198 Topics in Current Chemistry Editorial Board: A. de Meijere KN ...

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110 R.E. Meléndez · A.D. Hamilton (1-octene, squalene), alicyclic (camphor) and other guests like methoxyethylether, propellane, and epichlorohydrin. Although in some cases catenation is prevented from occurring, at present only five hexagonal networks stacked on top of each other have been observed [22]. Sections of the crystal structures of 2 with n-tetradecane and oleyl alcohol included in the cavities are shown in Fig. 12 [47]. a b Fig. 12 a, b. Structures of inclusion compounds of 2 with: a n-tetradecane; b oleyl alcohol. (Reproduced with permission of Pergamon (1996) from Comprehensive supramolecular chemistry, vol 6, chap 3) Fig. 13. Sheets formed in the crystal structure of [2 2 ◊ pyrene ◊ 2EtOH]
Hydrogen-Bonded Ribbons, Tapes and Sheets as Motifs for Crystal Engineering 111 Based on Herbstein’s results using long chain guests, Zimmerman proposed to prevent interpenetration of the trimesic acid networks by including a large and relatively non-flexible guest molecule such as pyrene in the cavities. Indeed the pyrene is incorporated in the cavity as well as some ethanol solvent molecules (Fig. 13). The hydrogen bonded dimer in 2 is actually expanded by the presence of ethanol molecules, although the formation of the hexamer prevails in the sheet formation [48]. In the context of generating porosity, Zaworotko’s group has used a modular approach in order to propagate the symmetry of trimesic acid. This strategy involves the use of hydrogen bonding spacers between units of 2 to expand the size of the cavities. In this case secondary amines were reacted with 2 to form salts 15 and 16 (Fig. 14). The resulting solid lattices were observed in the crystal b a = trimesate anion = ammonium spacer 15 16 15 H 3TMA = trimesic acid (2) Fig. 14 a, b. Schematic representation of the modular strategy for increasing cavity size in 2. b Hydrogen bonding pattern in salts 15 and 16 16
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198 Topics in Current Chemistry Edi
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Design of Organic Solids Volume Edi
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Volume Editors Prof. Dr. Edwin Webe
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VIII preface tion at an amazing lev
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Contents of Volume 196 Carbon Rich
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2 J.P. Glusker 5 Interactions of Pl
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4 J.P. Glusker Perturbations to the
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6 J.P. Glusker 2.1 Sources of Cryst
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8 J.P. Glusker other induced, will
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10 J.P. Glusker The forces here hav
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12 J.P. Glusker lographic structure
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14 J.P. Glusker a c Fig. 6 a - c. D
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16 J.P. Glusker hydrogen bond H◊
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18 J.P. Glusker Fig. 9. Citric acid
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20 J.P. Glusker peptide plane and a
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22 J.P. Glusker 4.5 F◊◊◊H Int
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24 J.P. Glusker rine-containing com
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26 J.P. Glusker Fig. 17. The packin
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28 J.P. Glusker bind to a metal ion
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30 J.P. Glusker As for carboxylate
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32 J.P. Glusker Fig. 24. The magnes
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34 J.P. Glusker structures of magne
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36 J.P. Glusker b a Fig. 28 a, b. A
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38 J.P. Glusker Fig. 30. Complexati
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40 J.P. Glusker 7.1 Descriptions of
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42 J.P. Glusker Fig. 34. Glycine cr
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44 J.P. Glusker bonding capabilitie
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46 J.P. Glusker 2. Non-intercalativ
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48 J.P. Glusker d Fig. 37 d. The ch
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50 J.P. Glusker Fig. 39. Hydrogen-b
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52 J.P. Glusker 72, 104], but other
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54 J.P. Glusker 23. Cody V, Murray-
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56 J.P. Glusker: Directional Aspect
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Crystalline Polymorphism of Organic
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Author Index Volumes 151-198 Author
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Author Index Volumes 151 - 198 2 1
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Author Index Volumes 151 - 198 213
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Author Index Volumes 151 - 198 2 ]
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Springer and the environment At Spr
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198 Topics in Current Chemistry Editorial Board: A. de Meijere KN ...

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