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A Manual of the Chemistry of the Carbon Compounds

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THE CARBON COMPOUNDS. 405<br />

Its alkaline solution may be boiled without being changed.<br />

Sulphuric acid dissolves hsematin, and on adding water, <strong>the</strong> compound<br />

C34H80N4O9 is precipitated; it is an amorphous mass resembling<br />

hsematin.<br />

ffcmatin Hydrochttyi'ide or Hasmine (C8,HMN^O6Fe)j!(HCl)3 is produced<br />

by heating hwmttglobin with glacial acetic acid, and common,<br />

salt. It crystallizes in thin rhombic plates, possessing a brownishred<br />

colour, and bluish-red reflection. Alkalis decompose it into<br />

hsematin and hydrochloric acid.<br />

The formation <strong>of</strong> <strong>the</strong>se blood-crystals is made use <strong>of</strong> as a test for<br />

detecting blood-spots in criminal cases.<br />

Mutin is contained in <strong>the</strong> secretions <strong>of</strong> <strong>the</strong> mucous membranes<br />

and is conveniently prepared by precipitating filtered cx-bile with<br />

alcohol, dissolving <strong>the</strong> precipitate in water, and precipitating again<br />

with acetic acid. It swells up in a little water, and dissolves in a<br />

large quantity ; its solution does not coagulate on heating. Mucin<br />

contains: carbon 52*2, hydrogen 7*0, nitrogen 12*6, oxygen 28*2.<br />

Keratriti.—TMs, name is given to <strong>the</strong> residual mass, which is<br />

obtained by exhausting epidermis, nails, claws, ho<strong>of</strong>s, hair, wool,<br />

-whale-bone, &c, with e<strong>the</strong>r, alcohol and a dilute acid. It dissolves<br />

in potash with <strong>the</strong> formation <strong>of</strong> ammonia and potassium sulphide,<br />

and acids produce in this solution a gelatinous precipitate. When<br />

<strong>the</strong> substances above mentioned are boiled with dilute sulphuric acid,<br />

<strong>the</strong>y yield tyrosine and leucine, and nitric acid imparts to <strong>the</strong>m a<br />

yellow colour, The composition <strong>of</strong> keratrin does not differ much<br />

from that <strong>of</strong> <strong>the</strong> proteids, but it contains more sulphur:—<br />

Poreentago <strong>of</strong><br />

Sulphur.<br />

Human-hair . . . . 4—5<br />

Human-nails . . . . 2-8<br />

Epidermis 0*7<br />

Wool 2—3-5<br />

Horse^ho<strong>of</strong>s . . . , 4*2<br />

Whale-bono . . . . 3*5<br />

Tortoise-shell.... 2*0<br />

Elastiii ia a substance resembling keratrin, and is contained iu <strong>the</strong><br />

ligammtmn, ntichas <strong>of</strong> cattle. It is in <strong>the</strong> moist state extensible, but<br />

becomes brittle after drying. Its alkaline solution is not precipitated<br />

by acids. A similar substance has been found in <strong>the</strong> egg <strong>of</strong> <strong>the</strong><br />

common snake.<br />

GELATIN AND CHONBEIN.<br />

These twc compounds do not pre-exist in <strong>the</strong> animal organism,<br />

But are produced by <strong>the</strong> action <strong>of</strong> boiling water on certain tissues.<br />

Gelatin is obtained by boiling bones, tendons, skin, bladder, &c.,

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