198 Topics in Current Chemistry Editorial Board: A. de Meijere KN ...

Hydrogen-Bonded Ribbons, Tapes and Sheets as Motifs for Crystal Engineering 127
4
Conclusion
In summary, we have shown that a wide range of molecular subunit shapes and
orientations can be used to generate designed packing arrangements in the solid
state. A key feature of these approaches is the exploitation of well defined and
directional intermolecular interactions. In several cases, certain recognition
motifs have been borrowed from solution based host-guest chemistry to impart
the necessary control and specificity on multicomponent aggregation in the
solid state. Both strong and weak hydrogen bonding interactions have been used
extensively to produce ordered tapes, ribbons, and sheets. As a result, new solid
materials with functional physical and chemical properties have been produced.
These have included polar crystals with non-linear optical properties, as well as
porous solids with well defined cavities that can selectively complex and even
catalyze reactions of small organic molecules.
Acknowledgment. The portions of this work carried out at the University of Pittsburgh and Yale
University were supported by the National Science Foundation (CHE 9213937).
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