Ikelic - Alliance Digital Repository
Ikelic - Alliance Digital Repository
Ikelic - Alliance Digital Repository
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OIL SANDS<br />
timized combination of the HSC and the ROSE<br />
(Residuum Oil Super-Critical Extraction) Process<br />
has been developed and offered jointly by TEC<br />
and Kerr-McGee Corporation, the licensor of the<br />
ROSE process.<br />
In this combination, HSC residue is further deas-<br />
phalted by the ROSE process to recover asphal<br />
tene free oil (DAO), which is utilized after<br />
hydrotreating, as an additional feedstock to an<br />
FCC or hydrocracker (Figure 2).<br />
An innovative concept in this process combina<br />
tion is to optimize the thermal cracking conver<br />
sion in the HSC process and the depth of extrac<br />
tion in the ROSE process so that the total liquid<br />
product yield is maximized. The flexibility af<br />
forded by the HSC process in selecting thermal<br />
conversion levels is a prerequisite for this op<br />
timization because optimal conversion by ther<br />
mal cracking for most feedstocks is higher than<br />
conventional visbreaking. Hydrotreating also<br />
plays an important role in completing this<br />
primary upgrading scheme.<br />
The advantage of this system is an extra high liq<br />
uid yield by a combination of relatively simple<br />
and inexpensive processes.<br />
FIGURE 2<br />
HSC-ROSE PROCESS<br />
riwidm<br />
"-<br />
1<br />
""d<br />
Cend*n*d AtphaltenM<br />
SOURCE: TOYO<br />
HSC Di!ill!<br />
OAO<br />
Hy*o-<br />
... taatw, ,<br />
3-16<br />
The residue from the HSC-ROSE process is a<br />
condensed asphaltene with a high softening<br />
point (R&B 200C) which Is produced as solid<br />
flakes.<br />
This residue is used as solid fuel in coal-fired<br />
boilers. Due to its relatively high volatile matter<br />
content (35-45 weight percent), combustibility is<br />
much better than petroleum cokes from the con<br />
ventional coking process (volatile matter content<br />
is less than 10 weight percent).<br />
In addition to its use as a quality fuel, the HSC-<br />
ROSE residue is an effective coking binder for<br />
production of high-quality cokes from low-grade<br />
carbon materials such as non-coking coals, lig<br />
nites and even from peats, bagasse and waste<br />
products of the forestry industry.<br />
Some examples of product yields from the HSC<br />
and the HSC-ROSE process, in comparison with<br />
conventional processes, are shown in Table 1<br />
(next page).<br />
Relative investment costs for each process are<br />
also given in Table 1 for a quick comparison in<br />
order of magnitude.<br />
####<br />
PRODUCTION PROBLEMS IN COLD LAKE<br />
SHALEY OIL SANDS ANALYZED<br />
The highly viscous bitumen from the Cold Lake<br />
reservoir in Alberta, Canada is produced by the<br />
Cyclic Steam Stimulation (CSS) process. The<br />
clean oil sands of the Cold Lake reservoir<br />
generally produce well, but the shaley oil sands<br />
with imbedded clasts have experienced lower<br />
bitumen production and lower steam injectivity.<br />
A paper by T. Chakrabarty of Imperial Oil<br />
Resources Limited and J. Longo of Exxon<br />
Production Research Company in the December<br />
issue of The Journal of Canadian Petroleum Tech<br />
nology presents an analysis of the problem.<br />
THE SYNTHETIC FUELS REPORT, JANUARY 1995