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Boreskov Institute of Catalysis of the Siberian Branch of Russian ...

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100 ANNIVERSARY OF PROFESSOR M.I. TEMKIND.Yu. MurzinProcess Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, FIN-20500,Turku/Åbo, Finland, fax: +358 2 215 4479, E-mail: dmurzin@abo.fiKN-1September 2008 marks 100 anniversary <strong>of</strong> Pr<strong>of</strong>.M.I. Temkin. He is considered as one <strong>of</strong> <strong>the</strong> founders <strong>of</strong>modern kinetics <strong>of</strong> complex catalytic reactions. Pr<strong>of</strong>. Temkinhad been working in Karpov <strong>Institute</strong> <strong>of</strong> Physical Chemistryin Moscow from 1932 after graduation from <strong>the</strong> MoscowState University till <strong>the</strong> last days <strong>of</strong> his life (1991), headingfor more than 50 years Laboratory <strong>of</strong> Chemical Kinetics.Being a disciple <strong>of</strong> famous scientists Pr<strong>of</strong>. A.N. Bakh (<strong>the</strong>fa<strong>the</strong>r <strong>of</strong> <strong>Russian</strong> biochemistry) and Pr<strong>of</strong>. A.N. Frumkin (<strong>the</strong>fa<strong>the</strong>r <strong>of</strong> <strong>Russian</strong> electrochemistry) he was also working withPr<strong>of</strong>. M.I. Temkin <strong>the</strong> Nobel prize winner Pr<strong>of</strong>. N.N. Semenov and Pr<strong>of</strong>. Michael(1908-1991)Polanyi in Manchester. Pr<strong>of</strong>. Temkin is famous for developing<strong>the</strong> <strong>the</strong>ory <strong>of</strong> catalytic processes on nonuniform surfaces. Independently with Pr<strong>of</strong>. J. Horiutihe developed <strong>the</strong> <strong>the</strong>ory <strong>of</strong> stationary reactions. Toge<strong>the</strong>r with his co-workers M.I. Temkinproposed a gradientless flow-circulation method, frequently used nowadays, for investigatingheterogeneous catalytic kinetics.The important feature <strong>of</strong> Temkin’s school is a unique blend <strong>of</strong> fundamental and appliedresearch. A particular example is kinetics <strong>of</strong> ammonia syn<strong>the</strong>sis, which serves as a basis forreactor design and intensification <strong>of</strong> industrial processes. Ano<strong>the</strong>r trade mark is logarithmicadsorption iso<strong>the</strong>rm, frequently referred as Temkin iso<strong>the</strong>rm. A seminal paper by Pr<strong>of</strong>.Temkin written in <strong>the</strong> 50-s was devoted to <strong>the</strong>rmodynamic analysis <strong>of</strong> molten salts and is stillwidely cited nowadays.Personal reflections on <strong>the</strong> experience working with Pr<strong>of</strong>. M.I. Temkin as a PhD studentand a research associate will be given.17

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