19.06.2013 Views

A Manual of the Chemistry of the Carbon Compounds

A Manual of the Chemistry of the Carbon Compounds

A Manual of the Chemistry of the Carbon Compounds

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

TUB CARBON COMPOUNDS. 399<br />

It forms long, slender, silky needles, melting at 15)9°, and subliming<br />

without decomposition,<br />

Oitmylic Add C6H2-< [IQ g 8 -—This monobasic acid has been prepared<br />

by boiling durene with dilute nitric acid. It is very sparingly<br />

soluble in water, and crystallizes from an alcoholic solution in hud,<br />

glistening needles or brilliant prisms, melting at 150°. It easily volatilizes,<br />

and sublimes in slender needles.<br />

Ciimidie Aeid'C6Vis { (co"^) is formed ' to g ft<strong>the</strong>r wit h cumylic<br />

acid. It is but sparingly soluble in water, and scarcely in benzene ;<br />

and is obtained in long, transparent prisms by adding benzene to its<br />

alcoholic solution. It sublimes at a high temperature without previously<br />

melting.<br />

DlMETHYMffTHYL-BEKZBNE, OK ETHYL-1BOXYLENR C6l :<br />

Has been obtained by acting with sodium on a mixture <strong>of</strong> ethyl<br />

bromide and monobroino-isoxylene. It is a colourless liquid, boiling<br />

at 184°.<br />

DIETHYt-BENZENE C6<br />

Is formed by acting with sodium on ethyl bromide and ethyl-monobromobenzena<br />

It boils at 179 s , and yields, on oxidation, ethylbenzoic<br />

acid and terephthalic add.<br />

METHYI--PHOPYI.-BENZENE<br />

This compound is formed by <strong>the</strong> action <strong>of</strong> sodium on a mixture <strong>of</strong><br />

14 bromotoluene and propyl bromide. It boils at 179°, and yields<br />

thick, oily nitro-compounds. Dilute nitric and chromic aoid oxidize<br />

it to paratoluic acid and terephthalio aoid.<br />

CYMENE, OK METHYL-18OPROPYL.BENZKNE C6H4 j rjHfCH ) '<br />

Cymene has not been produced by syn<strong>the</strong>sis, but occurs, toge<strong>the</strong>r<br />

with cuuiic aldehyde, in Koroan cumin-oil (Cvminum, Oymnvm), aad<br />

in <strong>the</strong> oil <strong>of</strong> <strong>the</strong> water-hemlock (Ciettta virosa), and mixed with<br />

thymol and a terpene in oil <strong>of</strong> thyme (Thytwus vulgaris), and <strong>the</strong> oils<br />

<strong>of</strong> Ptychotis Ajmwn, and Mtmarda pundata, and o<strong>the</strong>r volatile oils.<br />

Cymene has been obtained by abstracting two atoms <strong>of</strong> hydrogen

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!