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A Manual of the Chemistry of the Carbon Compounds

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184 THE CHBMHTRY OF<br />

CO.OH CO.OH<br />

CH2<br />

CH2<br />

CH2I CH2<br />

+ Ag2=| +2AgI<br />

CH2I CH2<br />

CH2<br />

CHg<br />

CO.OH CO.OH<br />

By <strong>the</strong> same reaction, ft lyromjnopionic acid is converted into<br />

dimethylsmxinic add,:—<br />

CO.OH<br />

I CO.OH<br />

CH.CH8 |<br />

Br CH.CH8<br />

8<br />

Br<br />

+ Ag, =<br />

CH.CH.<br />

I + 2AgI<br />

CH.CH<br />

CHCH3<br />

I CO.OH<br />

CO.OH<br />

Many <strong>of</strong> <strong>the</strong> aoids belonging to this group are formed by <strong>the</strong><br />

oxidation <strong>of</strong> fats and o<strong>the</strong>r bodies. Three <strong>of</strong> <strong>the</strong>m ocour in nature,<br />

viz. oxalic acid, succinic acid, and rooellic aoid.<br />

KTHENE COMPOUNDS.<br />

ETUEHE CgH4.<br />

This hydrocarbon is'formed, toge<strong>the</strong>r with many o<strong>the</strong>r products,<br />

by <strong>the</strong> destructive distillation <strong>of</strong> organic bodies, as fats, resins,<br />

wood, coal, &c. To obtain pure e<strong>the</strong>ne a mixture <strong>of</strong> one volume <strong>of</strong><br />

strong alcohol and 3—4 volumes <strong>of</strong> concentrated sulphuric acid is<br />

gently heated, and <strong>the</strong> gas washed with concentrated sulphuric acid<br />

and a solution <strong>of</strong> caustic soda, in order to free it from <strong>the</strong> vapours<br />

<strong>of</strong> alcohol and e<strong>the</strong>r, and from carbon dioxide and sulphur dioxide,<br />

which two gases are always formed towards <strong>the</strong> eud <strong>of</strong> tho reaction.<br />

E<strong>the</strong>ne ia a colourless gas having a pecnliat 1 faint and snffocating<br />

odour. It condenses at — 1-10° to a liquid; it is very inflammable,<br />

burning with a hright luminous flame.<br />

It was formerly called olcfiantgas, because it combines with chlorine<br />

to form e<strong>the</strong>ne dichloride, an oily liquid. E<strong>the</strong>ne also combines<br />

readily with bromine, but more difficultly with iodine. The concen-

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