification reactor.<br />

Kellogg was able to demonstrate gasification of paraffinic and aromatic naphthas in the Transport reactor and proposed to extend<br />

this technology to gasification of heavier refinery residua. Initial testing under the DOE contract was with a heavy crude emulsion-<br />

Results indicated that the quality of the gas produced depended significantly on the type of solids circulated in the Transport reac<br />

tor. An inert material resulted in low hydrogen yields and high olefinic content of the product gas. With a more active solid, high<br />

hydrogen yield was obtained and the gas contained essentially no hydrocarbons heavier than methane. Of significance, all of the<br />

metals in the crude feed were deposited on the circulating solid.<br />

Development will continue in 1995 on other refinery residua and on petroleum coke.<br />

- NEDO IGCC PROJECT New<br />

Energy and Industrial Technology Development Organization (NEDO) (C-408)<br />

NEDO is studying integrated gasification combined cycle technology as part of a national energy program. A 200 ton per day pilot<br />

plant has been constructed at the Nakoso power station site in Iwaki City, Fukushima Prefecture. The pilot began operating in ^<br />

March 1991.<br />

4-66<br />

"<br />

SYNTHETIC FUELS REPORT, JANUARY 1995

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