11.07.2015 Views

Boreskov Institute of Catalysis of the Siberian Branch of Russian ...

Boreskov Institute of Catalysis of the Siberian Branch of Russian ...

Boreskov Institute of Catalysis of the Siberian Branch of Russian ...

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

OP-IV-2LACTIC ACID AS A BACKGROUND CHEMICAL FOR A«WHITE CHEMICAL INDUSTRY» DEVELOPMENTV.V. Kolbakov*, R.A. Kozlovskiy**, V.N. Parmon***, V.F. Shvets***Nordbiochem Ltd., Kuuse 2, Põlva, 63303 Estonia, e-mail: info@nordbiochem.eu**Mendeleev University <strong>of</strong> Chemical Technology <strong>of</strong> Russia, Chair <strong>of</strong> PetrochemicalSyn<strong>the</strong>sis, 9 Miusskaya Square, Moscow, 125047, Russia,tel/fax: +7(499)978-95-54, e-mail: shvets@muctr.edu.ru***<strong>Boreskov</strong> <strong>Institute</strong> <strong>of</strong> Catalysys SB RAS, Novosibirsk, RussiaThe growing oil demand, high oil prices and lack <strong>of</strong> perspectives <strong>of</strong> substantial increasing<strong>of</strong> oil production were <strong>the</strong> main reasons for <strong>the</strong> development <strong>of</strong> new industry <strong>of</strong> motor fuelproduction from renewable sources based on carbohydrates and vegetable oils. Progress in <strong>the</strong>development <strong>of</strong> new technologies <strong>of</strong> renewable raw materials transformations to fuels makesit possible to displace now up to 10% <strong>of</strong> fossil fuels to biodiesel and bioethanol. Moreover apr<strong>of</strong>itability <strong>of</strong> a large number <strong>of</strong> petrochemical manufactures is going down because <strong>of</strong> <strong>the</strong>growing oil prices. For many petrochemicals it becomes critically low and for some <strong>of</strong> <strong>the</strong>m -negative and <strong>the</strong>ir production were closed (e.g. glycerol, based on propylene, lactic acid,based on ethylene or propylene, and o<strong>the</strong>rs). In <strong>the</strong>se situation <strong>the</strong> same raw materials <strong>of</strong>vegetable origin, as for bi<strong>of</strong>uels production, becomes competitive with oil for many <strong>of</strong>commodity chemical intermediate production. So unsaturated acids produced from vegetableoils are good raw materials for manufacture <strong>of</strong> alfa olefins, dicarboxilic acids and o<strong>the</strong>rproducts. Cheap glycerol, produced from vegetable oils, becomes attractive intermediate formany o<strong>the</strong>r chemical products. But <strong>the</strong> largest raw material source for commodity chemicalintermediate production is glucose and sugars which can be isolated from vegetable sources<strong>of</strong> different kind, or produced by means <strong>of</strong> biotechnological methods from vegetablecarbohydrates <strong>of</strong> different origin (starch from corn, wheat, potatoes; cellulose from wood,straw, wood dust and so on). Progress in biotechnology, large resources and low andcomparatively stable prices <strong>of</strong> vegetable raw materials permanently make <strong>the</strong> list <strong>of</strong>chemicals, produced from sugars and competitive with petrochemicals, longer and longer.Now <strong>the</strong> list includes ethanol, lactic acid, 1,3-propanediol, polyhydroxyalkanoates, pyruvicacid and some o<strong>the</strong>r products. The first two chemicals are <strong>the</strong> source for production <strong>of</strong> a hugenumber <strong>of</strong> o<strong>the</strong>r products many <strong>of</strong> which are ecologically friendly or biodegradable. So weare witnesses now <strong>of</strong> <strong>the</strong> birth <strong>of</strong> new kind <strong>of</strong> industrial chemistry which could be called«white chemistry». The «white chemistry» includes biotechnology, is based on sugars, isopposite to «black chemistry», based on oil, and corresponds to a part <strong>of</strong> «green chemistry»,142

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!