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Ikelic - Alliance Digital Repository

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OIL SANDS<br />

timized combination of the HSC and the ROSE<br />

(Residuum Oil Super-Critical Extraction) Process<br />

has been developed and offered jointly by TEC<br />

and Kerr-McGee Corporation, the licensor of the<br />

ROSE process.<br />

In this combination, HSC residue is further deas-<br />

phalted by the ROSE process to recover asphal<br />

tene free oil (DAO), which is utilized after<br />

hydrotreating, as an additional feedstock to an<br />

FCC or hydrocracker (Figure 2).<br />

An innovative concept in this process combina<br />

tion is to optimize the thermal cracking conver<br />

sion in the HSC process and the depth of extrac<br />

tion in the ROSE process so that the total liquid<br />

product yield is maximized. The flexibility af<br />

forded by the HSC process in selecting thermal<br />

conversion levels is a prerequisite for this op<br />

timization because optimal conversion by ther<br />

mal cracking for most feedstocks is higher than<br />

conventional visbreaking. Hydrotreating also<br />

plays an important role in completing this<br />

primary upgrading scheme.<br />

The advantage of this system is an extra high liq<br />

uid yield by a combination of relatively simple<br />

and inexpensive processes.<br />

FIGURE 2<br />

HSC-ROSE PROCESS<br />

riwidm<br />

"-<br />

1<br />

""d<br />

Cend*n*d AtphaltenM<br />

SOURCE: TOYO<br />

HSC Di!ill!<br />

OAO<br />

Hy*o-<br />

... taatw, ,<br />

3-16<br />

The residue from the HSC-ROSE process is a<br />

condensed asphaltene with a high softening<br />

point (R&B 200C) which Is produced as solid<br />

flakes.<br />

This residue is used as solid fuel in coal-fired<br />

boilers. Due to its relatively high volatile matter<br />

content (35-45 weight percent), combustibility is<br />

much better than petroleum cokes from the con<br />

ventional coking process (volatile matter content<br />

is less than 10 weight percent).<br />

In addition to its use as a quality fuel, the HSC-<br />

ROSE residue is an effective coking binder for<br />

production of high-quality cokes from low-grade<br />

carbon materials such as non-coking coals, lig<br />

nites and even from peats, bagasse and waste<br />

products of the forestry industry.<br />

Some examples of product yields from the HSC<br />

and the HSC-ROSE process, in comparison with<br />

conventional processes, are shown in Table 1<br />

(next page).<br />

Relative investment costs for each process are<br />

also given in Table 1 for a quick comparison in<br />

order of magnitude.<br />

####<br />

PRODUCTION PROBLEMS IN COLD LAKE<br />

SHALEY OIL SANDS ANALYZED<br />

The highly viscous bitumen from the Cold Lake<br />

reservoir in Alberta, Canada is produced by the<br />

Cyclic Steam Stimulation (CSS) process. The<br />

clean oil sands of the Cold Lake reservoir<br />

generally produce well, but the shaley oil sands<br />

with imbedded clasts have experienced lower<br />

bitumen production and lower steam injectivity.<br />

A paper by T. Chakrabarty of Imperial Oil<br />

Resources Limited and J. Longo of Exxon<br />

Production Research Company in the December<br />

issue of The Journal of Canadian Petroleum Tech<br />

nology presents an analysis of the problem.<br />

THE SYNTHETIC FUELS REPORT, JANUARY 1995

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