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Boreskov Institute of Catalysis of the Siberian Branch of Russian ...

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PP-III-32procedure presented by Mariani et al. [3] was employed. On <strong>the</strong> o<strong>the</strong>r hand, knowing <strong>the</strong>position <strong>of</strong> <strong>the</strong> centre <strong>of</strong> each sphere, <strong>the</strong> contact point can be calculated in a computationalway.The results were compared with experimental values from bibliography and ownexperimental results. A satisfactory agreement was obtained for any value <strong>of</strong> <strong>the</strong> aspect ratio,which means an additional support to <strong>the</strong> capability <strong>of</strong> <strong>the</strong> algorithm proposed. As anexample, in Fig. 1, a comparison <strong>of</strong> experimental (Giese et al. [4]) and simulated results <strong>of</strong> <strong>the</strong>radial void fraction distribution is presented.1ε r0,9Experimental points (Giese et al., 1998)0,80,7Simulation0,60,50,40,30,20,100 0,5 1 1,5 2 2,5 3 3,5 4 4,5 5xFigure 1: Comparison <strong>of</strong> experimental and simulated results <strong>of</strong> <strong>the</strong> radial void fraction distribution.On <strong>the</strong> o<strong>the</strong>r hand, <strong>the</strong> results obtained allow to check that <strong>the</strong> fractions <strong>of</strong> <strong>the</strong> spherescontacting <strong>the</strong> wall diminishes as <strong>the</strong> aspect ratio increases. Besides, <strong>the</strong> average number <strong>of</strong>particles contacting each o<strong>the</strong>r (average contact number) varies significatively depending onwhe<strong>the</strong>r <strong>the</strong> particles contact <strong>the</strong> wall or not. A simple expression to predict <strong>the</strong> averagecontact number as a function <strong>of</strong> <strong>the</strong> fraction <strong>of</strong> particles contacting <strong>the</strong> wall is proposed.References1. Nijemeisland, M., Dixon, A.G., A.I.Ch.E. J., 50, 906 (2004).2. Salvat, W.I., Mariani, N.J., Barreto, G.F., Martínez, O.M., Catal. Today, 107-108, 513 (2005).3. Mariani, N.J., Martínez, O.M., Barreto, G.F., Chem. Eng. Sci., 56, 5693 (2001).4. Giese, M., Rottschäfer, K., Vortmeyer, D., A.I.Ch.E.J., 44, 484 (1998).364

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