13.01.2013 Views

Dames & Moore, 1999 - USDA Forest Service

Dames & Moore, 1999 - USDA Forest Service

Dames & Moore, 1999 - USDA Forest Service

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

Since none of the UCL concentrations exceeded the acute or chronic benchmarks calculated in Table 7.1.3-<br />

2B, there is no need to conduct a further analysis of risk to benthic invertebrates in South Bank or<br />

mainstream of Railroad Creek from these metals.<br />

Benthic Invertebrates- Sediments<br />

In addition to the benthic macroinvertebrates that are attached to hard substrates, there may be benthic<br />

invertebrates that burrow in the sediments of Railroad Creek. Sediment samples were collected by USGS<br />

(1994) and analyzed in by a non-standard method that provided worst possible conditions for comparison<br />

with sediment quality benchmarks. Because there is relatively little sediment in Railroad Creek. the samples<br />

were collected from behind boulders, and from sandban. The samples were sieved, air dried. and then<br />

pulverized to a fine flow prior to extraction and analysis by ICP-AES. Pulverizing the sediments would<br />

have increased the amount of metal in contact with the strong acid and resulted in an apparent higher<br />

concentration than normal extraction procedures. USBM (1995) and Ecology (1997) collected sediment in<br />

Railroad Creek. With the exception of silver, the USGS data were the highest sediment values available.<br />

In Table 7.2.4-2C, the results of this analysis are compared against the sediment quality guideline values.<br />

The most conservative guidelines (ER-L) were used for screening purposes, although it must be noted that<br />

none of the samples exceeded the Ecology (1991) guidelines for freshwater sediments. Exceedances of the<br />

ER-Ls for cadmium, copper, iron, manganese and zinc are shown on Table 7.24-2C.<br />

Since risk was found for the UCLs of sediments, the median sediment concentrations were evaluated. There<br />

were insufficient data points to calculate median concentrations in upstream sediments.<br />

Exceedance of the ER-L means that sediments may "occasionally" be toxic (Long et al., 1995). Therefore,<br />

it is not appropriate to use these exceedances as evidence of adverse effects to the benthic communities at<br />

the sites where data was collected or for Railroad Creek in general. Because of the uncertainty associated<br />

with interpretation of sediment quality guidelines, it may be more appropriate to assess the potential toxicity<br />

of Railroad Creek sediments by exceedance of the ER-M, those concenb-ation "frequently" associated with<br />

toxicity. When this is done, exceedances are only found for manganese downstream from the mining site,<br />

and HQ is only slightly greater than 1.0.<br />

Washington State (Ecology, 1997) has recently developed freshwater sediment quality values (FSQVs).<br />

The FSQVs (freshwater sediment quality values) are probable apparent effects thresholds (PAETs). PAETs<br />

are the 95th percentile concentrations of compounds of concern from field collected studies above the<br />

highest concentration where no significant biological effects were found. The PAET is the concentration in<br />

freshwater sediments below which biological effects are unlikely to occur. When the concentrations are<br />

compared to FSQVs, only manganese and silver present risk to benthic invertebrates (Table 7.2.4-2C). In<br />

support of this usage of sediment quality guidelines, it is noteworthy that Ecology (1997) found sediments<br />

from the mine site area were non-toxic to the sensitive bioassay animal (Hyalelle asreca). Toxicity test data<br />

are generally believed to be a more reliable indicator of potential toxicity than comparison to sediment<br />

toxicity "guidance" values due to site-specific variations in conditions.<br />

Harper Owes (1989) sampled sediments 170 m offshore of the mouth of Railroad Creek in Lake Chelan.<br />

These sediments exceeded sediment quality guidelines for arsenic, iron, and zinc. However, it is important<br />

to note that Ecology (1997) found that sediments collected from the delta at the mouth of Railroad Creek<br />

\DM-SEA I\VOL I\COMMOMWnwpdr~\W5\RpomVIoldm.2\n~7Q,doc 7-63<br />

176934054lWuly 27.<strong>1999</strong>.5:29 PMDRAFTFINAL RI REPORT

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!