198 Topics in Current Chemistry Editorial Board: A. de Meijere KN ...

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Functional Organic Zeolite Analogues 137 ty of the cavities, the channels can be designed in a more straightforward manner by letting porous 2D nets stack sheet by sheet. Pillared clays and graphite, in contrast to zeolites and diamond, represent typical layer structures. Porous 2D nets are obtained by assembling planar tri- or tetratopic building blocks directly or via connectors. Layered 2D nets may be classified according to the types of intersheet interactions. When assembled with Cd II (Cd(NO 3 – )2◊ 2H 2O) as a linear (trans) or bent (cis) 2-connector, the above-mentioned tetra(4-pyridyl)porphyrin (3; X=N and M=Pd II ) forms a (4,2)-connected 2D net 17 (Fig. 4) [43]. The same Cd II ion in Cd(NO 3 – )2 acting in this case as a square planar 4-connector is used to assemble 4,4¢-bipyridine 18 as a bidentate linear ligand to afford a (2,4)-connected 2D net 19 (Fig. 5) [44]. Tritopic tricyano derivative 20 [41] or 22 [45] and the Ag I ion (AgOTf) in the trigonal-bipyramidal geometry form a (3,3)-connected 2D net composed of a hexagonal 21 or 12-annulene-like cyclic motif 23, respectively (Figs. 6 and 7). The resulting molecular sheets stack vertically to form channels incorporating solvent molecules and counter anions; the intersheet distances depend on the extent of coplanarity of the in-sheet aromatic moieties and are 4.68, 6.30, 17 Fig. 4. 2D net formed by 3◊ Cd(OH 2) 2(NO 3) 2 (X=N and M=Pd II ). The sheets (17) are layered to give intersheet channels
138 Y. Aoyama 18 19 Fig. 5. 2D net formed by 2(18)◊ Cd(NO 3) 2. The sheets (19) are layered to give intersheet channels 20 21 Fig. 6. Hexagonal motif formed by 20◊ AgOTf. The counteranion is not shown for clarity. The sheets (21) are layered by stacking
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198 Topics in Current Chemistry Edi
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Design of Organic Solids Volume Edi
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Volume Editors Prof. Dr. Edwin Webe
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VIII preface tion at an amazing lev
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Contents of Volume 196 Carbon Rich
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2 J.P. Glusker 5 Interactions of Pl
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4 J.P. Glusker Perturbations to the
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6 J.P. Glusker 2.1 Sources of Cryst
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8 J.P. Glusker other induced, will
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10 J.P. Glusker The forces here hav
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12 J.P. Glusker lographic structure
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14 J.P. Glusker a c Fig. 6 a - c. D
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16 J.P. Glusker hydrogen bond H◊
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18 J.P. Glusker Fig. 9. Citric acid
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20 J.P. Glusker peptide plane and a
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22 J.P. Glusker 4.5 F◊◊◊H Int
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24 J.P. Glusker rine-containing com
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26 J.P. Glusker Fig. 17. The packin
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28 J.P. Glusker bind to a metal ion
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30 J.P. Glusker As for carboxylate
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32 J.P. Glusker Fig. 24. The magnes
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34 J.P. Glusker structures of magne
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36 J.P. Glusker b a Fig. 28 a, b. A
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38 J.P. Glusker Fig. 30. Complexati
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40 J.P. Glusker 7.1 Descriptions of
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42 J.P. Glusker Fig. 34. Glycine cr
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44 J.P. Glusker bonding capabilitie
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46 J.P. Glusker 2. Non-intercalativ
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48 J.P. Glusker d Fig. 37 d. The ch
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50 J.P. Glusker Fig. 39. Hydrogen-b
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52 J.P. Glusker 72, 104], but other
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54 J.P. Glusker 23. Cody V, Murray-
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56 J.P. Glusker: Directional Aspect
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58 A. Nangia · G.R. Desiraju 7 Sup
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60 A. Nangia · G.R. Desiraju elect
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62 A. Nangia · G.R. Desiraju 14 15
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64 A. Nangia · G.R. Desiraju [23]
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66 A. Nangia · G.R. Desiraju struc
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68 A. Nangia · G.R. Desiraju Fig.
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70 A. Nangia · G.R. Desiraju -NH 2
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72 A. Nangia · G.R. Desiraju ingfu
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74 A. Nangia · G.R. Desiraju and r
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76 A. Nangia · G.R. Desiraju bonds
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78 A. Nangia · G.R. Desiraju 2.86-
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80 A. Nangia · G.R. Desiraju from
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82 A. Nangia · G.R. Desiraju ted a
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Page 139 and 140: 132 Y. Aoyama 4 Catalysis . . . . .
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Page 161 and 162: 154 Y. Aoyama The desorption of the
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Page 165 and 166: 158 Y. Aoyama 5 Concluding Remarks
Page 167 and 168: 160 Y. Aoyama 4. Hölderich W, Hess
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Crystalline Polymorphism of Organic
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Author Index Volumes 151-198 Author
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Author Index Volumes 151 - 198 2 1
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Author Index Volumes 151 - 198 213
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Author Index Volumes 151 - 198 2 ]
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Springer and the environment At Spr
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