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A Manual of the Chemistry of the Carbon Compounds

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302 THE OHEMI8T&Y OF<br />

to <strong>the</strong> right, Its chemical properties are very similar to those <strong>of</strong><br />

turpentine oil; it yields a solid hydrate, and crystalline hydrochloridea.<br />

With bromine and aniline it forms cymene. Similar terpenes exist<br />

in <strong>the</strong> oils <strong>of</strong> orange-peel, bergamot, &c.<br />

TEGPENES FROM OTHKR SOUKCES,<br />

These hydrocarbons are found in a great number <strong>of</strong> volatile oils,<br />

some <strong>of</strong> <strong>the</strong>m consisting only <strong>of</strong> terpens, such as oils <strong>of</strong> lavender, juniper,<br />

copaiba, cubebs, pepper, elemi, and <strong>the</strong> camphor-trees. O<strong>the</strong>rs are<br />

mixtures <strong>of</strong> terpenes with acids, as oil <strong>of</strong> valerian; or with aldehydes,<br />

as oil <strong>of</strong> chamomile, which contains angelicaldehyde, A great<br />

number <strong>of</strong> essential oils also contain, besides, terpenes, camphors,<br />

cymene, or o<strong>the</strong>r aromatic compounds.<br />

CAOUTCHOUC AND GUTTA-PJ3BCHA,<br />

Caoutchouc or IndAa^tvXAev is <strong>the</strong> dried milky juice <strong>of</strong> several<br />

tropical trees (Ficuselastica, Jatropha elastica, Sijphonia Cahuchu,SK.).<br />

The fresh juice has an acid reaction; on mixing it with water,<br />

caoutchouc separates gradually out as a white- curdy precipitate,<br />

whioh dries up to a gum-like mass. The black colour <strong>of</strong> <strong>the</strong> commercial<br />

article is due to <strong>the</strong> effect <strong>of</strong> smoke; it may be purified by<br />

dissolving it in chlor<strong>of</strong>orm, and precipitating <strong>the</strong> clear solution with<br />

Bpirits <strong>of</strong> wine. It consists olnefly <strong>of</strong> a mixture <strong>of</strong> hydrooarbous,<br />

polymeric with <strong>the</strong> terpenes. It is insoluble in water and alcohol;<br />

with e<strong>the</strong>r or petroleum it forms a gelatinous mass, and partially<br />

dissolves. It is completely soluble in oil <strong>of</strong> turpentine, benzene,<br />

chlor<strong>of</strong>orm, and carbon disulphide. When cold it is hard and tough;<br />

on heating it becomes s<strong>of</strong>t and elastic; and at a temperature above<br />

<strong>the</strong> boiling-point <strong>of</strong> water it melts, but on cooling does not return to<br />

<strong>the</strong> original state, but remains s<strong>of</strong>t and viscid.<br />

It is much used for <strong>the</strong> manufacture <strong>of</strong> waterpro<strong>of</strong> and elastic<br />

fabrics, for elastic tubing, &c., and is a most valuable substance for<br />

<strong>the</strong> chemists, as it is only affected by a very few chemical agents.<br />

Caoutchouc combines in different proportions with sulphur. The<br />

so-called vulcanized India-rubber, whioh is much more elastic than<br />

common caoutchouc, is obtained by mixing <strong>the</strong> latter intimately<br />

with sulphur by means <strong>of</strong> carbon disulphide; it contains about 2<br />

to 3 per cent, <strong>of</strong> sulphur. By mixing it with about half its weight<br />

<strong>of</strong> sulphur, it is converted into a hard, horny mass, called "Ebonite "<br />

or "Vulcanite," which is much used for making combs, disks for<br />

eleotrio machines, &o.<br />

By destructive distillation, caoutchouc yifelda a» oily liquid, con-

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