198 Topics in Current Chemistry Editorial Board: A. de Meijere KN ...

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114 R.E. Meléndez · A.D. Hamilton 20 21 Fig. 17. Dimers and ribbons formed by asymmetric 20 and symmetric dipyridones 21 b a Fig. 18 a, b. Lactam 22 has potential to form: a cyclic hexamer in pure enantiomeric form; b ribbon when (+) and (–) units alternate 22
Hydrogen-Bonded Ribbons, Tapes and Sheets as Motifs for Crystal Engineering 115 Fig. 19. Sheets formed by 23 and 24 23 24 compounds [57, 58]. They have found that the solid state structure formed by compounds of 25 and 26 is dependent upon steric interactions.Variations in the structure of each of the monomers were shown to have a significant effect on the architecture of the assembled system. For example, when the substituents on the phenyl rings in the melamine subunit are small (CH 3, F, Cl, Br, I) (Fig. 20a) tapes are formed. In the case of methyl and ethyl esters the components aggregate as ribbons (Fig. 20b). However, when the substituents are t-butyl groups a cyclic hexamer is formed (Fig. 20c) [59]. Lehn and coworkers designed a supramolecular cyclic aggregate based on subunits 25 and 27 [60].The butyl substituent on the triaminopyrimidine was not bulky enough to induce cyclic aggregate formation and instead formed the tape shown in Fig. 21 (see also the article by A. Nangia and G.R. Desiraju in this volume). Based on the previous result, Lehn et al. developed an elegant strategy for promoting the formation of cyclic aggregates based on hydrogen bonding function-
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198 Topics in Current Chemistry Edi
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Design of Organic Solids Volume Edi
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Volume Editors Prof. Dr. Edwin Webe
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VIII preface tion at an amazing lev
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Contents of Volume 196 Carbon Rich
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2 J.P. Glusker 5 Interactions of Pl
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4 J.P. Glusker Perturbations to the
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6 J.P. Glusker 2.1 Sources of Cryst
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8 J.P. Glusker other induced, will
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10 J.P. Glusker The forces here hav
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12 J.P. Glusker lographic structure
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14 J.P. Glusker a c Fig. 6 a - c. D
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16 J.P. Glusker hydrogen bond H◊
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18 J.P. Glusker Fig. 9. Citric acid
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20 J.P. Glusker peptide plane and a
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22 J.P. Glusker 4.5 F◊◊◊H Int
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24 J.P. Glusker rine-containing com
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26 J.P. Glusker Fig. 17. The packin
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28 J.P. Glusker bind to a metal ion
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30 J.P. Glusker As for carboxylate
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32 J.P. Glusker Fig. 24. The magnes
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34 J.P. Glusker structures of magne
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36 J.P. Glusker b a Fig. 28 a, b. A
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38 J.P. Glusker Fig. 30. Complexati
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40 J.P. Glusker 7.1 Descriptions of
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42 J.P. Glusker Fig. 34. Glycine cr
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44 J.P. Glusker bonding capabilitie
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46 J.P. Glusker 2. Non-intercalativ
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48 J.P. Glusker d Fig. 37 d. The ch
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50 J.P. Glusker Fig. 39. Hydrogen-b
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52 J.P. Glusker 72, 104], but other
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54 J.P. Glusker 23. Cody V, Murray-
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56 J.P. Glusker: Directional Aspect
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58 A. Nangia · G.R. Desiraju 7 Sup
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60 A. Nangia · G.R. Desiraju elect
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Page 141 and 142: 134 Y. Aoyama 2.2 Symmetry-Controll
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Page 153 and 154: 146 Y. Aoyama clusion compounds (se
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Page 157 and 158: 150 Y. Aoyama The tuning or enginee
Page 159 and 160: 152 Y. Aoyama Fig. 16. Binding isot
Page 161 and 162: 154 Y. Aoyama The desorption of the
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Page 165 and 166: 158 Y. Aoyama 5 Concluding Remarks
Page 167 and 168: 160 Y. Aoyama 4. Hölderich W, Hess
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Crystalline Polymorphism of Organic
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Author Index Volumes 151-198 Author
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Author Index Volumes 151 - 198 2 1
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Author Index Volumes 151 - 198 213
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Author Index Volumes 151 - 198 2 ]
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Springer and the environment At Spr
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