198 Topics in Current Chemistry Editorial Board: A. de Meijere KN ...

More documents

Recommendations

Info

Functional Organic Zeolite Analogues 143 the anthracene analogue. The excess hydrogen bonding capability is used in guest binding (O-H◊◊◊O-H◊◊◊OC) as in the anthracene case above. The sheet formation for the tetraresorcinol derivative 41 occurs in such a way as depicted in 42. In this case, intersheet hydrogen bonding (O-H◊◊◊O-H◊◊◊O-H◊◊◊O-H) is sterically allowed and gives rise to a continuous channel (cross-sectional area 33 Å 2 ) incorporating solvent (7C 6H 5CN) molecules [56]. A set of vertical hydrogen bonding is also used successfully to assemble cyclic peptides having alternating l- and D-amino acid moieties into nanotubes [57]. 39 41 Fig. 11. Top view of 2D net formed by 39 or 41 40 42
144 Y. Aoyama In the presence of a strong but weakly coordinating base such as triethylamine, fully deprotonated trimesic acid (43) (Fig. 12) acts as a hexamonodentate unit. It is assembled with the 6-coordinate Zn II ion (Zn(NO 3) 2) formally in a 2D fashon 44 and then into a rigid metal-coordinated 3D network 45 [58]. The basic unit in adduct 43 ◊ 2Zn◊ (NO 3)◊ (H 2O)◊ 5(CH 3CH 2OH) is a 10-membered macrocyclic ring motif 46. Highly mobile ethanol and water molecules reside in the extended channel having a 14 Å cross-section. Coordination networks can often be further cross-linked via hydrogen bonding between metal ligands [59, 60]. A chiral bicyclic diol 47 and its analogues such as 50 and 52 form spiral hydrogen-bonded spines ◊◊◊O-H◊◊◊O-H◊◊◊O-H◊◊◊O-H◊◊◊ (48) around a threefold screw axis (Fig. 13) [61]. The molecules are assembled in a helical manner to give welldefined intrahelix canals 49, 51,and 53 of different cross-sections) supported by six such spines. The cross-sectional area is ~ 20 Å 2 in the case of 49 and a variety of guest molecules are included therein to form a class of helical tubulate in- 43 44 45 Fig. 12. 3D net formed by 43◊2Zn◊(NO 3). The counteranion is not shown for clarity 46
Page 1 and 2:
198 Topics in Current Chemistry Edi
Page 3 and 4:
Design of Organic Solids Volume Edi
Page 5 and 6:
Volume Editors Prof. Dr. Edwin Webe
Page 7 and 8:
VIII preface tion at an amazing lev
Page 9 and 10:
Contents of Volume 196 Carbon Rich
Page 11 and 12:
2 J.P. Glusker 5 Interactions of Pl
Page 13 and 14:
4 J.P. Glusker Perturbations to the
Page 15 and 16:
6 J.P. Glusker 2.1 Sources of Cryst
Page 17 and 18:
8 J.P. Glusker other induced, will
Page 19 and 20:
10 J.P. Glusker The forces here hav
Page 21 and 22:
12 J.P. Glusker lographic structure
Page 23 and 24:
14 J.P. Glusker a c Fig. 6 a - c. D
Page 25 and 26:
16 J.P. Glusker hydrogen bond H◊
Page 27 and 28:
18 J.P. Glusker Fig. 9. Citric acid
Page 29 and 30:
20 J.P. Glusker peptide plane and a
Page 31 and 32:
22 J.P. Glusker 4.5 F◊◊◊H Int
Page 33 and 34:
24 J.P. Glusker rine-containing com
Page 35 and 36:
26 J.P. Glusker Fig. 17. The packin
Page 37 and 38:
28 J.P. Glusker bind to a metal ion
Page 39 and 40:
30 J.P. Glusker As for carboxylate
Page 41 and 42:
32 J.P. Glusker Fig. 24. The magnes
Page 43 and 44:
34 J.P. Glusker structures of magne
Page 45 and 46:
36 J.P. Glusker b a Fig. 28 a, b. A
Page 47 and 48:
38 J.P. Glusker Fig. 30. Complexati
Page 49 and 50:
40 J.P. Glusker 7.1 Descriptions of
Page 51 and 52:
42 J.P. Glusker Fig. 34. Glycine cr
Page 53 and 54:
44 J.P. Glusker bonding capabilitie
Page 55 and 56:
46 J.P. Glusker 2. Non-intercalativ
Page 57 and 58:
48 J.P. Glusker d Fig. 37 d. The ch
Page 59 and 60:
50 J.P. Glusker Fig. 39. Hydrogen-b
Page 61 and 62:
52 J.P. Glusker 72, 104], but other
Page 63 and 64:
54 J.P. Glusker 23. Cody V, Murray-
Page 65 and 66:
56 J.P. Glusker: Directional Aspect
Page 67 and 68:
58 A. Nangia · G.R. Desiraju 7 Sup
Page 69 and 70:
60 A. Nangia · G.R. Desiraju elect
Page 71 and 72:
62 A. Nangia · G.R. Desiraju 14 15
Page 73 and 74:
64 A. Nangia · G.R. Desiraju [23]
Page 75 and 76:
66 A. Nangia · G.R. Desiraju struc
Page 77 and 78:
68 A. Nangia · G.R. Desiraju Fig.
Page 79 and 80:
70 A. Nangia · G.R. Desiraju -NH 2
Page 81 and 82:
72 A. Nangia · G.R. Desiraju ingfu
Page 83 and 84:
74 A. Nangia · G.R. Desiraju and r
Page 85 and 86:
76 A. Nangia · G.R. Desiraju bonds
Page 87 and 88:
78 A. Nangia · G.R. Desiraju 2.86-
Page 89 and 90:
80 A. Nangia · G.R. Desiraju from
Page 91 and 92:
82 A. Nangia · G.R. Desiraju ted a
Page 93 and 94:
84 A. Nangia · G.R. Desiraju envir
Page 95 and 96:
86 A. Nangia · G.R. Desiraju PYRAZ
Page 97 and 98:
88 A. Nangia · G.R. Desiraju napht
Page 99 and 100: 90 A. Nangia · G.R. Desiraju b c F
Page 101 and 102: 92 A. Nangia · G.R. Desiraju all a
Page 103 and 104: 94 A. Nangia · G.R. Desiraju 42. J
Page 105 and 106: Hydrogen-Bonded Ribbons, Tapes and
Page 139 and 140: 132 Y. Aoyama 4 Catalysis . . . . .
Page 141 and 142: 134 Y. Aoyama 2.2 Symmetry-Controll
Page 143 and 144: 136 Y. Aoyama A trigonal centre is
Page 145 and 146: 138 Y. Aoyama 18 19 Fig. 5. 2D net
Page 147 and 148: 140 Y. Aoyama 24 ded (O-H◊◊◊O
Page 149: 142 Y. Aoyama 2.4 Interaction-Suppo
Page 153 and 154: 146 Y. Aoyama clusion compounds (se
Page 155 and 156: 148 Y. Aoyama are intriguing guests
Page 157 and 158: 150 Y. Aoyama The tuning or enginee
Page 159 and 160: 152 Y. Aoyama Fig. 16. Binding isot
Page 161 and 162: 154 Y. Aoyama The desorption of the
Page 163 and 164: 156 Y. Aoyama Fig. 17. Suggested me
Page 165 and 166: 158 Y. Aoyama 5 Concluding Remarks
Page 167 and 168: 160 Y. Aoyama 4. Hölderich W, Hess
Page 169 and 170: Crystalline Polymorphism of Organic
Page 201 and 202:
Crystalline Polymorphism of Organic
Page 203 and 204:
Page 205 and 206:
Page 207 and 208:
Page 209 and 210:
Page 211 and 212:
Page 213 and 214:
Page 215 and 216:
Author Index Volumes 151-198 Author
Page 217 and 218:
Author Index Volumes 151 - 198 2 1
Page 219 and 220:
Author Index Volumes 151 - 198 213
Page 221 and 222:
Page 223 and 224:
Author Index Volumes 151 - 198 2 ]
Page 225 and 226:
Page 227 and 228:
Springer and the environment At Spr
show all

198 Topics in Current Chemistry Editorial Board: A. de Meijere KN ...

Create successful ePaper yourself

Delete template?

Save as template?