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[H + ] = 0,2 M<br />

pH = – log [H + ]<br />

= – log 2.10 –1 = 1 – log 2<br />

Jadi pH larutan HCl 0,2 M = 1 – log 2.<br />

4. 100 mL larutan HBr 0,1 M diencerkan dengan air 100 mL.<br />

Tentukan: a. pH mula-mula,<br />

b. pH setelah diencerkan.<br />

Penyelesaian:<br />

a. pH mula-mula:<br />

[H + ] = [HBr] = 0,1 M = 10 –1<br />

pH = – log [H + ]<br />

pH = – log 10 –1 = 1<br />

b. pH setelah diencerkan:<br />

Mol HBr mula-mula = 100.0,1 = 10 mmol = 0,010 mol<br />

Volum larutan = 100 mL + 100 mL = 200 mL = 0,2 L<br />

Kosentrasi HBr setelah diencerkan:<br />

[HBr] = 0 , 010 mol<br />

= 0,05 M<br />

02 , L<br />

[H + ] = [HBr] = 0,05 = 5.10 –2<br />

pH = –log [H + ] = –log 5.10 –2 = 2 – log 5<br />

Jadi, pH mula-mula = 1 dan pH setelah diencerkan = 2 – log 5.<br />

5. Tentukan pH larutan jika 0,37 gram kalsium hidroksida dilarutkan dalam air<br />

sampai volum 250 mL.<br />

Penyelesaian:<br />

0,37gram Ca(OH) 2<br />

= 037 ,<br />

74<br />

= 0,005 mol<br />

[Ca(OH) 2<br />

] = 0 , 005 mol<br />

= 0,02 M<br />

025 , L<br />

Ca(OH) 2<br />

(aq) Ca 2+ (aq) + 2OH – (aq)<br />

0,02 M 0,02 M 2 x 0,02 M = 0,04 M<br />

[OH – ] = 0,04 M<br />

pOH = – log [OH – ]<br />

= – log 4 x 10 –2 = 2 – log 4<br />

pH + pOH = 14<br />

pH = 14 – (2 – log 4)<br />

= 12 + log 4<br />

Jadi, pH larutan = 12 + log 4.<br />

pH Larutan Asam-Basa 177

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