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Dames & Moore, 1999 - USDA Forest Service

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Source controls reflect the differences in oxygen availability and water flow.<br />

- Portions of the underground mine are likely well-oxygenated through the winter<br />

months due to temperature differences between the underground mine and the .<br />

ambient air, and may therefore be actively oxidizing in open stopes above the 1500-<br />

level of the mine. Random water flow in fractures dissolves weathering products,<br />

some of which are discharged in the 1500-level main portal drainage, and some of<br />

which are stored as salts formed by evapo-concentration. Discharge water reflects<br />

precipitation of iron in the workings and precipitation of aluminum within the mine<br />

hnd in the portal drainage and Railroad Creek.<br />

- The tailings piles are only oxygenated near the surface. Chemical processes leading<br />

to the release of heavy metals occur primarily in this zone and not at depth. Acid<br />

neutralization occurs at depth. Groundwaters contain reduced iron which rapidly<br />

oxidizes upon emergence in seeps, forming femcrete and flocculent. ,<br />

The metal attenuation processes that occur downgradient of sources prior to entering<br />

Railroad Creek include precipitation due to pH increase and aeration, efflorescence<br />

(causing seasonal formation of salts), co-precipitation of heavy metals (primarily with<br />

iron), and adsorption. Precipitation of aluminum, iron and copper flocculent probably<br />

occurs when seeps mix with slightly alkaline Railroad Creek water and groundwater<br />

adjacent to Railroad Creek.<br />

The magnesium (conservative parameter) balance indicated that all major sources were<br />

identified and that the required flow balances were consistent with measured magnesium<br />

concentrations. Therefore, the magnesium balance comborates the site-specific water<br />

balance in Section 4.4.<br />

Mass balance calculations for Railroad Creek at the Site indicate that the mass of zinc,<br />

cadmium, copper and iron originating from the underground mine, waste rock piles, and<br />

tailings piles has been accounted for. Seasonal and yearly variations are apparent<br />

reflecting changing variations in flow characteristics and timing of sampling with respect<br />

to the spring snowmelt.<br />

Copper and zinc loads to Railroad Creek from measured point sources and other<br />

groundwater (baseflow) sources are highest during the spring snowmelt and groundwater<br />

discharge period when groundwater levels are highest in the deep wells beneath the<br />

tailings, and high flow occurs at the 1500-level portal drainage. During the May round<br />

when flows are the highest, the portal drainage is the primary source of loading of<br />

cadmium, copper and zinc to Railroad Creek.<br />

Seeps SP-23 and SP-23B are the two next highest point sources that are estimated to<br />

contribute copper, cadmium and zinc during May; however, this load drops to zero later in<br />

the year as seep SP-23 dries up.<br />

Iron enters Railroad Creek primarily by groundwater and iron loads are greater in<br />

September than May. Iron loads enter Railroad Creek downstream of the load sources<br />

\ \ D M _ ~ ~ A , I \ W L I \ C O M M O M W R ~ ~ ~ ~ ~ - Z \ ~ ~ ~ . ~ ~ ~<br />

6-52<br />

1769MO5419Uuly 27.<strong>1999</strong>;4:11 -RAPT FINAL RI REPORT<br />

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