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Biofuels in Perspective

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100 <strong>Biofuels</strong><br />

are captured <strong>in</strong> the guard beds. When a syngas conta<strong>in</strong>s higher loads of these compounds<br />

it is economically more attractive to <strong>in</strong>stall a hydrolysis step to convert them to H2S and<br />

NH3, respectively. These components are readily removed <strong>in</strong> the gas clean<strong>in</strong>g. With this<br />

clean<strong>in</strong>g process the syngas specifications are met (Table 6.1).<br />

6.3 Biomass Gasification-Based FT-Diesel Production Concepts<br />

6.3.1 Syngas and FT-diesel Market<br />

Syngas is a versatile build<strong>in</strong>g block <strong>in</strong> chemical <strong>in</strong>dustry. 8,9 The total global annual use<br />

of fossil-derived syngas is approximately 6000 PJth, which corresponds to 2 % of the<br />

total primary energy consumption. The largest part of the syngas is used for the synthesis<br />

of ammonia for fertilizer production (∼55 %), the second largest share is the amount of<br />

hydrogen from syngas consumed <strong>in</strong> oil ref<strong>in</strong><strong>in</strong>g processes (∼24 %), and smaller amounts<br />

are used for methanol production (12 %). Figure 6.2 shows the present and predicted<br />

future syngas market distribution. 10 Today’s, global use of syngas for the production of<br />

transportation fuels <strong>in</strong> the so-called ‘gas-to-liquids’ processes (GTL) correspond to approx.<br />

500 PJ per year, i.e. from the FT-processes of Sasol <strong>in</strong> South Africa and Qatar and of Shell<br />

<strong>in</strong> B<strong>in</strong>tulu, Malaysia.<br />

6.3.1.1 Scale and Location<br />

The future biosyngas demand exceeds the present syngas consumption by a factor of eight.<br />

Therefore, it is clear that large biosyngas production capacities are needed to meet the<br />

European and national renewable energy and CO2-emission reduction targets. Not only are<br />

large <strong>in</strong>stalled capacities necessary, also the <strong>in</strong>dividual plants, compared to typical biomass<br />

plants, have to be large consider<strong>in</strong>g the typical plant scales for the two ma<strong>in</strong> applications, i.e.<br />

� Transportation fuels <strong>in</strong> BTL plants: few 100 MW to several 1,000 MW<br />

� Chemical sector: 50 ∼ 200 MW<br />

Syngas demands for liquid fuel synthesis will typically be larger than 1000 MW for<br />

plants, where the whole cha<strong>in</strong> from biomass to the f<strong>in</strong>al product is realized, to benefit from<br />

Figure 6.2 Present world syngas market (left) and predicted world syngas market <strong>in</strong> 2040 (right). Reproduced<br />

by permission of ECN.

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