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KN-6individual reaction stages within certain phases of the technological cycle, which opens upwide prospects for the varying of the reactant concentrations on the catalyst surface. In manycases, the correct arrangement of this process in combination with the temperature factorallows one to overcome the equilibrium limitations and reach higher yields of target productsas compared with analogous stationary processes. It is interesting that in many cases, theparameters of non-stationary modes substantially depend on the factors that play a minor roleor have an indirect effect on the stationary technologies. These factors include the energy ofthe reactant bond with the catalyst surface, the heat capacity of the catalyst, its specificsurface, etc.Prospective for application of unsteady catalytic and sorption-catalytic processes areanalyzed for different case applications: VOC incineration, NOx reduction, purification ofautomotive exhausts, the Claus process, H 2 S decomposition, SO 2 oxidation, hydrogen andsyngas production by steam conversion of methane and CO, the Deacon process, selectiveoxidation of hydrocarbons and others.The following advantages of the sorption-catalytic technologies over the stationarymethods can be mentioned:• principally new options for heat management, possibility to perform highly-exothermalreactions in packed adiabatic beds without catalyst overheating;• a decrease in the energy consumption in processing of low-concentration gases;• an increase in the efficiency of cleaning of exhaust gases;• the shift of equilibrium in thermodynamically limited reactions;• the enhanced selectivity of partial «anaerobic» oxidation processes using thechemisorbed oxygen as a «soft» oxidant.In many cases, these advantages may include the reduction in the capital costs in and also,paradox as this may look at the first glance, the simplification of technological schemes andthe enhancement of their operation stability.In general, unsteady state and sorption-catalytic ideology discovers new degrees offreedom for process development and may become the basement for new generation ofhighly-efficient catalytic technologies in the nearest future.26
ORAL PRESENTATIONSSection 1. Kinetics of catalytic reactionsThe Section is dedicated to the 100 th anniversary ofProfessor M.I. Temkin, the outstanding specialist in thefield of physical chemistry and chemical kineticsSection 2. Physico-chemical and mathematical fundamentals of theprocesses in chemical reactorsSection 3. Catalytic processesí development and reactors design:modeling, optimization, new catalyst applicationSection 4. Catalytic technologies in fuel and energy productionñ production of hydrogenñ production of environmental friendly fuelsñ environmentally friendly engineeringSection 5. Catalytic processing of renewable sources: fuel, energy,chemicals
Page 1 and 2: Boreskov Institute of Catalysis of
Page 3 and 4: Mikhail G. Slinko,Honour ChairmanVa
Page 5 and 6: PLENARY LECTURES
Page 7: PL-1built up from an intrinsic cont
Page 10 and 11: PL-3DEVELOPMENT OF ZEOLITE-COATED M
Page 12 and 13: PL-4processes in order to evaluate
Page 14 and 15: PL-5CATALYTIC PARTIAL OXIDATION OF
Page 16 and 17: KEY-NOTE PRESENTATIONS
Page 18 and 19: KN-2GETTING TO THE POINT: FROM MOLE
Page 20 and 21: KN-3PROBLEMS AND PROSPECTS FOR IMRO
Page 22 and 23: KN-4remain out of the sight of rese
Page 24 and 25: KN-5SSITKA allows to study not only
Page 28 and 29: Section 1.Kinetics of catalytic rea
Page 30 and 31: OP-I-1-specialthat Г s /f changed
Page 32 and 33: OP-I-3-specialKINETIC MODELING OF L
Page 34 and 35: OP-I-4PARTIAL OXIDATION OF TOLUENE
Page 36 and 37: OP-I-5Also, the approach to modelin
Page 38 and 39: OP-I-6starch granules, but after a
Page 40 and 41: OP-I-8KINETICS OF CARBON MONOXIDE O
Page 42 and 43: OP-I-9CHAOTIC DYNAMICS IN THE THREE
Page 44 and 45: OP-I-10ADSORPTION OF COMPLEX MOLECU
Page 46 and 47: OP-I-11KINETIC ASPECTS OF METHANE O
Page 48 and 49: OP-I-12KINETIC STUDIES IN STRUCTURE
Page 50 and 51: OP-I-13A STUDY ON THERMAL COMBUSTIO
Page 52 and 53: OP-I-14KINETICS OF THE CONVERSION O
Page 54 and 55: OP-I-15HYDROCRACKING OF LONG CHAIN
Page 56 and 57: OP-I-16KINETICS IN THE HYDROGENATIO
Page 58 and 59: OP-I-17MECHANISM OF FORMATION OF ET
Page 60 and 61: OP-I-18KINETIC STUDIES OF PROPANE D
Page 62 and 63: OP-I-19ACTIVITY AND DEACTIVATION OF
Page 64 and 65: OP-I-20GAS PHASE OXIDATION OF FORMA
Page 66 and 67: OP-I-21Where k A is the rate consta
Page 68 and 69: OP-I-22al., 2008; Monolith, 2008).
Page 70 and 71: OP-I-23Fig. 1. Scheme of the FIM ma
Page 72 and 73: OP-I-24Θ DZ centersdeactivationr D
Page 74 and 75: OP-I-25equation [2] to nitrogen iso
Page 76 and 77:
OP-II-1CHEMICAL NANOREACTORS AS BAS
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OP-II-2gas model use, there is no n
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OP-II-3Taking into account these pr
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OP-II-4WATER2METH1STEAM2AOFF3AIR10O
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OP-II-5completely dry, at the same
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OP-II-6Many factors have been found
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OP-II-7mechanistic and kinetic stud
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OP-II-9MODELLING OF DIESEL PARTICUL
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Section 3.Catalytic processesí dev
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OP-III-1BIC’s catalyst for N 2 О
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OP-III-2powder sample with the same
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OP-III-3Analysis of the results sho
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OP-III-4Exhaustaftertreatmenttechno
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OP-III-6SOME PROPERTIES OF PEROVSKI
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OP-III-7with the conventional react
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OP-III-8resistance is the membrane
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OP-III-9mass dispersion and to anal
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OP-III-11PROCESS INTENSIFICATION US
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OP-III-12ETHYL ACETATE SYNTHESIS BY
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OP-III-12products are vaporized and
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OP-III-13The reforming reaction was
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OP-III-14reactivity (compared to ot
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OP-III-15Fig. 2. The spent Smopex-1
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OP-III-16Numbers of curves are acco
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OP-III-17perimeter were determined.
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OP-III-18of 2. MSR has been coupled
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OP-III-19chemisorption heat and pro
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OP-III-20In the experiments, total
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OP-III-21obtained by the new techno
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OP-III-22reactor wall from the two-
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OP-III-23and parameters of synthesi
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OP-III-24Results and discussionThe
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OP-IV-1DEEP DESULPHURIZATION OF PET
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OP-IV-2LACTIC ACID AS A BACKGROUND
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OP-IV-3CO REMOVAL FROM H 2 -rich GA
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OP-IV-4REFORMING OF ETHANOL OVER ME
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OP-IV-5MODELING OF HYDROGEN PRODUCT
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OP-IV-6PRODUCTION OF HYDROGEN FROM
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OP-IV-7SYNTHESIS GAS PRODUCTION FRO
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OP-IV-8HYDROGEN PRODUCTION FROM MET
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OP-IV-9A NEW GENERATION OF SUPER-TH
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OP-IV-10EXERGY ANALYSIS OF ENZYMATI
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OP-IV-11ADVANCEMENT OF SLURRY BUBBL
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OP-IV-12Pd-DOPED PEROVSKITE CATALYS
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OP-IV-13HYDROGEN PRODUCTION VIA MET
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Section 5.Catalytic processing of r
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OP-V-1Scheme 1. The developing path
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OP-V-2An example of the model compo
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OP-V-3catalysts were shown to be su
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OP-V-4Catalyst deactivation was mor
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OP-V-53) Study of the FFAs esterifi
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OP-V-6In the present work, a compre
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OP-V-7Ca 2 Fe 2 O 5 , MgFe 2 O 4 an
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OP-V-8cellulose components decompos
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OP-V-9sintering a couple of spirale
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OP-V-10Catalyst preparationA series
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OP-V-11Catalysts characterizationIn
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OP-V-12Kinetic ExperimentsHexadecan
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OP-V-13DESIGN OF PILOT REACTOR AND
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OP-V-14DEVELOPMENT OF A LAB SCALE C
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OP-V-15DEVELOPMENT OF TWO-STAGE PRO
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OP-V-15The data of Table 2 show, th
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OP-V-17ENERGY PRODUCTION FROM BIOMA
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OP-V-18CATALYTIC PARTIAL OXIDATION
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OP-V-19A PHOTOCATALYTIC REACTOR FOR
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OP-V-20BIOMASS GASIFICATION IN A CA
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OP-V-21ESTIMATION OF OPTIMAL REACTO
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POSTER PRESENTATIONSSection 1. Kine
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PP-I-1CONVERSION OF ETHANOL OVER CO
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PP-I-2LATERAL INTERACTIONS, FINITE
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PP-I-3UTILIZATION OF TAFT EQUATION:
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PP-I-4SELECTIVE HYDROGENATION OF CI
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PP-I-5NON OXIDATIVE REGENERATION ME
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PP-I-6Table 1. Parameters in kineti
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PP-I-7where: k nc , k 1 , k a , k b
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PP-I-8After each adsorption or deso
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PP-I-9The increase in pressure, in
Page 230 and 231:
PP-I-10The analysis of the composit
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PP-I-11The network of βP oxidation
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PP-I-12order of magnitude lower. Th
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PP-I-13ab1,01,0Isotope fraction0,5[
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PP-I-14Relations ‘rate vs alcohol
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PP-I-15[EEAA] t , M[EEAA] t -1 , M
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PP-I-17NEW OSCILLATING REACTION:CAR
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PP-I-18NEW OSCILLATING REACTIONS OF
Page 246 and 247:
PP-I-19KINETICS OF GAS-LIQUID PROCE
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PP-I-20COMPLETE OXIDATION OF HARMFU
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PP-I-21THEORETICAL RESEARCH OF SURF
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PP-I-22INFLUENCE OF ORGANIC HELATES
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PP-I-23The equation of the reaction
Page 256 and 257:
PP-I-25SELECTIVE OXIDATION OF METHA
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PP-I-26coefficients of the equation
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PP-I-27into propionic acid. The giv
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PP-I-28In the studied range of temp
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PP-I-29Table. Reaction temperature
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PP-I-30other in both direction of t
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PP-I-31Reynolds number. The boundar
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PP-I-32NANOPARTICLES AND CATALYSISI
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Section 2.Physico-chemical and math
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PP-II-1For investigation, we used n
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PP-II-2criterion «Zn dissolved in
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PP-II-3exist around the steady stat
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PP-II-4in range 0-1. In our case n
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PP-II-5at comparable activity, the
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PP-II-7CFD-CALCULATION OF MALDISTRI
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PP-II-8INVESTIGATION OF NONLINEAR P
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PP-II-8reactivity. There is a small
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PP-II-10CALCULATION OF INDUSTRIAL C
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PP-II-11type of reactors a catalyst
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PP-II-13MATHEMATTICAL MODELLING OF
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PP-II-13where I Э , M 1Э , M 2Э
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PP-II-14where TOC 0 is the initial
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PP-II-16AUTOCATALYTIC REACTION FRON
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Section 3.Catalytic processesí dev
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PP-III-1for the traditional scheme
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PP-III-2Initial conditions: С i (0
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PP-III-3Afterward, a 30% aqueous hy
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PP-III-4The influence of the water
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PP-III-5Vanadium oxide was grafted
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PP-III-6(T p ) was taken as an inde
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PP-III-7dCdτLABdCNABdτdCdτdCdτd
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PP-III-8O 2 , balanced by He, at a
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PP-III-9Solution of system (3) for
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PP-III-10HDT330ºCHDT350ºCHDT370º
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PP-III-11The activity of Au/support
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PP-III-1249775 m 3 /h0,65Initial te
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PP-III-13through one layer of ACC w
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PP-III-14the runs was always higher
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PP-III-15The experimental data for
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PP-III-16Catalytic hydrogenation of
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PP-III-17The following parameters a
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PP-III-18Figure 1 - Dependence of t
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PP-III-19Our method has some advant
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PP-III-20Furthermore, Ayude et al.
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PP-III-22OPTIMIZATION OF THE METHAN
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PP-III-23EXPERIMENTAL INVESTIGATION
Page 348 and 349:
PP-III-24CATALYTIC REACTORS WITH HY
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PP-III-25ACTIVITY OF Cu/ZSM-5 CATAL
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PP-III-26SIMULATION AND OPTIMISATIO
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PP-III-27model of plug flow reactor
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PP-III-28Calculations were experime
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PP-III-29continuous and pressurized
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PP-III-30adequacy of multistage mod
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PP-III-31+CH 3 OHH 2 O + HO-(CH(CH
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PP-III-32procedure presented by Mar
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PP-III-33HPA-x + 2 H + + Pd 0 ⎯
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PP-III-34of the process as well as
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PP-III-35This study was financially
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PP-III-36phase. Peroxopolyoxometall
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PP-III-37performed under atmospheri
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PP-III-38orders of magnitude larger
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PP-III-39CATALYTIC REACTORS WITH ST
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PP-III-40THE OXIDATIVE DEHYDROGENAT
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PP-III-41MODELLING AND DESIGN OF TH
Page 384 and 385:
PP-III-42COMPLEX TECHNOLOGY OF TREA
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PP-III-43PHOTO ELECTROCHEMISTRY APP
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PP-III-45MODELING OF CATALYTIC α-O
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PP-III-46steady states. It was show
Page 392 and 393:
PP-III-47Results and discussion:The
Page 394 and 395:
PP-III-49FIBROUS PALLADIUM-SUPPORTE
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Section 4.Catalytic technologies in
Page 398 and 399:
PP-IV-1method is adiabatic or autot
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PP-IV-2It had been established that
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PP-IV-4INTERACTION OF ACTIVATED ALU
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PP-IV-5ENVIRONMENTALLY FRIENDLY PRO
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PP-IV-6THE 5%Ni-2%Au/Al 3 CrO 6 SYS
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PP-IV-7MESOPOROUS ANODES BASED ON Y
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PP-IV-8ADVANCED OXIDATION PROCESS F
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PP-IV-9PROCESSING OF POLYMERIC CORD
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PP-IV-10EFFECT OF SULPHUR ON THE CA
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PP-IV-11OXIDATIVE CONVERSION OF MET
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PP-IV-13CATALYTIC FLUE GAS CONDITIO
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PP-IV-14RIBBON POROUS NICKEL BASED
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PP-IV-15ETHANOL CONVERSION TO HYDRO
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PP-IV-16A HIGH-EFFICIENT MICROREACT
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PP-IV-17DIRECT DECOMPOSITION OF NIT
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PP-IV-18NICKEL CATALYSTS BASED ON P
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PP-IV-19SELECTION OF FAVOURABLE FEE
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PP-IV-20FORMALDEHYDE FORMATION DURI
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PP-IV-21PRODUCTION OF HYDROGEN-RICH
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PP-IV-22INFLUENCE OF COMPOSITION OF
Page 438 and 439:
PP-IV-24ONE-STAGE CATALYTIC CONVERS
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PP-IV-25THE STUDY OF METHANE DEHYDR
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PP-IV-26MCM-41-SUPPORTED PdNi CATAL
Page 444 and 445:
PP-IV-27IMPROVING THE FLOW SHEET OF
Page 446 and 447:
PP-IV-29THE PARTIAL OXIDATION OF CH
Page 448 and 449:
PP-IV-30PRODUCTION OF CO-FREE HYDRO
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PP-IV-31PHOTOCATALYTICAL ACTIVITY O
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PP-IV-32NEW ELECTRODE MATERIALSFOR
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PP-IV-33THE CATALYTIC HYDROGENATION
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PP-IV-34W 0, μmol O 2/min0,25 1. 1
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PP-V-1INFLUENCE OF ICE ON MEAs OF P
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PP-V-2DIRECT OILS HYDROGENATION TO
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PP-V-3DEVELOPMENT OF Pd/SIBUNIT CAT
Page 464 and 465:
PP-V-4Pt NANOPARTICLE-HOLLOW POROUS
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PP-V-5THE PROCESS FOR PRODUCING ORG
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PP-V-6water removing. This method p
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PP-V-7ResultsThe presented technolo
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PP-V-8the most effective catalysts.
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PP-V-9Neither the low sulphur conte
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PP-V-10composition (methyl esters,
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PP-V-11reactor we can see that its
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PP-V-12Recent studies lead in this
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PP-V-13catalysts (e.g. Pt or Pd), t
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PP-V-14Alkali catalyst. For a basic
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PP-V-15obtaining the related profil
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PP-V-16reaction parameters, not rep
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PP-V-18STUDY OF THE CATALYTIC ACTIV
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PP-V-19BIOMORPHIC CATALYSTS ON THE
Page 494 and 495:
PP-V-20Al,Cu-PILLARED CLAYS AS CATA
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PP-V-21KINETICS OF THE HYDROXYMATAI
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PP-V-22THE NEW METHOD OF OBTAINING
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PP-V-23containing mono- and di-subs
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AUTOCLAVE ENGINEERS COMPANYSYSTEMAT
Page 504 and 505:
CATACON CATACON CATACON CATACON CAT
Page 506 and 507:
Page 508 and 509:
Page 510 and 511:
George AvgouropoulosFoundation for
Page 512 and 513:
Leonid BykovJSC «Chemphyst-Alloy L
Page 514 and 515:
Debora FinoPolitecnico di TorinoCor
Page 516 and 517:
Jenő HancsókUniversity of Pannoni
Page 518 and 519:
Andrey KhudoshinLomonosov Moscow St
Page 520 and 521:
Cristian LedesmaEnergetic Technique
Page 522 and 523:
Uri Matatov-MeytalDepartment of Che
Page 524 and 525:
Karina OjedaIndustrial University o
Page 526 and 527:
Yuri PyatnitskyPisarzhevsky Institu
Page 528 and 529:
Vera ScmachkovaBoreskov Institute o
Page 530 and 531:
Peter StrizhakPisarzhevsky Institut
Page 532 and 533:
Nadezhda VernikovskayaBoreskov Inst
Page 534 and 535:
Nataliya ZubritskayaRSC «Applied C
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ORAL PRESENTATIONS.................
Page 538 and 539:
OP-I-21Saeedizad M., Sahebdelfar S.
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OP-III-9Nekhamkina O., Sheintuch M.
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OP-IV-5Hernández L., Kafarov V.V.M
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OP-V-13Sadykov V., Mezentseva N., V
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PP-I-15PP-I-16PP-I-17PP-I-18PP-I-19
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PP-II-9 Nikiforov A., Paek U-Hyon,
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PP-III-17 Vernikovskaya N.V., Kashk
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PP-III-42 Goshu Y.W., Tsaryov Y.V.,
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PP-IV-17 Ohnishi C.H., Yoshino H.,
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PP-V-9 Hancsók J., Magyar S., Kall
Page 558:
XVIII International Conference on C
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