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Dames & Moore, 1999 - USDA Forest Service

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concentrations, but statistically the two concentrations were equivalent because of the above-mentioned<br />

uncertainties associated with the flow estimates.<br />

Relative to measured incoming load in Reach 2 (tailings influenced stream segment from RC-4 to RC-7),<br />

the additions of magnesium were less than the additions in Reach 1. The deficit was +I550 mg/s. The<br />

calculated concentration using this deficit was 26.1 mg/L (Table 6.6-1) which was close to the range of<br />

magnesium concenlrations of 30 mg/L to greater than 100 mg/L in seeps.<br />

The deficit between RC-7 and RC-2 was 684 mg/s, which was close to the contribution fiom SP-4 (5 15<br />

mg/s).<br />

The May 1997 analysis for magnesium implies that there are no significant missing magnesium load<br />

contributions in the spring. The deficits between surface water additions and measured loads in Railroad<br />

Creek can be accounted for by reasonable groundwater flows and magnesium concentrations.<br />

The September 1997 magnesium load calculation for Reach 1 (Table 6.6-2) indicates little change between<br />

RC-1 and RC-4 (-19 m a). The load provided by the only measurable source (P-5) was not significant<br />

relative to the load entering the Site at .RC-1, and represented only 1.1 percent of the load previously<br />

measured in May 1997. The Reach 1 balance was shown as a negative load (-75 mg/s). This small negative<br />

load was consistent with the apparent flow loss in the reach (Section 4.3.7). In Reach 2, the load balance<br />

was 71 1 mg/s, which can be accounted for by a groundwater contribution similar to that observed in May<br />

1997.<br />

In summary, the magnesium balance is in agreement with the site-specific water balance. The magnesium<br />

balance indicated that all major sources were identified and that the required flow balances were consistent<br />

with magnesium concentrations observed in both surface water and groundwater.<br />

Quasi-Conservative Parameters - Zinc and Cadmium<br />

Zinc and cadmium are often observed to show almost conservative behavior because their solubility is not<br />

influenced by pH within the pH range normally encountered on site. They can be adsorbed onto soil and<br />

sediment particles; however, this may not be a strong effect in coarse gravelly soils and stream beds.<br />

The loading calculation of zinc followed the sarne'approach as for magnesium. In May, the difference<br />

between RC-1 and RC-4 was 850 mg/s. The majority of this difference can be accounted for by P-5 (849<br />

mg/s). SP-23 provided 71 mg/s, hence the cumulative load at RC-4 from measured sources was 1 123 mg/s.<br />

This load at RC-2 was greater than the load at RC-4 (1034 mg/s). The balance of -90 mg/s is small relative<br />

to the inflow from P-5 and therefore is not significant. The data imply that all significant loads in Reach 1<br />

have been identified.<br />

In Reach 2, very little zinc was added compared to Reach 1. The Copper Creek diversion was the largest<br />

source. The required balance was 146 mg/s, which was larger than the point sources along Reach 2. The<br />

concentration required to produce this balance was 2.5 m&. This implies that groundwater originating in<br />

Reach 1 (i.e., from the mine support areas) enters Railroad Creek in Reach 2. The total of the balances for<br />

Reach 1 and Reach 2 is 56 mg/s. This is less than 5 percent of the total load in Railroad Creek and implies<br />

overall that non-point sources contribute insignificantly to the load in Railroad Creek during May. P-5 is the<br />

\WM-SMl\VOLl\COMMON\WP\~W)~UloIdm-2\n7M).doc<br />

6-42<br />

17693-005-019Uuly 27,<strong>1999</strong>,4:11 PM;DRAFf FINAL Rl REPORT

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