Poster Session, Thursday, June 17Theme F686 - N1123New Trends <strong>in</strong> Tribology and Nano- Mesoscale TribologyY. SoydanSakarya University, Faculty of Mechanical Eng<strong>in</strong>eer<strong>in</strong>g, Turkey.Abstract—In this paper, the author presents a review of new trends <strong>in</strong> tribology among which are the micro to meso and nanoscaletransition, the development of new experimental apparatus, nanotribological applications of bioeng<strong>in</strong>eer<strong>in</strong>g, biomimetic, automotive,manufactur<strong>in</strong>g, lubrication, surface eng<strong>in</strong>eer<strong>in</strong>g, magnetic storage systems materials, micro or nanoelectromechanical systems etc.Tribology is the science of <strong>in</strong>teract<strong>in</strong>g surfaces <strong>in</strong> relativemotion. Nanotribology can be def<strong>in</strong>ed as the <strong>in</strong>vestigationsof <strong>in</strong>terfacial processes occurr<strong>in</strong>g dur<strong>in</strong>g friction,nano<strong>in</strong>dentation, th<strong>in</strong>-film lubrication, and wear at thenanometer scale. Understand<strong>in</strong>g and controll<strong>in</strong>g matter at thenanoscale <strong>in</strong>terests researchers <strong>in</strong> the sciences and <strong>in</strong>dustrybecause materials properties at the nanoscale can be verydifferent from those at a macro scale. Nanotribology today,widely uses many new <strong>in</strong>struments designed over the last 50years, such as AFM [1], the FFM [2], SFA, STM and QCMare able to perform experiments on well characterized modelsystems at the nanoscale [3]. From the technical po<strong>in</strong>t ofview, however, some difficulties take place if wear is spottedwith a friction force microscope. The suggested approach isbased on the comb<strong>in</strong>ation friction force and dynamic forcemicroscopy [4]. Studies on orig<strong>in</strong> of tribological features atthe atomic scale, s<strong>in</strong>ce they highly depends on the surface<strong>in</strong>teractions, us<strong>in</strong>g sophisticated experimental andcomputational tools should be utilized <strong>in</strong> order to provide adeeper understand<strong>in</strong>g of friction <strong>in</strong> nanoscale [5].Fig.2. Schematic image of sk<strong>in</strong> structure with different layers [9]The tribological applications <strong>in</strong> current eng<strong>in</strong>e materialsare argued <strong>in</strong> scientific community. Several suggested<strong>in</strong>terfaces are go<strong>in</strong>g to be considered with a brief history ofmaterials used and some explanation of future trends [11].Tribology associated with the ma<strong>in</strong>tenance of productionequipment is called ma<strong>in</strong>tenance tribology [10].Control of the structure and composition of coat<strong>in</strong>gs atthe nanoscale is an <strong>in</strong>terest<strong>in</strong>g scientific subject comb<strong>in</strong>edwith an <strong>in</strong>dustrial challenge. In recent years, numerousexcit<strong>in</strong>g developments have been done <strong>in</strong> the fields oftribological and solid lubricant coat<strong>in</strong>gs (Fig.3). One of mostimportant development is the coat<strong>in</strong>g for dry and near drymach<strong>in</strong><strong>in</strong>g applications. No doubt that such coat<strong>in</strong>gs willbecome available <strong>in</strong> the near future [12].Fig.1. Example of MEMS components after laboratory wear test [9].Additionally, MEMS/NEMS and BioMEMS/BioNEMS arealso used <strong>in</strong> electromechanical, electronics, chemical, andbiological applications. Therefore, MEMS/NEMS materialsneed to exhibit good mechanical and tribological propertieson the micro/nanoscale. Methods need to be developed toenhance adhesion between biomolecules and the devicesubstrate. Fig.1 shows a polysilicon, multiple microgearspeed reduction unit after laboratory wear tests conducted[6].Biologically <strong>in</strong>spired design or adaptation or derivationfrom nature is named as “biomimetics.” Several creatures<strong>in</strong>clud<strong>in</strong>g <strong>in</strong>sects, spiders, and lizards, have developed aunique cl<strong>in</strong>g<strong>in</strong>g skill that utilizes dry adhesion [7]. On theother hand, for most people, clean<strong>in</strong>g and ma<strong>in</strong>tenance oftheir sk<strong>in</strong> is a daily process. A systematic characterization ofthe friction and adhesion properties of sk<strong>in</strong> and sk<strong>in</strong> creamare also carried out on the nano- and macroscale, which isessential to develop better sk<strong>in</strong> care products and advancebiological, dermatology, and cosmetic science (Fig.2) [8].Moreover, process tribology plays an important role <strong>in</strong>the automobile manufactur<strong>in</strong>g <strong>in</strong>dustry. It ma<strong>in</strong>ly concernsabout friction, lubrication and wear dur<strong>in</strong>g the metal form<strong>in</strong>gprocess<strong>in</strong>g where four elements of die, work, lubricant andexternal conditions [10].Fig.3. Historical development of tribological coat<strong>in</strong>gs and solid lubricantfilms over the past 25 years on this subject.* Correspond<strong>in</strong>g author: soydan@sakarya.edu.tr[1] Deng H, Scharf TW, Barnard JA., J Appl Phys 1997;81:5396–8.[2] Schonherr H, Vancso GJ., Macromole cules 1997;30:6391–4.[3] O.M. Braun, A.G. Naumovets, Surface Science Reports 60 (2006)[4] J. E. Schmutza at al., Wear 268 (2010)[5] C.A.Charitidis, Int. Journal of Refractory Metals & Hard Mat.28 (2010)[6] B. Bhushan, Microelectronic Eng<strong>in</strong>eer<strong>in</strong>g 84 (2007).[7] B. Bhushan, Conference on Trends <strong>in</strong> Nanotribology, 2009[8] W. Tanga, B. Bhushan, Colloids and Surfaces : Bio<strong>in</strong>terfaces 76 (2010)[9] A. Shai, H.Maibach, R. Baran, Handbook of Cosmetic Sk<strong>in</strong> Care, 2001.[10] Y. Tsuchiya, Rev,ew of Toyota CRDL, 34, 1999.[11] E. P. Becker, Tribology International 37 (2004) .[12] C. Donneta, A. Erdemir, Surface and Coat<strong>in</strong>gs Technology, (2004).6th Nanoscience and Nanotechnology Conference, zmir, 2010 745
PPP andP (.cm).Poster Session, Thursday, June 17Theme F686 - N11230BTemperature Dependent Electrical Conductivity of Ardel D-100 / MWCNT Nanocomposite121Murat ÇalkanP P, Dolunay akarPUMerih Ser<strong>in</strong>UP P*1PDepartment of Physics, Yildiz Technical University, stanbul 34210, Turkey2PDepartment of Chemistry, Yildiz Technical University, Istanbul 34210, TurkeyTAbstractT-In this work, ARDEL D-100/MWCNT (1.5 wt%) nanocomposite was studied. The characterization of the electrical properties ofprepared nanocomposite with respect to the temperature were studied. Direct-current measurements with a cont<strong>in</strong>uously chang<strong>in</strong>g temperatureof sample were presented. The resistivity of the ARDEL D-100 was decreased by 10 order of magnitude onaddition of 1.5wt%of MWCNT.Multiwalled carbon nanotubes (MWCNTs) areconsidered to be the ideal re<strong>in</strong>forc<strong>in</strong>g agent forhigh-strength polymer composites, because of theirfantastic mechanical strength, high electrical and thermalconductivity and high aspect ratio [1].ARDEL D-100 which is high eng<strong>in</strong>eer<strong>in</strong>g thermoplasticand an amorphous aromatic polyester of bisphenol-A withterephthalic and isophthalic acid (50/50) was studied. It hashigh heat-deflection temperature, high impact strength andgood electrical properties [2].Our aim was to obta<strong>in</strong> an <strong>in</strong>sight of the mechanism of theconductivity of ARDEL D-l00/MWCNT nanocompositeand to determ<strong>in</strong>e the characteristic glass transitiontemperature, Tg, of the sample. For this purpose, thecharacterization of the electrical properties of preparednanocomposite with respect to the temperature werestudied. Direct-current measurements with a cont<strong>in</strong>uouslychang<strong>in</strong>g temperature of sample were presented.ARDEL D-100/MWCNT (1.5 wt%) nanocomposite wasprepared by melt mix<strong>in</strong>g at 300 °C, 50 rpm <strong>in</strong> 5 m<strong>in</strong>. Thiswas carried out <strong>in</strong> the Leibniz Institute of Polymer ResearchDresden. The film of melt compounded ARDEL D – 100 /MWCNT (1.5wt%) nanocomposite was prepared viasolvent cast<strong>in</strong>g method on glass substrate.The volume resistivity of melt mix<strong>in</strong>g sample wasdeterm<strong>in</strong>ed by measur<strong>in</strong>g the DC resistance on the pressedplates. The measurement was performed on strips cut fromthe pressed sheets us<strong>in</strong>g a four-po<strong>in</strong>t text fixture comb<strong>in</strong>edwith a Keithley DMM 2000 electrometer. Prior to themeasurement, the surface of the sample was cleaned withethanol. This was carried out <strong>in</strong> The Leibniz Institute ofPolymer Research Dresden.For the electrical characterization, dark conductivity ofproduced films were measured as a function of temperatureus<strong>in</strong>g a Janis liquid nitrogen vacuum cryostat, hav<strong>in</strong>g athermocouple <strong>in</strong> good thermal contact with the sample.Samples were placed on top of a copper plate that is heatedby a bolt heater embedded with<strong>in</strong>.Temperature was controlled by Lakeshore TemperatureController 331. Dark conductivity measurements wereaccomplished us<strong>in</strong>g a programmable Keitley 6517A digitalelectrometer/voltage source <strong>in</strong>terfaced to a computer.The temperature dependence of conductivity wasmeasured as the temperature be<strong>in</strong>g <strong>in</strong>creased at a constant-1rate of 3K m<strong>in</strong>PP. The film thickness was determ<strong>in</strong>edfrom the area formed by spread<strong>in</strong>g polymer solution withknown volume and concentration.The change <strong>in</strong> the conductivity of the sample wasexperimentally measured under a constant electrical field.-6The measurements were carried out <strong>in</strong> l0PPTorr vacuum andthe dark. The electrical conductivity of the polymer wasmeasured <strong>in</strong> AI/ARDEL D-100/MWCNT/A1 structureover the temperature range of 300-520K.The volume resistivity of pure ARDEL D-100 was14measured as 1.54x10P The volume and specificresistivity of the nanocomposite sample was measured as453.5lxl0P P(.cm) and 8.56 xl0P P(.cm), respectively, at roomtemperature.In summary, we showed that the resistivity of the ARDELD-100 was decreased (conductivity <strong>in</strong>creased) by ten ordersof magnitude on addition of 1.5wt% MWCNT.The electrical conductivity values of ARDEL D-100/MWCNT with <strong>in</strong>creas<strong>in</strong>g temperature, which would beuseful for a wide range of applications, were achieved. Thisnanocomposite film showed semiconductor behavior withthe exponential variation of <strong>in</strong>verse temperaturedependence of electrical conductivity. Therefore, it ispossible to expla<strong>in</strong> the conduction mechanism of thenanocomposite by us<strong>in</strong>g exist<strong>in</strong>g solid state theory.This work was partially supported by the Leibniz Instituteof Polymer Research Dresden, and by Yildiz TechnicalUniversity, Scientific Research Project Coord<strong>in</strong>ation, underGrant No. BAPK-2001-01-01-01 andBAPK-2007-01-01-07.*Correspond<strong>in</strong>g author: ser<strong>in</strong>@vildiz.edu.tr[1] EW. Wong, PE. Sheehan, CM. Lieber. Science, 277:1971–5,(1997).[2] D. Sakar, O. Cankurtaran and F. Karaman, Journal ofApplied Polymer Science, 98(6): 2365-2368 (2005).6th Nanoscience and Nanotechnology Conference, zmir, 2010 746
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