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OP-IV-9A NEW GENERATION OF SUPER-THIN HYDROGEN FILTERINGPALLADIUM MEMBRANES (CREATING OF TECHNOLOGY ANDDEVELOPMENT OF PRODUCTION)Barelko V.V. 1 , Ivanyuk A.G. 2 , Danishevski A.L. 2 , Chepelenko V.N. 2 , Bykov L.A. 3 ,Baichtok Yu.K. 3 , Slovetski D.I. 3 , Ivanov I.V. 4 , Brizitski O.F. 4 , Terent’ev V.Ya. 41 Institute of Problems of Chemical Physics, Russian Academy of Sciiences, Chernogolovka,Moscow Region, e-mail: barelko@icp.ac.ru2 FUGP «Moscow plant on the treatment of special alloys», e-mail: chepelenko@mzss.ru3 «Chemphyst-Alloy LTD» Chernogolovka, e-mail: lbik@icp.ac.ru4 VNIIEF, Sarov, e-mail: brizitski@aven.visa44.vniief.ruIn this report we inform on the program that is represented by the above science,technology and commerce corporation. The aim of this program is the fastest application ofthe industrial production of the equipment to prepare super pure hydrogen from gaseousmixtures by the method of diffusion through membranes from palladium alloys.The actual importance of this task due to the orientation of the mankind to the hydrogentechnologies does not cause any doubt. The general assignment of hydrogen permeablematerials based on palladium alloys is directed to their application in various technologies ofthe hydrogen energy: the production of hydrogen by conversion of different hydrocarbons asalternative ecologically pure fuel in the auto industry and in the wide spectrum of equipmentswith fuel cells, in the metallurgy (the production of protective atmospheres), as well as in anumber of technologies in the chemical industry which transfers their schemes to«membrane» reactors (the preparation of ethylene, propylene, benzene, etc.).The main component of the developed composite membrane with the super thin diffusivelayer from the palladium alloy is the foil with thickness of 10 microns and lower. One of thekey elements of the developed technology providing to it the principal novelty and highcompetitive ability is the introduction to the process of stages, taken from the industrialtechnology for the production of tinsel gold in that the authors occupy the monopolepositions.The main task of the program is the forced development of the production of mentionedhydrogen filtering membranes which must provide the implementation leading positions forthe science technology corporation both on the forming Russian market and on the foreignmarkets for such items.The creation of selective hydrogen-filtering material with small thickness is the main butnot single task in the development and industrial production of hydrogen diffusive elements156
OP-IV-9for the separation of super pure hydrogen from gaseous mixture. The program also includessearch effective new diffusive alloys and the development of optimal construction of thedevices.Here are some characteristics of developed diffusive elements on base of compositemembranes including a selective filtering hydrogen membranes with 10 micron thickness.The special hydrogen filtering composite membrane at temperature of 550 °C, partialhydrogen pressure in the mixture of.0.6 MPa and the pressure of evolved hydrogen 0.15MPa sis equal to ~100 nm 3 H 2 /m 2 hour. For the developed diffusive elements the work temperatureis in the interval 400-700 °C.Presented below photos illustrated first construction decision of a composite filteringelement and also scheme for their testing in a laboratory reactor for production of sin-gasfrom methane.157
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Boreskov Institute of Catalysis of
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Mikhail G. Slinko,Honour ChairmanVa
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PLENARY LECTURES
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PL-1built up from an intrinsic cont
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PL-3DEVELOPMENT OF ZEOLITE-COATED M
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PL-4processes in order to evaluate
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PL-5CATALYTIC PARTIAL OXIDATION OF
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KEY-NOTE PRESENTATIONS
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KN-2GETTING TO THE POINT: FROM MOLE
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KN-3PROBLEMS AND PROSPECTS FOR IMRO
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KN-4remain out of the sight of rese
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KN-5SSITKA allows to study not only
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KN-6individual reaction stages with
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Section 1.Kinetics of catalytic rea
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OP-I-1-specialthat Г s /f changed
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OP-I-3-specialKINETIC MODELING OF L
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OP-I-4PARTIAL OXIDATION OF TOLUENE
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OP-I-5Also, the approach to modelin
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OP-I-6starch granules, but after a
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OP-I-8KINETICS OF CARBON MONOXIDE O
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OP-I-9CHAOTIC DYNAMICS IN THE THREE
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OP-I-10ADSORPTION OF COMPLEX MOLECU
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OP-I-11KINETIC ASPECTS OF METHANE O
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OP-I-12KINETIC STUDIES IN STRUCTURE
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OP-I-13A STUDY ON THERMAL COMBUSTIO
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OP-I-14KINETICS OF THE CONVERSION O
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OP-I-15HYDROCRACKING OF LONG CHAIN
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OP-I-16KINETICS IN THE HYDROGENATIO
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OP-I-17MECHANISM OF FORMATION OF ET
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OP-I-18KINETIC STUDIES OF PROPANE D
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OP-I-19ACTIVITY AND DEACTIVATION OF
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OP-I-20GAS PHASE OXIDATION OF FORMA
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OP-I-21Where k A is the rate consta
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OP-I-22al., 2008; Monolith, 2008).
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OP-I-23Fig. 1. Scheme of the FIM ma
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OP-I-24Θ DZ centersdeactivationr D
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OP-I-25equation [2] to nitrogen iso
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OP-II-1CHEMICAL NANOREACTORS AS BAS
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OP-II-2gas model use, there is no n
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OP-II-3Taking into account these pr
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OP-II-4WATER2METH1STEAM2AOFF3AIR10O
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OP-II-5completely dry, at the same
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OP-II-6Many factors have been found
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OP-II-7mechanistic and kinetic stud
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OP-II-9MODELLING OF DIESEL PARTICUL
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Section 3.Catalytic processesí dev
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OP-III-1BIC’s catalyst for N 2 О
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OP-III-2powder sample with the same
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OP-III-3Analysis of the results sho
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OP-III-4Exhaustaftertreatmenttechno
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OP-III-6SOME PROPERTIES OF PEROVSKI
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OP-III-7with the conventional react
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Page 108 and 109: OP-III-9mass dispersion and to anal
Page 110 and 111: OP-III-11PROCESS INTENSIFICATION US
Page 112 and 113: OP-III-12ETHYL ACETATE SYNTHESIS BY
Page 114 and 115: OP-III-12products are vaporized and
Page 116 and 117: OP-III-13The reforming reaction was
Page 118 and 119: OP-III-14reactivity (compared to ot
Page 120 and 121: OP-III-15Fig. 2. The spent Smopex-1
Page 122 and 123: OP-III-16Numbers of curves are acco
Page 124 and 125: OP-III-17perimeter were determined.
Page 126 and 127: OP-III-18of 2. MSR has been coupled
Page 128 and 129: OP-III-19chemisorption heat and pro
Page 130 and 131: OP-III-20In the experiments, total
Page 132 and 133: OP-III-21obtained by the new techno
Page 134 and 135: OP-III-22reactor wall from the two-
Page 136 and 137: OP-III-23and parameters of synthesi
Page 138 and 139: OP-III-24Results and discussionThe
Page 140 and 141: OP-IV-1DEEP DESULPHURIZATION OF PET
Page 142 and 143: OP-IV-2LACTIC ACID AS A BACKGROUND
Page 144 and 145: OP-IV-3CO REMOVAL FROM H 2 -rich GA
Page 146 and 147: OP-IV-4REFORMING OF ETHANOL OVER ME
Page 148 and 149: OP-IV-5MODELING OF HYDROGEN PRODUCT
Page 150 and 151: OP-IV-6PRODUCTION OF HYDROGEN FROM
Page 152 and 153: OP-IV-7SYNTHESIS GAS PRODUCTION FRO
Page 154 and 155: OP-IV-8HYDROGEN PRODUCTION FROM MET
Page 158 and 159: OP-IV-10EXERGY ANALYSIS OF ENZYMATI
Page 160 and 161: OP-IV-11ADVANCEMENT OF SLURRY BUBBL
Page 162 and 163: OP-IV-12Pd-DOPED PEROVSKITE CATALYS
Page 164 and 165: OP-IV-13HYDROGEN PRODUCTION VIA MET
Page 166 and 167: Section 5.Catalytic processing of r
Page 168 and 169: OP-V-1Scheme 1. The developing path
Page 170 and 171: OP-V-2An example of the model compo
Page 172 and 173: OP-V-3catalysts were shown to be su
Page 174 and 175: OP-V-4Catalyst deactivation was mor
Page 176 and 177: OP-V-53) Study of the FFAs esterifi
Page 178 and 179: OP-V-6In the present work, a compre
Page 180 and 181: OP-V-7Ca 2 Fe 2 O 5 , MgFe 2 O 4 an
Page 182 and 183: OP-V-8cellulose components decompos
Page 184 and 185: OP-V-9sintering a couple of spirale
Page 186 and 187: OP-V-10Catalyst preparationA series
Page 188 and 189: OP-V-11Catalysts characterizationIn
Page 190 and 191: OP-V-12Kinetic ExperimentsHexadecan
Page 192 and 193: OP-V-13DESIGN OF PILOT REACTOR AND
Page 194 and 195: OP-V-14DEVELOPMENT OF A LAB SCALE C
Page 196 and 197: OP-V-15DEVELOPMENT OF TWO-STAGE PRO
Page 198 and 199: OP-V-15The data of Table 2 show, th
Page 200 and 201: OP-V-17ENERGY PRODUCTION FROM BIOMA
Page 202 and 203: OP-V-18CATALYTIC PARTIAL OXIDATION
Page 204 and 205: OP-V-19A PHOTOCATALYTIC REACTOR FOR
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OP-V-20BIOMASS GASIFICATION IN A CA
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OP-V-21ESTIMATION OF OPTIMAL REACTO
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POSTER PRESENTATIONSSection 1. Kine
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PP-I-1CONVERSION OF ETHANOL OVER CO
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PP-I-2LATERAL INTERACTIONS, FINITE
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PP-I-3UTILIZATION OF TAFT EQUATION:
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PP-I-4SELECTIVE HYDROGENATION OF CI
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PP-I-5NON OXIDATIVE REGENERATION ME
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PP-I-6Table 1. Parameters in kineti
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PP-I-7where: k nc , k 1 , k a , k b
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PP-I-8After each adsorption or deso
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PP-I-9The increase in pressure, in
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PP-I-10The analysis of the composit
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PP-I-11The network of βP oxidation
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PP-I-12order of magnitude lower. Th
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PP-I-13ab1,01,0Isotope fraction0,5[
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PP-I-14Relations ‘rate vs alcohol
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PP-I-15[EEAA] t , M[EEAA] t -1 , M
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PP-I-17NEW OSCILLATING REACTION:CAR
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PP-I-18NEW OSCILLATING REACTIONS OF
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PP-I-19KINETICS OF GAS-LIQUID PROCE
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PP-I-20COMPLETE OXIDATION OF HARMFU
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PP-I-21THEORETICAL RESEARCH OF SURF
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PP-I-22INFLUENCE OF ORGANIC HELATES
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PP-I-23The equation of the reaction
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PP-I-25SELECTIVE OXIDATION OF METHA
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PP-I-26coefficients of the equation
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PP-I-27into propionic acid. The giv
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PP-I-28In the studied range of temp
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PP-I-29Table. Reaction temperature
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PP-I-30other in both direction of t
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PP-I-31Reynolds number. The boundar
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PP-I-32NANOPARTICLES AND CATALYSISI
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Section 2.Physico-chemical and math
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PP-II-1For investigation, we used n
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PP-II-2criterion «Zn dissolved in
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PP-II-3exist around the steady stat
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PP-II-4in range 0-1. In our case n
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PP-II-5at comparable activity, the
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PP-II-7CFD-CALCULATION OF MALDISTRI
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PP-II-8INVESTIGATION OF NONLINEAR P
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PP-II-8reactivity. There is a small
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PP-II-10CALCULATION OF INDUSTRIAL C
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PP-II-11type of reactors a catalyst
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PP-II-13MATHEMATTICAL MODELLING OF
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PP-II-13where I Э , M 1Э , M 2Э
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PP-II-14where TOC 0 is the initial
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PP-II-16AUTOCATALYTIC REACTION FRON
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Section 3.Catalytic processesí dev
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PP-III-1for the traditional scheme
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PP-III-2Initial conditions: С i (0
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PP-III-3Afterward, a 30% aqueous hy
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PP-III-4The influence of the water
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PP-III-5Vanadium oxide was grafted
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PP-III-6(T p ) was taken as an inde
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PP-III-7dCdτLABdCNABdτdCdτdCdτd
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PP-III-8O 2 , balanced by He, at a
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PP-III-9Solution of system (3) for
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PP-III-10HDT330ºCHDT350ºCHDT370º
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PP-III-11The activity of Au/support
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PP-III-1249775 m 3 /h0,65Initial te
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PP-III-13through one layer of ACC w
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PP-III-14the runs was always higher
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PP-III-15The experimental data for
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PP-III-16Catalytic hydrogenation of
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PP-III-17The following parameters a
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PP-III-18Figure 1 - Dependence of t
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PP-III-19Our method has some advant
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PP-III-20Furthermore, Ayude et al.
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PP-III-22OPTIMIZATION OF THE METHAN
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PP-III-23EXPERIMENTAL INVESTIGATION
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PP-III-24CATALYTIC REACTORS WITH HY
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PP-III-25ACTIVITY OF Cu/ZSM-5 CATAL
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PP-III-26SIMULATION AND OPTIMISATIO
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PP-III-27model of plug flow reactor
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PP-III-28Calculations were experime
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PP-III-29continuous and pressurized
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PP-III-30adequacy of multistage mod
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PP-III-31+CH 3 OHH 2 O + HO-(CH(CH
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PP-III-32procedure presented by Mar
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PP-III-33HPA-x + 2 H + + Pd 0 ⎯
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PP-III-34of the process as well as
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PP-III-35This study was financially
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PP-III-36phase. Peroxopolyoxometall
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PP-III-37performed under atmospheri
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PP-III-38orders of magnitude larger
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PP-III-39CATALYTIC REACTORS WITH ST
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PP-III-40THE OXIDATIVE DEHYDROGENAT
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PP-III-41MODELLING AND DESIGN OF TH
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PP-III-42COMPLEX TECHNOLOGY OF TREA
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PP-III-43PHOTO ELECTROCHEMISTRY APP
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PP-III-45MODELING OF CATALYTIC α-O
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PP-III-46steady states. It was show
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PP-III-47Results and discussion:The
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PP-III-49FIBROUS PALLADIUM-SUPPORTE
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Section 4.Catalytic technologies in
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PP-IV-1method is adiabatic or autot
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PP-IV-2It had been established that
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PP-IV-4INTERACTION OF ACTIVATED ALU
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PP-IV-5ENVIRONMENTALLY FRIENDLY PRO
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PP-IV-6THE 5%Ni-2%Au/Al 3 CrO 6 SYS
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PP-IV-7MESOPOROUS ANODES BASED ON Y
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PP-IV-8ADVANCED OXIDATION PROCESS F
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PP-IV-9PROCESSING OF POLYMERIC CORD
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PP-IV-10EFFECT OF SULPHUR ON THE CA
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PP-IV-11OXIDATIVE CONVERSION OF MET
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PP-IV-13CATALYTIC FLUE GAS CONDITIO
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PP-IV-14RIBBON POROUS NICKEL BASED
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PP-IV-15ETHANOL CONVERSION TO HYDRO
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PP-IV-16A HIGH-EFFICIENT MICROREACT
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PP-IV-17DIRECT DECOMPOSITION OF NIT
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PP-IV-18NICKEL CATALYSTS BASED ON P
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PP-IV-19SELECTION OF FAVOURABLE FEE
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PP-IV-20FORMALDEHYDE FORMATION DURI
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PP-IV-21PRODUCTION OF HYDROGEN-RICH
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PP-IV-22INFLUENCE OF COMPOSITION OF
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PP-IV-24ONE-STAGE CATALYTIC CONVERS
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PP-IV-25THE STUDY OF METHANE DEHYDR
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PP-IV-26MCM-41-SUPPORTED PdNi CATAL
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PP-IV-27IMPROVING THE FLOW SHEET OF
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PP-IV-29THE PARTIAL OXIDATION OF CH
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PP-IV-30PRODUCTION OF CO-FREE HYDRO
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PP-IV-31PHOTOCATALYTICAL ACTIVITY O
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PP-IV-32NEW ELECTRODE MATERIALSFOR
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PP-IV-33THE CATALYTIC HYDROGENATION
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PP-IV-34W 0, μmol O 2/min0,25 1. 1
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PP-V-1INFLUENCE OF ICE ON MEAs OF P
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PP-V-2DIRECT OILS HYDROGENATION TO
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PP-V-3DEVELOPMENT OF Pd/SIBUNIT CAT
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PP-V-4Pt NANOPARTICLE-HOLLOW POROUS
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PP-V-5THE PROCESS FOR PRODUCING ORG
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PP-V-6water removing. This method p
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PP-V-7ResultsThe presented technolo
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PP-V-8the most effective catalysts.
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PP-V-9Neither the low sulphur conte
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PP-V-10composition (methyl esters,
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PP-V-11reactor we can see that its
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PP-V-12Recent studies lead in this
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PP-V-13catalysts (e.g. Pt or Pd), t
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PP-V-14Alkali catalyst. For a basic
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PP-V-15obtaining the related profil
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PP-V-16reaction parameters, not rep
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PP-V-18STUDY OF THE CATALYTIC ACTIV
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PP-V-19BIOMORPHIC CATALYSTS ON THE
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PP-V-20Al,Cu-PILLARED CLAYS AS CATA
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PP-V-21KINETICS OF THE HYDROXYMATAI
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PP-V-22THE NEW METHOD OF OBTAINING
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PP-V-23containing mono- and di-subs
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AUTOCLAVE ENGINEERS COMPANYSYSTEMAT
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CATACON CATACON CATACON CATACON CAT
Page 506 and 507:
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George AvgouropoulosFoundation for
Page 512 and 513:
Leonid BykovJSC «Chemphyst-Alloy L
Page 514 and 515:
Debora FinoPolitecnico di TorinoCor
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Jenő HancsókUniversity of Pannoni
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Andrey KhudoshinLomonosov Moscow St
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Cristian LedesmaEnergetic Technique
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Uri Matatov-MeytalDepartment of Che
Page 524 and 525:
Karina OjedaIndustrial University o
Page 526 and 527:
Yuri PyatnitskyPisarzhevsky Institu
Page 528 and 529:
Vera ScmachkovaBoreskov Institute o
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Peter StrizhakPisarzhevsky Institut
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Nadezhda VernikovskayaBoreskov Inst
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Nataliya ZubritskayaRSC «Applied C
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ORAL PRESENTATIONS.................
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OP-I-21Saeedizad M., Sahebdelfar S.
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OP-III-9Nekhamkina O., Sheintuch M.
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OP-IV-5Hernández L., Kafarov V.V.M
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OP-V-13Sadykov V., Mezentseva N., V
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PP-I-15PP-I-16PP-I-17PP-I-18PP-I-19
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PP-II-9 Nikiforov A., Paek U-Hyon,
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PP-III-17 Vernikovskaya N.V., Kashk
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PP-III-42 Goshu Y.W., Tsaryov Y.V.,
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PP-IV-17 Ohnishi C.H., Yoshino H.,
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PP-V-9 Hancsók J., Magyar S., Kall
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XVIII International Conference on C
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