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A Manual of the Chemistry of the Carbon Compounds

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THE CARBON COMPOUNDS, 297<br />

The stony conoretions <strong>of</strong> pears principally consist <strong>of</strong> glueodrupose<br />

C^HjgOj,,, which by boiling with hydrochlorio acid yields dextrose<br />

and drupom Cj-H^Og; and <strong>the</strong> latter, when boiled with weak nitric<br />

acid, yields cellulose, whilst on fusing it with caustio potash pyrocatechin<br />

is formed.<br />

rcrancro.<br />

This name has been given to a substance whioh has <strong>the</strong> greatest<br />

resemblance to cellulose, and appears to be identical with it. It<br />

occurs in <strong>the</strong> mantle <strong>of</strong> Ascidia (spec, <strong>of</strong> Cynthia, Phallusia, &c),<br />

from which it is obtained by boiling <strong>the</strong> mantles first with hydrochloric<br />

acid, and <strong>the</strong>n with caustio potash. In concentrated sulphuric<br />

acid it deliquesces to a colourless liquid, which on boiling with water<br />

yields a glncose.<br />

FERMENTATION.<br />

Several kinds <strong>of</strong> sugar and o<strong>the</strong>r bodies undergo, under certain<br />

conditions, a peculiar ohetnical ohange called fermentalim. Fermentation<br />

is always caused by <strong>the</strong> presence <strong>of</strong> a ferment or a substance<br />

in a peculiar state <strong>of</strong> decomposition. Although to start<br />

fermentation <strong>the</strong> presence <strong>of</strong> a ferment is necessary, it does not take<br />

part in <strong>the</strong> decomposition <strong>of</strong> <strong>the</strong> fermenting substance. The products<br />

<strong>of</strong> fermentation vary according to <strong>the</strong> nature <strong>of</strong> <strong>the</strong> fermenting body, as<br />

well as according to <strong>the</strong> nature <strong>of</strong> <strong>the</strong> ferment. Each peculiar kind<br />

<strong>of</strong> fermentation requires a certain temperature, and it is nearly always<br />

accompanied by <strong>the</strong> development <strong>of</strong> certain living bodies (infusoria<br />

or fungi); but whe<strong>the</strong>r <strong>the</strong> growth <strong>of</strong> <strong>the</strong>se is acause or a consequence<br />

<strong>of</strong> <strong>the</strong> chemical ohange has not yet been decided.<br />

In many oases fermentation sets in withont bringing a ferment in<br />

<strong>the</strong> liquid,' thus grape-juice, when exposed to <strong>the</strong> air, soon begins to<br />

ferment, because it contains albuminous substances which, U* contact<br />

with <strong>the</strong> air, readily undergo decomposition or putrefaction, and are<br />

thus converted into a ferment.<br />

Vinous Fermentation.—-When yeaat is added to a dilute solution <strong>of</strong><br />

dextrose or ano<strong>the</strong>r glucose, vinous fermentation speedily sets in ;<br />

whilst a solution <strong>of</strong> cane-sugar undergoes fermentation only slowly,<br />

<strong>the</strong> cause being that this sugar must first be converted into inverted<br />

sugar before fermentation can commence. Vinous fermentation<br />

does not take place at a temperature below 0° or above 35°, and<br />

proceeds most rapidly at 26° to 30°, The presence <strong>of</strong> a large quantity<br />

<strong>of</strong> acids or alkalis prevents fermentation; while if <strong>the</strong> liquid has a<br />

faint aoid reaction, fermentation proceeds best. The ohief produote <strong>of</strong><br />

vinous fermentation arc ethyl aloohol ami catbon dioxide;—<br />

C6H12O8 = 2CjH6O + 2COa

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