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A Manual of the Chemistry of the Carbon Compounds

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THE GARBON COMPOUNDS. 281<br />

Oa heating, it is oonverted into Imdosan CJH^OJ, an amorphous<br />

mass, which may be reconverted into levulose by boiling it with a<br />

dilute acid.<br />

By saturating a dilute solution <strong>of</strong> levulose with chlorine, and<br />

<strong>the</strong>n treating <strong>the</strong> liquid with silver oxide, no gluconic acid is formed,<br />

but glycoUie add.<br />

From this it appears that <strong>the</strong> constitution <strong>of</strong> levulose is different<br />

from that <strong>of</strong> dextrose; it is also <strong>the</strong> aldehyde <strong>of</strong> a Lexad alcohol<br />

radical, ami its constitution may be expressed by <strong>the</strong> following<br />

formula, which at least readily explains why it is easily resolved into<br />

glycollic acid:-<br />

HO.C<br />

CH. H.OH<br />

CH.OH<br />

COH<br />

Now, as cane-sugar has to be regarded as an e<strong>the</strong>r, its constitution<br />

would be as follows;— CIL.OH<br />

H3.OH<br />

This formula shows that cane-sugar contains <strong>the</strong> group hydroxyl<br />

eight times, a fact which is proved by its forming an acetic e<strong>the</strong>r containing<br />

eight acetyls (page 286); and fur<strong>the</strong>r, it is shown that in canesugar<br />

<strong>the</strong> aldehyde-group COH is not present; it acts <strong>the</strong>refore as<br />

reducing agent only after being resolved into dextrose and kvulose.<br />

ti2

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