198 Topics in Current Chemistry Editorial Board: A. de Meijere KN ...

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Functional Organic Zeolite Analogues 139 22 23 Fig. 7. 12-Annulene-like motif formed by 22◊ AgOTf. The counteranion is not shown for clarity. The sheets (23) are layered to form intersheet channels and 3.55 Å in the porphyrin (3 ◊ 2Cd(NO 3) 2◊ 8.6H 2O), bipyridine [2(18) ◊ Cd(NO 3) 2◊ 2(o-C 6H 4Br 2)] and tricyano (20 ◊ AgOTf) systems, respectively. Trimesic (benzene-1,3,5-tricarboxylic) acid (24) forms a hydrogen-bonded hexagonal motif 25 with a 14 Å-hole (Fig. 8). It stacks in the vertical direction as above.An extensive interpenetration of the networks, however, leaves no channel capable of guest binding [46] (see also the article by R.E. Meléndez and A.D. Hamilton in this volume). Such an interpenetration or polycatenation can be elegantly prevented by building a covalently-closed macrocyclic ring 26 with a 9 Å-hole [47] or an open dimer 27 [48]. The use of a bulky amine as a spacer also leads to a non-interpenetrating and hence guest-binding motif 28 with a 12.7 Åhole [49]. The cyclohexyl groups in the amine partially cover the guest-binding cavity, thereby inhibiting interpenetration of the networks. Anthracene-diresorcinol derivative 29 [50–52] is an in-plane tetraol, having an inclined or orthogonal anthracene spacer (Fig. 9). It forms a hydrogen-bon-
140 Y. Aoyama 24 ded (O-H◊◊◊O-H) 2D net 30. There is no interpenetration of the nets. Their layer structure is somehow different from the previous cases. The presence of the orthogonal spacers sticking out of the sheet prevents close packing thereof. Actually, the sheets are layered in a staggered manner (31 for the top view of neighbouring sheets) with an intersheet distance of ~7 Å. This gives rise to a “depth” of the big cavities (~ 10 Å height for the free space, referring to 30), which incorporate two guest molecules (ketone or ester), antiparallel with each 25 28 26 27 Fig. 8. Hexagonal motifs formed by 24 and its covalently-linked derivatives ◊◊◊◊ ◊◊◊◊◊◊ … … ◊◊◊◊◊ ◊◊◊◊◊
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198 Topics in Current Chemistry Edi
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Design of Organic Solids Volume Edi
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Volume Editors Prof. Dr. Edwin Webe
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VIII preface tion at an amazing lev
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Contents of Volume 196 Carbon Rich
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2 J.P. Glusker 5 Interactions of Pl
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4 J.P. Glusker Perturbations to the
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6 J.P. Glusker 2.1 Sources of Cryst
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8 J.P. Glusker other induced, will
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10 J.P. Glusker The forces here hav
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12 J.P. Glusker lographic structure
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14 J.P. Glusker a c Fig. 6 a - c. D
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16 J.P. Glusker hydrogen bond H◊
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18 J.P. Glusker Fig. 9. Citric acid
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20 J.P. Glusker peptide plane and a
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22 J.P. Glusker 4.5 F◊◊◊H Int
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24 J.P. Glusker rine-containing com
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26 J.P. Glusker Fig. 17. The packin
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28 J.P. Glusker bind to a metal ion
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30 J.P. Glusker As for carboxylate
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32 J.P. Glusker Fig. 24. The magnes
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34 J.P. Glusker structures of magne
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36 J.P. Glusker b a Fig. 28 a, b. A
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38 J.P. Glusker Fig. 30. Complexati
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40 J.P. Glusker 7.1 Descriptions of
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42 J.P. Glusker Fig. 34. Glycine cr
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44 J.P. Glusker bonding capabilitie
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46 J.P. Glusker 2. Non-intercalativ
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48 J.P. Glusker d Fig. 37 d. The ch
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50 J.P. Glusker Fig. 39. Hydrogen-b
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52 J.P. Glusker 72, 104], but other
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54 J.P. Glusker 23. Cody V, Murray-
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56 J.P. Glusker: Directional Aspect
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58 A. Nangia · G.R. Desiraju 7 Sup
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60 A. Nangia · G.R. Desiraju elect
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62 A. Nangia · G.R. Desiraju 14 15
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64 A. Nangia · G.R. Desiraju [23]
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66 A. Nangia · G.R. Desiraju struc
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68 A. Nangia · G.R. Desiraju Fig.
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70 A. Nangia · G.R. Desiraju -NH 2
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72 A. Nangia · G.R. Desiraju ingfu
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74 A. Nangia · G.R. Desiraju and r
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76 A. Nangia · G.R. Desiraju bonds
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78 A. Nangia · G.R. Desiraju 2.86-
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80 A. Nangia · G.R. Desiraju from
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82 A. Nangia · G.R. Desiraju ted a
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84 A. Nangia · G.R. Desiraju envir
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Page 139 and 140: 132 Y. Aoyama 4 Catalysis . . . . .
Page 141 and 142: 134 Y. Aoyama 2.2 Symmetry-Controll
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Page 151 and 152: 144 Y. Aoyama In the presence of a
Page 153 and 154: 146 Y. Aoyama clusion compounds (se
Page 155 and 156: 148 Y. Aoyama are intriguing guests
Page 157 and 158: 150 Y. Aoyama The tuning or enginee
Page 159 and 160: 152 Y. Aoyama Fig. 16. Binding isot
Page 161 and 162: 154 Y. Aoyama The desorption of the
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Page 165 and 166: 158 Y. Aoyama 5 Concluding Remarks
Page 167 and 168: 160 Y. Aoyama 4. Hölderich W, Hess
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Crystalline Polymorphism of Organic
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Author Index Volumes 151-198 Author
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Author Index Volumes 151 - 198 2 1
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Author Index Volumes 151 - 198 213
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Author Index Volumes 151 - 198 2 ]
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Springer and the environment At Spr
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198 Topics in Current Chemistry Editorial Board: A. de Meijere KN ...

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