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PES Skill Sheets.book - Capital High School

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Name: Date:<br />

14.2 Percent Yield<br />

You can predict the amount of product to expect from a reaction if you know how much reactant you started with.<br />

For example, if you start out with one mole of limiting reactant, you can expect to produce one mole of product.<br />

In real-world chemical reactions, the actual amount of product is usually less than the predicted amount. This is<br />

due to experimental error and other factors (such as the fact that some product is difficult to collect and measure).<br />

The amount of product you expect to produce is called the predicted yield. The amount of product that you are<br />

able to measure after the reaction is called the actual yield. The percent yield is the actual yield divided by the<br />

predicted yield and then multiplied by 100.<br />

Actual yield<br />

Percent yield =<br />

----------------------------------- × 100<br />

Predicted yield<br />

The percent yield can provide information about how carefully the experiment was performed. If a percent yield<br />

is low, chemical engineers look for sources of error. Manufacturers of chemical products try to maximize their<br />

percent yield so that they can get the maximum amount of product to sell from the reactants that they purchased.<br />

I<br />

• In the reaction below, potassium and water are combined in a chemical reaction that produces potassium<br />

hydroxide and hydrogen gas. If two moles of potassium (the limiting reactant) are used, what is the predicted<br />

yield of potassium hydroxide (KOH) in grams?<br />

2K + 2H 2O → 2KOH + H 2<br />

1. Looking for: Predicted yield of KOH in grams<br />

2. Given: Two moles of the limiting reactant (K) are used<br />

3. Relationships: Two moles of limiting reactant should produce two moles of product. Two moles of<br />

the product will have a mass twice its molar mass.<br />

4. Solution: Molar mass of KOH = atomic mass of K + atomic mass of O + atomic mass of H<br />

From periodic table, molar mass of KOH = 39.10 + 16.00 + 1.01 = 56.11 grams<br />

Because we started with two moles of limiting reactant, we should end up with two<br />

moles, or 112.22 grams, of KOH.<br />

• If the actual yield of KOH was 102.5 grams, what was the percent yield for this reaction?<br />

1. Looking for: Percent yield of KOH<br />

2. Given: Actual yield = 102.5 g; predicted yield = 122.22 g<br />

3. Relationships: Percent yield = actual yield ÷ predicted yield × 100<br />

4. Solution: Percent yield = 102.5 g ÷ 112.22 g × 100 = 91.3%<br />

14.2

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