Poster Session, Thursday, June 17Theme F686 - N1123Free vibration analysis of carbon nanotubes based on nonlocal cont<strong>in</strong>uum and gradientelasticity theoriesÖmer Civalek 1 , Bekir Akgöz, Hakan Ersoy1 Akdeniz University, Civil Eng<strong>in</strong>eer<strong>in</strong>g Department, Division of MechanicsAntalya-TURKIYE, Tel: + 90- 242-310 6319, Fax: + 90-242-310 6306Abstract- Free vibration analysis of s<strong>in</strong>gle walled carbon nanotubes (CNT) is presented based on the Euler-Bernoulli beamtheory. The size effect is taken <strong>in</strong>to consideration us<strong>in</strong>g the Er<strong>in</strong>gen’s non-local elasticity theory. Gradient elasticity theory isalso adopted for model<strong>in</strong>g. The govern<strong>in</strong>g differential equations for CNT vibration is be<strong>in</strong>g solved us<strong>in</strong>g the differentialquadrature (DQ) method. Numerical results are presented to show the effect of nonlocal behavior on frequencies of CNT.The concept of carbon nanotubes (CNTs) was first<strong>in</strong>troduced <strong>in</strong> 1991 by Iijima [1] <strong>in</strong> Japan. Reviews on thedevelopment and application of such nano structures havebeen presented [2]. So, the studies of mechanical behaviorsof carbon nanotubes have be<strong>in</strong>g attracted more and moreattentions of scientists <strong>in</strong> the world and also have become anew research area of applied mechanics [3,4]. In thepresent work, the consistent govern<strong>in</strong>g equations for thebeam model for CNTs are derived for free vibrationanalysis. Nonlocal beam and couple stress beam theoriesare adopted for model<strong>in</strong>g. It is known that, the stress stateof any body at a po<strong>in</strong>t x is related to stra<strong>in</strong> state at the samepo<strong>in</strong>t x <strong>in</strong> the classical elasticity. But this theory is notconflict the atomic theory of lattice dynamics andexperimental observation of phonon dispersion. As statedby Er<strong>in</strong>gen [5] the l<strong>in</strong>ear theory of nonlocal elasticity leadsto a set of <strong>in</strong>tegropartial differential equations for thedisplacements field for homogeneous, isotropic bodies.Accord<strong>in</strong>g to the nonlocal elasticity theory of Er<strong>in</strong>gen’s,the stress at any reference po<strong>in</strong>t <strong>in</strong> the body depends notonly on the stra<strong>in</strong>s at this po<strong>in</strong>t but also on stra<strong>in</strong>s at allpo<strong>in</strong>ts of the body. This def<strong>in</strong>ition of the Er<strong>in</strong>gen’snonlocal elasticity is based on the atomic theory of latticedynamics and some experimental observations on phonondispersion. In the present manuscript two differentapproaches are used for model<strong>in</strong>g of carbon nanotubes.Euler-Bernoulli beam-nonlocal model [5]42 W22 WEI A W ( e0a)A 0 (1)42xxEuler-Bernoulli beam-gradient elasticity theory [6] Wx Wx4422EI g EI A 0 (2)447Table 1. First three frequencies (10) of S-S carbon8nanotubes via gradient theory ( L 510m ,312 2 2300kg/ m , m , t 510 10E 10 N /m )Modeg/L (DQ results)0.005 0.015 0.1251 0.10388 0.10669 0.113742 0.41065 0.41103 0.423013 0.91863 0.92007 0.934857Table 2. First three frequencies (10) of S-S carbon8nanotubes via nonlocal theory( L 510m ,312 2 2300kg/ m , m , t 510 10E 10 N /m )Mode (e 0 a) 2 (DQ results)0 2 41 0.10273 0.10158 0.099622 0.40967 0.40863 0.405533 0.9172 0.90864 0.90637[1] S. Iijima, Nature, 354, 56 (2001).[2] D. Qian, G.J. Wagner, W.K. Liu, Appl. Mech. Rev.,55, 495(2002).[3] C.M. Wang, V.B.C. Tan, T.Y. Zhang, J. Sound Vib.294, 1060 (2006).[4] J.N. Reddy, S.D. Pang, J. Appl. Phys. 103, 023511(2008).[5] A.C. Er<strong>in</strong>gen, J. Appl. Phys., 54, 4703 (1983).[6] S.P. Beskou, D. Polyzos, D.E. Beskos, Struct. Eng.Mech. 15, 705(2003).[7] Ö. Civalek, Eng<strong>in</strong>eer<strong>in</strong>g Structures, 26, 171(2004).The results obta<strong>in</strong>ed by differential quadrature (DQ)method [7] us<strong>in</strong>g two higher order elasticity theories arelisted <strong>in</strong> Tables 1-2. In table 1, first three frequencies ofsimple supported (S-S) carbon nanotubes are listed fordifferent gradient parameter. It is shown that, thefrequencies are <strong>in</strong>creased gradually with the <strong>in</strong>creas<strong>in</strong>gvalue of g for all modes. Nonlocal parameter also affectedon frequencies (Table 2). When the nonlocal parametersare <strong>in</strong>creased, the values of frequencies are decreased,significantly. It is possible to say that, the classical beamtheories can not to capture to size effect on mechanicalbehavior of nano sized structures. So, it is suitable to usesome higher order cont<strong>in</strong>uum theory such as nonlocalelasticity theory or gradient stra<strong>in</strong> theory to <strong>in</strong>vestigate thesize effect on mechanical behaviour of nano/microstructures.6th Nanoscience and Nanotechnology Conference, zmir, 2010 705
Poster Session, Thursday, June 17Theme F686 - N1123Hexagonal Boron Nitride (h-BN)/Polyimide Hybrid FilmsCanan Kızılkaya * , Yusuf Mülazim, M.Vezir Kahraman, Nilhan Kayaman Apohan, Atilla GüngörMarmara University, Department of Chemistry 34722 Istanbul/TurkeyAbstract - Polyimide (PI)/hexagonal boron nitride (h-BN) hybrid materials were prepared from a polyimide precursorand functionalized h-BN with a silane coupl<strong>in</strong>g agent by thermal imidization technique. Their surface morphologies,structures and thermal performances were determ<strong>in</strong>ed. The thermal characteristics of PI/ h-BN hybrid films were foundto be better than the polyimide without h-BN.Aromatic polyimide films have aroused a great deal of<strong>in</strong>terest as one of the attractive precursors for produc<strong>in</strong>gcarbon and graphite films <strong>in</strong> recent years. Compared withmost organic polymeric materials, PI exhibits superiorthermal stability and mechanical strength. Therefore, alarge number of PI compositions have been extensively<strong>in</strong>vestigated and most of them are well-suited for use asmatrix res<strong>in</strong>s, adhesives, and coat<strong>in</strong>gs for highperformanceapplications <strong>in</strong> the aerospace, electric, andmicro-electronic <strong>in</strong>dustries [1,2].Boron nitride is a ceramic material that is isoelectronicwith carbon. Much like carbon, it exists <strong>in</strong> multipleallotropic forms. The most common structure of boronnitride is the hexagonal form (h-BN). Hexagonal boronnitride has a graphite-like structure with strong bond<strong>in</strong>gwith<strong>in</strong> the planar, fused, six-membered r<strong>in</strong>gs and weak vander waals bond<strong>in</strong>g <strong>in</strong>-between layers. Along the c-axis forh-BN, boron and nitrogen atoms are stacked above eachother <strong>in</strong> alternat<strong>in</strong>g layers [ 3]. Because of its properties, ithas found uses <strong>in</strong> heat conductivity applications, electrical<strong>in</strong>sulation applications, corrosion resistance applications,lubrication applications, personal care applications, and asa plastic additive [4].In the present study, Polyimide (PI)/hexagonal boronnitride (h-BN) hybrid materials were prepared from apolyamic acid as a polyimide precursor and modified h-BN with a silane coupl<strong>in</strong>g agent. Am<strong>in</strong>oalkoxysilane isone of the most widely adopted silane coupl<strong>in</strong>g agents forthe modification of various oxide surfaces. This agent,uses for surface treatment of the filler to improve theaff<strong>in</strong>ity between filler and matrix, thereby significantly<strong>in</strong>creas<strong>in</strong>g the thermal properties of the composite. Insilane acts as a bridge to connect the ceramic filler and thepolymer matrix together, because it has two differentchemical structures at the two ends of the molecule. Themorphological, mechanical, and thermal properties of thepolyimide hybrid films with different h-BN content werecharacterized.In conclusion, h-BN conta<strong>in</strong><strong>in</strong>g PI hybrid materials wereprepared. ATR-FTIR study <strong>in</strong>dicates that the <strong>in</strong>organicnetwork had formed dur<strong>in</strong>g imidization. Themorphological study proved that the h-BN particles <strong>in</strong> thepolyimide matrix is dispersed homogeneously. Thethermal stability of the hybrid materials improved with the<strong>in</strong>creas<strong>in</strong>g amount of h-BN <strong>in</strong> the compositions. TheLimit<strong>in</strong>g Oxygen Index results <strong>in</strong>creased from 32.0 to42.6. The h-BN conta<strong>in</strong><strong>in</strong>g hybrid materials show fireresistance than the pure polyimide. The mechanicalproperties show that the polyimides/h-BN hybrid materialsare hard and brittle compared with pure polyimide. Thesolvent and chemical resistance experiments for allmaterials show good performance.Figure 1: SEM Micrographs of PI/h-BN 0.5*Correspond<strong>in</strong>g author: ckizilkaya@gmail.com[1] C.Kızılkaya ,S. Karataş , N. K. Apohan , A. Güngör, Journalof Applied Polymer Science, 115, 3256-3264, (2010).[2] S Karatas, N.K. Apohan, H. Demirer, A. Gungor Polym.Adv. Technol., 18,490–496 (2007)[3] M.T. Huang, H. Ishida, Surf. Interface Anal.,37, 621–627(2005).[4] J. Eichler, C. Lesniak, J European Ceramic Society, 28,1105–1109, ( 2008)..6th Nanoscience and Nanotechnology Conference, zmir, 2010 706
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