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A Manual of the Chemistry of the Carbon Compounds

A Manual of the Chemistry of the Carbon Compounds

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424 THE CHEMI8TBY OF<br />

above 300°, and subliming in s<strong>of</strong>t, pale-yellow, interlaced needles.<br />

Mitrio acid oxidizes it to diphthalio acid (C^A,(CO),(CO.OH)«<br />

forming microscopic needles, metying at 265°. By heating this acid<br />

above its melting-point, it yields diphthalyl, and phthalic anhydride,<br />

whilst by boiling it with nitric acid for some time it ia oxidized to<br />

phthalic acid.<br />

C2(COH6)4.<br />

By acting with phosphorus pentachloride on diphenyl ketone it is<br />

converted into diphmyl-dicliiwomtham (C^Hj^CClj, and this compound,<br />

when heated with silver-dust, yields tetraphenyl-etbene,<br />

crystallizing from hot benzene in pointed prisms, melting at 221°.<br />

Hot concentrated sulphuric acid converts it into tctrapltenyl-tetramdphonic<br />

acid, which, when fused with potash, yields <strong>the</strong> corresponding<br />

phenol, or<br />

Tetrmytelraplienyhetfane C^(C9H4.OH). crystallizing from hot<br />

glacial acetic acid in very thin, small plates, which in tho air assume<br />

a faint violet tinge. On adding ferric chloride to a solution<br />

<strong>of</strong> this phenol in acetic acid, a dark blood-red liquid is formed,<br />

from which crystals, having a metallic lustre, and consisting <strong>of</strong><br />

(

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