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A Manual of the Chemistry of the Carbon Compounds

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TEE CBBMI8TRY OF<br />

sweetish astringent taste. Its dust produces violent sneezing, and its<br />

aqueous solution, when shaken, froths like a soap-solution. Fuming<br />

hydrochloric acid resolves it into an amorphous sugar and sapogenin<br />

Caincin C^H^O is found in <strong>the</strong> caihca-root {Ghiococca racemosa),<br />

and crystallizes in slender prisms. Hydrochloric acid decomposes it<br />

into sugar and caHmebin, CgjH^Oj, •which when fused with potash is<br />

resolved into butyric acid and caimczgenin 014HMOs.<br />

Ckinovin C^H^Oj has been found in China nova and o<strong>the</strong>r cinchona-barks.<br />

It is an amorphous powder, which is insoluble in<br />

water, and by boiling it with an acid yields mannitane and chinovie<br />

add C^HjoO# which is insoluble in water, sparingly soluble in boiling<br />

alcohol, and forms a white crystalline powder. It is a bibasic<br />

acid, and apparently homologous with <strong>the</strong> phthalic acids.<br />

Qlycyrrkicin, or Liquorice-sugar O^H^Og, is <strong>the</strong> sweet principle<br />

contained in <strong>the</strong> root <strong>of</strong> tha common liquorice, and is prepared by<br />

precipitating an aqueous infusion <strong>of</strong> <strong>the</strong> root with basic lead acetate,<br />

and decomposing <strong>the</strong> washed precipitate "With hydrogen sulphide. It<br />

is a yellowish amorphous powder, having a sweet and acrid taste,<br />

When boiled with a dilute acid, it is resolved into sugar and resinous<br />

Oaphnin C8lH^Ol9 + 4Ha0 is found in <strong>the</strong> bark <strong>of</strong> <strong>the</strong> mezereon<br />

and o<strong>the</strong>r species <strong>of</strong> Daphne. It is almost insoluble in cold water,<br />

and crystallizes from a boiling solution in colourless prisms. Dilute<br />

acids decompose it into sugar and daphnctin CWHMO9.<br />

DigUalin is a most violent poison, existing in <strong>the</strong> common foxglove,<br />

and forms an amorphous powder having an intensely bitter taste. Its<br />

composition is not known; acids resolve it into sugar and amorphous<br />

digitalretin.<br />

Antiarin is <strong>the</strong> active principle <strong>of</strong> <strong>the</strong> arrow-poison <strong>of</strong> Java, which<br />

is prepared from <strong>the</strong> milky juice <strong>of</strong> Antiaris toocioaria. It forms<br />

colourless crystals, and is soluble in water and alcohol It has not<br />

been analyzed; acids convert it into sugar and a resinous substance.<br />

Cyclamin CJS2fiio occurs in <strong>the</strong> tubers <strong>of</strong> Cyclamen curopmun,<br />

and is resolvedinto sugar and cyclamirctin CnH,0O6.<br />

Oiwnin O^H^O,, is contained in <strong>the</strong> root ot Owmia spinosa, and is<br />

decomposed by boiling hydroohlorio acid into sugar and formonatin<br />

C^H-jOy, which by alkalis is resolved into omonetin CjjHjjQg and<br />

formic acid,<br />

Conifcrin occurs in <strong>the</strong> cambial liquid <strong>of</strong> <strong>the</strong> Conifera>, and has<br />

been resolved into sugar and a resin.<br />

Menyanthin, which is found in Menyan<strong>the</strong>s trifoliata, yields with<br />

acids sugar and menyantkol CgH8O, winch is a liquid resembling oil<br />

<strong>of</strong> bitter almonds, and when exposed to <strong>the</strong> air is oxidized to an acid<br />

<strong>of</strong>-unknown composition.<br />

Polychrtfitt 0^11^0,9 is <strong>the</strong> colouring matter <strong>of</strong> aaffron, and forms<br />

an amorphous, deliquescent, ruby-red mass. When boiled with a<br />

dilute acid it yields sugar, crociu, and a volatile oil. Croein. CwHlgO6

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