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Weichmacherverlust bei PVC-Objekten von Joseph Beuys – Versuche zu kurativen und konservatorischen Massnahmen<br />

ANHANG III: ZUSAMMENSTELLUNG VON ABSTRACTS<br />

two step process: (1) soaking in a liquid and (2) drying at various temperatures. Some process parameters, such as<br />

time axnd temperature of soaking, temperature and time of drying, influence the treatment efficacy. The best values<br />

consider in from these factors were found due to experimental designs and the physical significance of the results is<br />

discussed.<br />

© 2003 Society of Chemical Industry<br />

Fugit, Jean-Luc; Taverdet, Jean-Louis (2001): Decreasing pollution of plasticized PVC packaging: A<br />

comparison of three plastic treatments. In: Journal of Applied Polymer Science, Volume 80, Issue 10, Date:<br />

16 June 2001, S. 1841-1847<br />

This study proposed three different treatments of plasticized PVC, which decreases diffusion of the plasticizer when<br />

the plastic is in contact with a liquid food or simulated liquid food. The treated PVCs were tested under the same<br />

operating conditions, and their efficiency was able to be assessed thanks to a diffusion model previously described. It<br />

was shown that the time and the temperature of the storage of the treated PVCs influenced the effectiveness of the<br />

treatment. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 1841-1847, 2001<br />

Bichara, Ali; Fugit, Jean-Luc; Ouillon, Isabelle; Taverdet, Jean-Louis (1999): Optimization of a process capable<br />

of decreasing the pollution from PVC packaging material. In: Journal of Applied Polymer Science, Volume<br />

74, Issue 14, Date: 27 December 1999, S. 3492-3500<br />

This work is the study of a process capable of decreasing the migration of the plasticizer into a liquid food or a<br />

simulant from a plasticized PVC packaging. The treatment is a two-step process: (1) soaking in a liquid, and (2)<br />

drying at various temperatures. The efficiency of this method depends on many factors: nature of the liquid and<br />

immersion time, temperature and time of drying, etc. The influence of the most important of them had been<br />

quantified with a mathematical model previously described. The purpose of this study is to search for the best value<br />

of each parameter and, therefore, to optimize the reduction of mass transfers.<br />

Bichara, Ali; Fugit, Jean-Luc; Taverdet, Jean-Louis (1999): Modeling of mass transfers between food<br />

simulants and treated plasticized PVC. In: Journal of Applied Polymer Science, Volume 72, Issue 1, Date: 4<br />

April 1999, S. 49-58<br />

(...) This study concerns mass transfers between plasticized PVC, having been subjected to a treatment, and liquid<br />

food or food simulants. The treatment reduces the diffusion of the plasticizer and the influence of some factors of this<br />

processing are investigated. A mathematical model, able to simulate these mass transfers and to quantify the<br />

treatment parameters, is proposed.<br />

Taverdet, J. L.; Vergnaud, J. M. (1986): Preparation of plasticized PVC samples with very low matter<br />

transfers. In: European Polymer Journal, Volume 22, Issue 12 , 1986, S. 959-962<br />

Plasticized PVC is very often used for packaging for liquid foods or blood and blood components. Two simultaneous<br />

matter transfers may take place, one concerned with the liquid entering the PVC, and the other with the plasticizer<br />

leaving the PVC. Both transfers are controlled by diffusion in transient conditions with concentration-dependent<br />

diffusivities. By using information obtained on the profiles of concentration of both these liquids developed through a<br />

PVC sheet during the process and with the help of a model based on an explicit numerical analysis with finite<br />

differences, we have developed a method of preparation of plasticized PVC sample with very low matter transfers.<br />

The principle of this method is as follows: after soaking the sample in a liquid for a definite short time, the sample is<br />

extracted and the liquid is evaporated. The concentration of the plasticizer is high within the PVC, but very low on the<br />

surface; the sample is therefore not permeable to liquids.

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