19.06.2013 Views

A Manual of the Chemistry of the Carbon Compounds

A Manual of the Chemistry of the Carbon Compounds

A Manual of the Chemistry of the Carbon Compounds

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

342 TEE CHEMISTRY OF<br />

•warm potash-solution with a red colour, and on cooling purple needles<br />

<strong>of</strong> potassium cbloranilate crystallize out—<br />

4K0H - C6Clj03| £! + 2KC1 + 2H «°<br />

By decomposing this salt with sulphuric acid, oliloranilic acid is<br />

obtained in small reddish-white plates, which, alter drying, assume<br />

<strong>the</strong> colour <strong>of</strong> red lead, and dissolve in water with a violet colour.<br />

C "NTTT<br />

CMoranilamie Acid C0C120*2] Qg 2 —The ammonium salt <strong>of</strong> this<br />

acid is obtained by dissolving choranil in ammonia. The free acid<br />

crystallizes in almost black needles, having a diamond-lustie. By<br />

heating it with dilute acids, it is converted into chloranilio acid.<br />

f OH<br />

Pyroeatechin, or Oxyplwnic Add C0H4 i Q£.—This second dioxybenzene<br />

is found amongst <strong>the</strong> products <strong>of</strong> <strong>the</strong> distillation <strong>of</strong> wood,<br />

and in several vegetable extracts, such as " Hno," " catechu," &c.;<br />

and has also been found, but ia small quantity only, in <strong>the</strong> green<br />

leaves <strong>of</strong> <strong>the</strong> Virginian creeper. It is also produced by heating<br />

oxysalicylic acid:—<br />

COHJ CO.OH » co _ r jT 10CH3 ^ -n<br />

It is a colourless liquid, boiling at 205°, aad possessing an aromatic<br />

smell. By heating it with concentrated hydriodic acid> it is resolved<br />

nto methyl iodide and pyroeatechin.<br />

Jtcsordn €H41 Q-^.—This body is formed by fusing several resins<br />

or gum-resins (as galbanuin), or extract <strong>of</strong> sapan-wood and o<strong>the</strong>r

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!