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The Dreaded Orange Shift<br />

Acidity<br />

As I discuss more in Chapter 7, acidic components in either a print or the accompanying<br />

support, backing board, or mat can be destructive eventually. Many inkjet papers on the<br />

market are, in fact, produced with an acidic paper base. These papers may have good light<br />

stability but will typically have worse dark stability.<br />

What Can Happen?<br />

■ Paper yellowing over time<br />

■ Slow destruction of print materials<br />

Chapter 5 ■ Determining Print Permanence 151<br />

The problem of atmospheric contamination was rudely brought to everyone’s attention in 2000 by the Orange Shift fiasco. What happened was<br />

that some people’s inkjet prints made on Epson’s Premium Glossy Photo Paper (PGPP) inexplicably experienced severe color shifting, turning<br />

bright orange, sometimes within 24 hours of being printed! But, this didn’t happen to everyone; it was completely dependent on where you lived,<br />

what your local environment was like, and whether your prints were covered or not. It turned out that PGPP was Epson’s first paper to use a<br />

“microporous” coating to improve image quality. Unfortunately, this coating acted like a sponge, soaking up any ozone or other atmospheric contaminants<br />

and speeding up the exchange of gases to the cyan dye in the inks. The cyan rapidly faded, and that left only the yellow and magenta,<br />

which combined to produce orange (“differential fading”). (For those who didn’t have the problem, the prints were—and continue to be—fine.)<br />

Epson, along with everyone else (photographer Bob Meyer points out that this was not just an Epson problem), was caught off-guard, and they<br />

ultimately released new types of paper coatings to help put the problem behind them.<br />

This situation pointed out the importance of air flow over the surface of the print. It is now universally recommended that prints destined for<br />

long-term display should be framed under glass or plastic or otherwise protected from atmospheric contaminants.<br />

Photographer Bob Meyer’s Bair Test<br />

Chart images at bottom show an Epson<br />

Premium Glossy Photo Paper print<br />

before (left) and after exposure to his<br />

“ozone chamber,” which involves<br />

placing the print at the bottom of an<br />

electronic air filter, a known ozone<br />

source. The larger images were taken of<br />

a neutral gray patch on a similarly<br />

orange-shifted print (plus a control)<br />

with a microscope (150x<br />

magnification) by Roger Smith at the<br />

University of New Brunswick, Canada.<br />

Before is on the left; after is on the<br />

right.<br />

Courtesy of Roger Smith (top) and Bob<br />

Meyer (bottom); Bair Test Chart:<br />

www.inkjetart.com/custom/index.html

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