Bio-based Fischer-Tropsch Diesel Production Technologies 113 <strong>in</strong> a 150 MWth biomass plant. 45 However, one can question how many of these locations will exist with<strong>in</strong> a global biomass market. Therefore, based on economic considerations, it is advisable to direct technology development towards large BTL facilities. Additionally, it should be noted that the use of a scale factor of 0.7 for calculat<strong>in</strong>g the <strong>in</strong>vestment costs, most likely results <strong>in</strong> an underestimation of the costs for scales below 2,500 MWth (or 20,000 bbld). A factor of 0.6 for these smaller scales is probably more accurate, while a factor of 0.5 should be used for the even smaller scales below 5,000 bbld (600 MWth). 6.5 Conclusions To meet the longer-term market demands as mentioned e.g., <strong>in</strong> the Vision document of the European Technology Platform on <strong>Biofuels</strong>, and to gradually shift to biofuels with a better overall CO2-reduction potential, the <strong>in</strong>troduction of so-called second-generation biofuels is a necessity. Mak<strong>in</strong>g H2 and CO (syngas) from biomass is widely recognized as a necessary step <strong>in</strong> the production of second-generation biofuels. There are two major approaches <strong>in</strong> convert<strong>in</strong>g biomass <strong>in</strong>to a syngas. The first approach is based on fluidized bed gasification: biomass is converted to fuel gas at approximately 900 ◦ C. This option requires almost no biomass pre-treatment, but the product gas needs downstream catalytic upgrad<strong>in</strong>g. A catalytic reactor is needed to reform the hydrocarbons to syngas. Support R&D is be<strong>in</strong>g performed at VTT (F<strong>in</strong>land), Värnamo (Sweden), and CUTEC (Germany). The fluidized bed gasification approach has the advantage that the gasification technology has already been developed and demonstrated with biomass for the production of heat and/or electricity. The second approach is based on entra<strong>in</strong>ed flow gasification: fuel is converted at high temperature (1000–1300 ◦ C) <strong>in</strong>to a syngas with little or no methane and other hydrocarbons. The entra<strong>in</strong>ed flow gasification processes have already been developed and demonstrated on large-scale for coal. In some cases even mixtures of coal and specific biomass have been tested successfully. Most biomass feedstocks, however, are not suitable to be directly <strong>in</strong>jected <strong>in</strong>to an entra<strong>in</strong>ed flow gasifier because the fuel size needs to be small. Additional extensive pre-treatment (e.g. pyrolysis, torrefaction) is therefore required. It should be realized that the above-mentioned options are not necessarily compet<strong>in</strong>g processes. The preference very much depends on boundary conditions, based on fuel type and fuel availability. Furthermore, the potential scale of the plants is an important issue. The back-end of the process generally needs to be as large as possible because of the dom<strong>in</strong>ant economy-of-scale effect <strong>in</strong> biofuel synthesis and upgrad<strong>in</strong>g. The front-end however <strong>in</strong>volves biomass supply. This generally means that <strong>in</strong>creas<strong>in</strong>g plant size means higher feedstock costs because longer transport distances are <strong>in</strong>volved. There is however an attractive way to deal with this scale ‘mismatch’ by splitt<strong>in</strong>g the two parts: biomass is pre-treated <strong>in</strong> relatively small-scale plants close to the geographical orig<strong>in</strong> of the biomass and the <strong>in</strong>termediate is transported to a central large-scale plant where it is converted <strong>in</strong>to a biofuel. The pre-treatment should preferably result <strong>in</strong> a densified and easy to transport material. Conventional pelletization is an option, but more attractive is the use of dedicated pre-treatment that also produces a feedstock that can be used directly <strong>in</strong> the large-scale syngas plant, e.g. torrefaction or pyrolysis. Loss of efficiency due to pretreatment then <strong>in</strong> general is compensated for by the logistic advantages of densification.
114 <strong>Biofuels</strong> References 1. M.E. Dry, The Fischer-Tropsch Synthesis, <strong>in</strong> Catalysis-Science and Technology, J.R. Anderson; M. Boudart (Eds), Spr<strong>in</strong>ger-Verlag, New York, USA, 159–255, 1981. 2. H. Boerrigter, H. den Uil and H.P. Calis, Green diesel from biomass via Fischer-Tropsch synthesis: new <strong>in</strong>sights <strong>in</strong> gas clean<strong>in</strong>g and process design, <strong>in</strong> Pyrolysis and Gasification of Biomass and Waste, A.V. Bridgwater (Ed.), CPL Press, Newbury, UK, 371–383, 2003. 3. H. Boerrigter and H. den Uil, Green diesel from biomass by Fischer-Tropsch synthesis: new <strong>in</strong>sights <strong>in</strong> gas clean<strong>in</strong>g and process design, RX–03-047, ECN, Petten, the Netherlands, 1–15, 2003. 4. (a) D. Hunt, Synfuels Handbook, Industrial Press Inc., McGraw-Hill Inc., New York, 1983 and (b) Encyclopaedia of Science and Technology, 7th ed., McGraw-Hill Inc., New York., USA, 1992. 5. E.D. Larson (2006) Advanced Technologies for Biomass Conversion to Energy, <strong>in</strong> Proceed<strong>in</strong>gs of the 2nd Olle L<strong>in</strong>dström Symposium on Renewable Energy, Bio-Energy, Royal Institute of Technology, Stockholm, Sweden, 2006. 6. (a) K. Hedden. A. Jess and T. Kuntze, From Natural Gas to Liquid Hydrocarbons, <strong>in</strong> Edröl Erdgas Kohle, part 1, 110, 318–321, 1999, (b) Idem, part 2, 110, 365–370, 1994, (c) Idem, part 3, 111, 67–71, 1995 and (d) Idem, part 4, 113, 531–540, 1997. 7. C. Higman and M. van der Burgt, Gasification, Elsevier Science, USA, 2003. 8. H. Boerrigter, A. van der Drift and R. van Ree, Biosyngas; markets, production technologies, and production concepts for biomass-based syngas, RX–04-013, ECN, Petten, the Netherlands, 1–37, 2004. 9. H.J. Ver<strong>in</strong>ga and H. Boerrigter, De syngas-route ...van duurzame productie tot toepass<strong>in</strong>gen, RX–04-014, ECN, Petten, the Netherlands, 2004. 10. (a) A. van der Drift, R. van Ree, H. Boerrigter and K. Hemmes, Bio-syngas: key <strong>in</strong>termediate for large scale production of green fuels and chemicals, <strong>in</strong> proceed<strong>in</strong>gs of 2nd World Conference and Technology Exhibition on Biomass for Energy, Industry and Climate Protection, Vol. II, 2155–2157, Rome, Italy, 2004 and (b) Idem, RX–04-048, ECN, Petten, the Netherlands, 1–4, 2004. 11. H. Boerrigter, A. van der Drift and E.P. Deurwaarder, Biomass-to-liquids: Opportunities & challenges with<strong>in</strong> the perspectives of the EU Directives, <strong>in</strong> 5th Annual GTL (Gas-to-Liquids) Technology & Commercialization Conference & Exhibition, 2006. 12. M. Kaltschmitt and H. Hartmann, Energie aus Biomasse, Grundlagen, Techniken und Verfahren, Spr<strong>in</strong>ger-Verlag, Berl<strong>in</strong>, 770. 13. Conclusion from the Congress on Synthetic <strong>Biofuels</strong> – Technologies, Potentials, Prospects, Wolfsburg, Germany, 2004. 14. H. Boerrigter and A. van der Drift, Large-scale production of Fischer-Tropsch diesel from biomass: optimal gasification and gas clean<strong>in</strong>g systems., RX–04-119, ECN, Petten, The Netherlands, 2004. 15. H. Boerrigter, H.P. Calis, D.J. Slort, H. Bodenstaff, A.J. Kaandorp, H. den Uil and L.P.L.M. Rabou, Gas clean<strong>in</strong>g for <strong>in</strong>tegrated Biomass Gasification (BG) and Fischer-Tropsch (FT) systems, C–04-056, ECN, 2004. 16. M.A. Paisley, R.P. Overend, M.J. Welch and B.M. Igoe, FERCO’s SilvaGas biomass gasification process commercialisation opportunities for power, fuels, and chemicals, <strong>in</strong> The 2nd World Conference on Biomass for Energy, Industry, and Climate Protection, Rome, Italy, 2004. 17. K. Whitty, State-of-the-art <strong>in</strong> black liquor gasification technology, <strong>in</strong> IEA Annex XV meet<strong>in</strong>g, Pite˚a, Sweden, 2002. 18. A. van der Drift, An overview of <strong>in</strong>novative biomass gasification concepts, <strong>in</strong> 12th European Conference on Biomass for Energy, Amsterdam, the Netherlands, 381-11384, 2002.
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Biofuels Biofuels. Edited by Wim So
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Biofuels Edited by WIM SOETAERT Ghe
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Contents Series Preface ix Preface
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Contents vii 6.3 Biomass Gasificati
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Series Preface Renewable resources,
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Preface This volume on Biofuels fit
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Editors List of Contributors Wim So
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1 Biofuels in Perspective W. Soetae
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Table 1.1 Approximate average world
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Table 1.3 Energy yields of bio-ener
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Biofuels in Perspective 7 is burnt
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2 Sustainable Production of Cellulo
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Sustainable Production of Cellulosi
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Sustainable Production of Cellulosi
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Sustainable Production of Cellulosi
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Sustainable Production of Cellulosi
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Sustainable Production of Cellulosi
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Sustainable Production of Cellulosi
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Figure 2.9 2004 US adoption rates o
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Sustainable Production of Cellulosi
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Sustainable Production of Cellulosi
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Sustainable Production of Cellulosi
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Sustainable Production of Cellulosi
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Sustainable Production of Cellulosi
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Sustainable Production of Cellulosi
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Sustainable Production of Cellulosi
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3 Bio-Ethanol Development in the US
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Bio-Ethanol Development in the USA
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Biorefineries in Production (115) B
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Bio-Ethanol Development in the USA
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Bio-Ethanol Development in the USA
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Bio-Ethanol Development in the USA
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Cost of Cellulosic Ethanol, $ per g
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Bio-Ethanol Development in the USA
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4 Bio-Ethanol Development(s) in Bra
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Bio-Ethanol Development(s) in Brazi
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Share of energy consumption 100% 90
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Bio-Ethanol Development(s) in Brazi
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Production of Biodiesel from Waste
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Production of Biodiesel from Waste
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CPO I 1 1 Heating 60°C Reaction st
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References Production of Biodiesel
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10 Biomass Digestion to Methane in
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Cow manure Pig manure Yard manure B
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Number of plants 3000 2500 2000 150
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Biomass Digestion to Methane in Agr
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Biomass Digestion to Methane in Agr
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Table 10.4 Alternative forms of ene
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Biomass Digestion to Methane in Agr
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Wet fermentation 3 - 10% TS applica
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Rel. Frequency [%] 35 30 25 20 15 1
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Steam 2 1 Energy crops (& manure) D
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Biomass Digestion to Methane in Agr
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Biomass Digestion to Methane in Agr
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198 Biofuels 11.1 Introduction Hydr
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200 Biofuels lactate 6 glucose 1 GA
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Table 11.2 Continued Organism Domai
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204 Biofuels NADH is that the react
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206 Biofuels Clostridium thermocell
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208 Biofuels in particular in Cl. p
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210 Biofuels ferredoxin-dependent m
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212 Biofuels Concentration (mM) 45
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214 Biofuels genes of the glycolysi
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216 Biofuels 11. S. Tanisho and Y.
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218 Biofuels 49. M. J. Axley, D. A.
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220 Biofuels 83. P. J. Silva, E. C.
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12 Improving Sustainability of the
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Table 12.1 Corn ethanol dry mill: e
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Table 12.2 Atmospheric CO2 (equival
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Table 12.3 Incremental CO2 equivale
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Improving Sustainability of the Cor
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Improving Sustainability of the Cor
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Index italic entries indicate refer
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iorefineries 3, 10, 11, 41 and corn
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policy (official) 59-61 production
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NADH 200-6, 207, 210 natural gas 1